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Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate. / Semenov, A. P.; Mendgaziev, R. I.; Stoporev, A. S. et al.

In: Chemistry and Technology of Fuels and Oils, Vol. 54, No. 6, 15.01.2019, p. 738-742.

Research output: Contribution to journal › Article › peer-review

Harvard

Semenov, AP, Mendgaziev, RI, Stoporev, AS, Gushchina, YF, Anikushin, BM, Gushchin, PA & Khlebnikov, VN 2019, 'Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate', Chemistry and Technology of Fuels and Oils, vol. 54, no. 6, pp. 738-742. https://doi.org/10.1007/s10553-019-00981-2

APA

Semenov, A. P., Mendgaziev, R. I., Stoporev, A. S., Gushchina, Y. F., Anikushin, B. M., Gushchin, P. A., & Khlebnikov, V. N. (2019). Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate. Chemistry and Technology of Fuels and Oils, 54(6), 738-742. https://doi.org/10.1007/s10553-019-00981-2

Vancouver

Semenov AP, Mendgaziev RI, Stoporev AS, Gushchina YF, Anikushin BM, Gushchin PA et al. Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate. Chemistry and Technology of Fuels and Oils. 2019 Jan 15;54(6):738-742. doi: 10.1007/s10553-019-00981-2

Author

Semenov, A. P. ; Mendgaziev, R. I. ; Stoporev, A. S. et al. / Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate. In: Chemistry and Technology of Fuels and Oils. 2019 ; Vol. 54, No. 6. pp. 738-742.

BibTeX

@article{4f17ee9dfcef4e01ac8fdc44ebd78806,
title = "Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate",
abstract = " Mixtures of magnesium chloride and MeOH were studied as mixed thermodynamic inhibitors of hydrate formation. The equilibrium P,T-conditions for methane hydrate decomposition in the presence of binary solutions H 2 O—MeOH and H 2 O—MgCl 2 and ternary solutions H 2 O—MeOH—MgCl 2 were determined using an isochoric method in a stirred autoclave. Measurements were made at pressures of 3.5-9.5 MPa; MeOH concentrations, 0-25 mass%. The salt content in the aqueous solutions was constant at 5 mass%. The results showed that mixed samples containing MeOH and MgCl 2 gave the largest thermodynamic shifts of hydrate formation as compared to samples with MeOH at the same inhibitor mass fraction. The larger thermodynamic shift was related to synergism between the affects of MgCl 2 and MeOH in the aqueous solution. ",
keywords = "gas hydrates, hydrate-formation inhibitors, MeOH, MgC1",
author = "Semenov, {A. P.} and Mendgaziev, {R. I.} and Stoporev, {A. S.} and Gushchina, {Yu F.} and Anikushin, {B. M.} and Gushchin, {P. A.} and Khlebnikov, {V. N.}",
year = "2019",
month = jan,
day = "15",
doi = "10.1007/s10553-019-00981-2",
language = "English",
volume = "54",
pages = "738--742",
journal = "Chemistry and Technology of Fuels and Oils",
issn = "0009-3092",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Synergism of Methanol and Magnesium Chloride for Thermodynamic Inhibition of Methane Hydrate

AU - Semenov, A. P.

AU - Mendgaziev, R. I.

AU - Stoporev, A. S.

AU - Gushchina, Yu F.

AU - Anikushin, B. M.

AU - Gushchin, P. A.

AU - Khlebnikov, V. N.

PY - 2019/1/15

Y1 - 2019/1/15

N2 - Mixtures of magnesium chloride and MeOH were studied as mixed thermodynamic inhibitors of hydrate formation. The equilibrium P,T-conditions for methane hydrate decomposition in the presence of binary solutions H 2 O—MeOH and H 2 O—MgCl 2 and ternary solutions H 2 O—MeOH—MgCl 2 were determined using an isochoric method in a stirred autoclave. Measurements were made at pressures of 3.5-9.5 MPa; MeOH concentrations, 0-25 mass%. The salt content in the aqueous solutions was constant at 5 mass%. The results showed that mixed samples containing MeOH and MgCl 2 gave the largest thermodynamic shifts of hydrate formation as compared to samples with MeOH at the same inhibitor mass fraction. The larger thermodynamic shift was related to synergism between the affects of MgCl 2 and MeOH in the aqueous solution.

AB - Mixtures of magnesium chloride and MeOH were studied as mixed thermodynamic inhibitors of hydrate formation. The equilibrium P,T-conditions for methane hydrate decomposition in the presence of binary solutions H 2 O—MeOH and H 2 O—MgCl 2 and ternary solutions H 2 O—MeOH—MgCl 2 were determined using an isochoric method in a stirred autoclave. Measurements were made at pressures of 3.5-9.5 MPa; MeOH concentrations, 0-25 mass%. The salt content in the aqueous solutions was constant at 5 mass%. The results showed that mixed samples containing MeOH and MgCl 2 gave the largest thermodynamic shifts of hydrate formation as compared to samples with MeOH at the same inhibitor mass fraction. The larger thermodynamic shift was related to synergism between the affects of MgCl 2 and MeOH in the aqueous solution.

KW - gas hydrates

KW - hydrate-formation inhibitors

KW - MeOH

KW - MgC1

UR - http://www.scopus.com/inward/record.url?scp=85064835731&partnerID=8YFLogxK

U2 - 10.1007/s10553-019-00981-2

DO - 10.1007/s10553-019-00981-2

M3 - Article

AN - SCOPUS:85064835731

VL - 54

SP - 738

EP - 742

JO - Chemistry and Technology of Fuels and Oils

JF - Chemistry and Technology of Fuels and Oils

SN - 0009-3092

IS - 6

ER -

ID: 19629339