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Supramolecular interactions in the solid state. / Resnati, Giuseppe; Boldyreva, Elena; Bombicz, Petra et al.

In: IUCrJ, Vol. 2, 2015, p. 675-690.

Research output: Contribution to journalArticlepeer-review

Harvard

Resnati, G, Boldyreva, E, Bombicz, P & Kawano, M 2015, 'Supramolecular interactions in the solid state', IUCrJ, vol. 2, pp. 675-690. https://doi.org/10.1107/S2052252515014608

APA

Resnati, G., Boldyreva, E., Bombicz, P., & Kawano, M. (2015). Supramolecular interactions in the solid state. IUCrJ, 2, 675-690. https://doi.org/10.1107/S2052252515014608

Vancouver

Resnati G, Boldyreva E, Bombicz P, Kawano M. Supramolecular interactions in the solid state. IUCrJ. 2015;2:675-690. doi: 10.1107/S2052252515014608

Author

Resnati, Giuseppe ; Boldyreva, Elena ; Bombicz, Petra et al. / Supramolecular interactions in the solid state. In: IUCrJ. 2015 ; Vol. 2. pp. 675-690.

BibTeX

@article{c507817683b44d86ad1ed2015412f932,
title = "Supramolecular interactions in the solid state",
abstract = "In the last few decades, supramolecular chemistry has been at the forefront of chemical research, with the aim of understanding chemistry beyond the covalent bond. Since the long-range periodicity in crystals is a product of the directionally specific short-range intermolecular interactions that are responsible for molecular assembly, analysis of crystalline solids provides a primary means to investigate intermolecular interactions and recognition phenomena. This article discusses some areas of contemporary research involving supramolecular interactions in the solid state. The topics covered are: (1) an overview and historical review of halogen bonding; (2) exploring non-ambient conditions to investigate intermolecular interactions in crystals; (3) the role of intermolecular interactions in morphotropy, being the link between isostructurality and polymorphism; (4) strategic realisation of kinetic coordination polymers by exploiting multi-interactive linker molecules. The discussion touches upon many of the prerequisites for controlled preparation and characterization of crystalline materials.",
keywords = "coordination polymers, crystal engineering, halogen bonding, intermolecular interactions, kinetic assembly, non-ambient conditions, phase transitions, polymorphism, self-assembly",
author = "Giuseppe Resnati and Elena Boldyreva and Petra Bombicz and Masaki Kawano",
year = "2015",
doi = "10.1107/S2052252515014608",
language = "English",
volume = "2",
pages = "675--690",
journal = "IUCrJ",
issn = "2052-2525",
publisher = "International Union of Crystallography",

}

RIS

TY - JOUR

T1 - Supramolecular interactions in the solid state

AU - Resnati, Giuseppe

AU - Boldyreva, Elena

AU - Bombicz, Petra

AU - Kawano, Masaki

PY - 2015

Y1 - 2015

N2 - In the last few decades, supramolecular chemistry has been at the forefront of chemical research, with the aim of understanding chemistry beyond the covalent bond. Since the long-range periodicity in crystals is a product of the directionally specific short-range intermolecular interactions that are responsible for molecular assembly, analysis of crystalline solids provides a primary means to investigate intermolecular interactions and recognition phenomena. This article discusses some areas of contemporary research involving supramolecular interactions in the solid state. The topics covered are: (1) an overview and historical review of halogen bonding; (2) exploring non-ambient conditions to investigate intermolecular interactions in crystals; (3) the role of intermolecular interactions in morphotropy, being the link between isostructurality and polymorphism; (4) strategic realisation of kinetic coordination polymers by exploiting multi-interactive linker molecules. The discussion touches upon many of the prerequisites for controlled preparation and characterization of crystalline materials.

AB - In the last few decades, supramolecular chemistry has been at the forefront of chemical research, with the aim of understanding chemistry beyond the covalent bond. Since the long-range periodicity in crystals is a product of the directionally specific short-range intermolecular interactions that are responsible for molecular assembly, analysis of crystalline solids provides a primary means to investigate intermolecular interactions and recognition phenomena. This article discusses some areas of contemporary research involving supramolecular interactions in the solid state. The topics covered are: (1) an overview and historical review of halogen bonding; (2) exploring non-ambient conditions to investigate intermolecular interactions in crystals; (3) the role of intermolecular interactions in morphotropy, being the link between isostructurality and polymorphism; (4) strategic realisation of kinetic coordination polymers by exploiting multi-interactive linker molecules. The discussion touches upon many of the prerequisites for controlled preparation and characterization of crystalline materials.

KW - coordination polymers

KW - crystal engineering

KW - halogen bonding

KW - intermolecular interactions

KW - kinetic assembly

KW - non-ambient conditions

KW - phase transitions

KW - polymorphism

KW - self-assembly

UR - http://www.scopus.com/inward/record.url?scp=84946732334&partnerID=8YFLogxK

U2 - 10.1107/S2052252515014608

DO - 10.1107/S2052252515014608

M3 - Article

AN - SCOPUS:84946732334

VL - 2

SP - 675

EP - 690

JO - IUCrJ

JF - IUCrJ

SN - 2052-2525

ER -

ID: 25462413