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Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies. / Radiush, Ekaterina A.; Sinelnikov, Gleb O.; Shurikov, Matvey K. et al.

In: CrystEngComm, Vol. 27, No. 48, 24.10.2025.

Research output: Contribution to journal › Article › peer-review

Harvard

Radiush, EA, Sinelnikov, GO, Shurikov, MK, Shamshurin, MV, Semenov, NA, Postnikov, PS, Sokolov, MN & Abramov, PA 2025, 'Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies', CrystEngComm, vol. 27, no. 48. https://doi.org/10.1039/d5ce00829h

APA

Radiush, E. A., Sinelnikov, G. O., Shurikov, M. K., Shamshurin, M. V., Semenov, N. A., Postnikov, P. S., Sokolov, M. N., & Abramov, P. A. (2025). Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies. CrystEngComm, 27(48). https://doi.org/10.1039/d5ce00829h

Vancouver

Radiush EA, Sinelnikov GO, Shurikov MK, Shamshurin MV, Semenov NA, Postnikov PS et al. Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies. CrystEngComm. 2025 Oct 24;27(48). doi: 10.1039/d5ce00829h

Author

Radiush, Ekaterina A. ; Sinelnikov, Gleb O. ; Shurikov, Matvey K. et al. / Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies. In: CrystEngComm. 2025 ; Vol. 27, No. 48.

BibTeX

@article{5c5ca3eb39294b00a21eae2d5650ce56,
title = "Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies",
abstract = "Silver nitrate reacts with pyridines leading to complexes of different stoichiometry. These compounds feature: i) polymorphism, ii) ligands loss and iii) supramolecular association. Dissolution of AgNO 3 in liquid pyridines (py-R) results in formation of [Ag(py-R) n ](NO 3 ) ( n = 2, 3) complexes of different nature. Six complexes with py-R = pyridine (py), 2-methylpyridine (2-Mepy), 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy), 3,5-dimethylpyridine (3,5-Me 2 py), and 3-bromopyridine (3-Brpy) have been prepared and characterized by single crystal X-ray diffraction (SCXRD). The diffraction experiments were performed for i) crystals directly isolated from the mother liquor and ii) crystals of bulk samples stored after air-drying. The collected data show polymorphism or pyridine loss from [Ag(py-R) 3 ](NO 3 ) during the storage of bulk samples. The energies of Ag–N bonding inside the ionic pairs have been estimated by quantum-chemical calculations. ",
author = "Radiush, {Ekaterina A.} and Sinelnikov, {Gleb O.} and Shurikov, {Matvey K.} and Shamshurin, {Maxim V.} and Semenov, {Nikolay A.} and Postnikov, {Pavel S.} and Sokolov, {Maxim N.} and Abramov, {Pavel A.}",
year = "2025",
month = oct,
day = "24",
doi = "10.1039/d5ce00829h",
language = "English",
volume = "27",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "48",

}

RIS

TY - JOUR

T1 - Substituent effects on the structure of [Ag(py-R)n](NO3) ionic pairs: structural and computational studies

AU - Radiush, Ekaterina A.

AU - Sinelnikov, Gleb O.

AU - Shurikov, Matvey K.

AU - Shamshurin, Maxim V.

AU - Semenov, Nikolay A.

AU - Postnikov, Pavel S.

AU - Sokolov, Maxim N.

AU - Abramov, Pavel A.

PY - 2025/10/24

Y1 - 2025/10/24

N2 - Silver nitrate reacts with pyridines leading to complexes of different stoichiometry. These compounds feature: i) polymorphism, ii) ligands loss and iii) supramolecular association. Dissolution of AgNO 3 in liquid pyridines (py-R) results in formation of [Ag(py-R) n ](NO 3 ) ( n = 2, 3) complexes of different nature. Six complexes with py-R = pyridine (py), 2-methylpyridine (2-Mepy), 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy), 3,5-dimethylpyridine (3,5-Me 2 py), and 3-bromopyridine (3-Brpy) have been prepared and characterized by single crystal X-ray diffraction (SCXRD). The diffraction experiments were performed for i) crystals directly isolated from the mother liquor and ii) crystals of bulk samples stored after air-drying. The collected data show polymorphism or pyridine loss from [Ag(py-R) 3 ](NO 3 ) during the storage of bulk samples. The energies of Ag–N bonding inside the ionic pairs have been estimated by quantum-chemical calculations.

AB - Silver nitrate reacts with pyridines leading to complexes of different stoichiometry. These compounds feature: i) polymorphism, ii) ligands loss and iii) supramolecular association. Dissolution of AgNO 3 in liquid pyridines (py-R) results in formation of [Ag(py-R) n ](NO 3 ) ( n = 2, 3) complexes of different nature. Six complexes with py-R = pyridine (py), 2-methylpyridine (2-Mepy), 3-methylpyridine (3-Mepy), 4-methylpyridine (4-Mepy), 3,5-dimethylpyridine (3,5-Me 2 py), and 3-bromopyridine (3-Brpy) have been prepared and characterized by single crystal X-ray diffraction (SCXRD). The diffraction experiments were performed for i) crystals directly isolated from the mother liquor and ii) crystals of bulk samples stored after air-drying. The collected data show polymorphism or pyridine loss from [Ag(py-R) 3 ](NO 3 ) during the storage of bulk samples. The energies of Ag–N bonding inside the ionic pairs have been estimated by quantum-chemical calculations.

UR - https://www.scopus.com/pages/publications/105024705754

UR - https://www.mendeley.com/catalogue/86af2b86-ecf4-35bf-adea-e9ddcb5938db/

U2 - 10.1039/d5ce00829h

DO - 10.1039/d5ce00829h

M3 - Article

VL - 27

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 48

ER -

ID: 72826116