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Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd). / Jamous, A. Y.; Kuznetsov, A. B.; Kokh, K. A. et al.

In: Journal of Alloys and Compounds, Vol. 905, 164162, 05.04.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Jamous, AY, Kuznetsov, AB, Kokh, KA, Svetlichnyi, VA, Kononova, NG, Shevchenko, VS, Ryadun, AA & Kokh, AE 2022, 'Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd)', Journal of Alloys and Compounds, vol. 905, 164162. https://doi.org/10.1016/j.jallcom.2022.164162

APA

Jamous, A. Y., Kuznetsov, A. B., Kokh, K. A., Svetlichnyi, V. A., Kononova, N. G., Shevchenko, V. S., Ryadun, A. A., & Kokh, A. E. (2022). Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd). Journal of Alloys and Compounds, 905, [164162]. https://doi.org/10.1016/j.jallcom.2022.164162

Vancouver

Jamous AY, Kuznetsov AB, Kokh KA, Svetlichnyi VA, Kononova NG, Shevchenko VS et al. Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd). Journal of Alloys and Compounds. 2022 Apr 5;905:164162. doi: 10.1016/j.jallcom.2022.164162

Author

Jamous, A. Y. ; Kuznetsov, A. B. ; Kokh, K. A. et al. / Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd). In: Journal of Alloys and Compounds. 2022 ; Vol. 905.

BibTeX

@article{15025e6f5f7a413e82e7cf3a788fc465,
title = "Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd)",
abstract = "RBO3 – ScBO3 diagrams (R = La, Pr and Nd) were investigated by the solid state synthesis and DSC methods. In these systems the solid solutions based on RSc3(BO3)4, RBO3 and ScBO3 were identified. The single crystals of RSc3(BO3)4 were grown by spontaneous crystallization method from LiBO2-LiF flux. The borates containing Pr and Nd have typical luminescence in the red/IR range which correlated to Pr3+: 3P0 → 3H6, 1D2 → 3H4 (~ 620 nm), and 3P0 → 2F2, 1D2 → 3H5 (~ 655 nm) and Nd3+ electron transitions 4F3/2 → 4I9/2 (875 nm) and 4F3/2 → 4I11/2 (1055 nm). The luminescence intensity strongly depends on the concentration of the fluorophores. In addition the SHG efficiency (for radiation of Nd:YAG laser, 1064 nm) for grown PrSc3(BO3)4 crystals was found to be 1.85 times higher (deff) than for KDP revealing its high potential for various NLO applications.",
keywords = "Crystal growth, Luminescence, Nonlinear crystal, Rare earth borate, Second harmonic generation (SHG), Solid state synthesis",
author = "Jamous, {A. Y.} and Kuznetsov, {A. B.} and Kokh, {K. A.} and Svetlichnyi, {V. A.} and Kononova, {N. G.} and Shevchenko, {V. S.} and Ryadun, {A. A.} and Kokh, {A. E.}",
note = "Funding Information: The work was supported by Russian Foundation for basic research [No. 19–05–00198 ]; Ministry of Science and Higher Education of the Russian Federation [No. 121031700313-8 , state assignment of IGM SB RAS]; and Tomsk State University [Development Programme (Priority-2030)]. Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",
year = "2022",
month = apr,
day = "5",
doi = "10.1016/j.jallcom.2022.164162",
language = "English",
volume = "905",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Study of RBO3-ScBO3 phase diagrams and RSc3(BO3)4 orthoborates (R = La, Pr and Nd)

AU - Jamous, A. Y.

AU - Kuznetsov, A. B.

AU - Kokh, K. A.

AU - Svetlichnyi, V. A.

AU - Kononova, N. G.

AU - Shevchenko, V. S.

AU - Ryadun, A. A.

AU - Kokh, A. E.

N1 - Funding Information: The work was supported by Russian Foundation for basic research [No. 19–05–00198 ]; Ministry of Science and Higher Education of the Russian Federation [No. 121031700313-8 , state assignment of IGM SB RAS]; and Tomsk State University [Development Programme (Priority-2030)]. Publisher Copyright: © 2022 Elsevier B.V.

PY - 2022/4/5

Y1 - 2022/4/5

N2 - RBO3 – ScBO3 diagrams (R = La, Pr and Nd) were investigated by the solid state synthesis and DSC methods. In these systems the solid solutions based on RSc3(BO3)4, RBO3 and ScBO3 were identified. The single crystals of RSc3(BO3)4 were grown by spontaneous crystallization method from LiBO2-LiF flux. The borates containing Pr and Nd have typical luminescence in the red/IR range which correlated to Pr3+: 3P0 → 3H6, 1D2 → 3H4 (~ 620 nm), and 3P0 → 2F2, 1D2 → 3H5 (~ 655 nm) and Nd3+ electron transitions 4F3/2 → 4I9/2 (875 nm) and 4F3/2 → 4I11/2 (1055 nm). The luminescence intensity strongly depends on the concentration of the fluorophores. In addition the SHG efficiency (for radiation of Nd:YAG laser, 1064 nm) for grown PrSc3(BO3)4 crystals was found to be 1.85 times higher (deff) than for KDP revealing its high potential for various NLO applications.

AB - RBO3 – ScBO3 diagrams (R = La, Pr and Nd) were investigated by the solid state synthesis and DSC methods. In these systems the solid solutions based on RSc3(BO3)4, RBO3 and ScBO3 were identified. The single crystals of RSc3(BO3)4 were grown by spontaneous crystallization method from LiBO2-LiF flux. The borates containing Pr and Nd have typical luminescence in the red/IR range which correlated to Pr3+: 3P0 → 3H6, 1D2 → 3H4 (~ 620 nm), and 3P0 → 2F2, 1D2 → 3H5 (~ 655 nm) and Nd3+ electron transitions 4F3/2 → 4I9/2 (875 nm) and 4F3/2 → 4I11/2 (1055 nm). The luminescence intensity strongly depends on the concentration of the fluorophores. In addition the SHG efficiency (for radiation of Nd:YAG laser, 1064 nm) for grown PrSc3(BO3)4 crystals was found to be 1.85 times higher (deff) than for KDP revealing its high potential for various NLO applications.

KW - Crystal growth

KW - Luminescence

KW - Nonlinear crystal

KW - Rare earth borate

KW - Second harmonic generation (SHG)

KW - Solid state synthesis

UR - http://www.scopus.com/inward/record.url?scp=85124515505&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2022.164162

DO - 10.1016/j.jallcom.2022.164162

M3 - Article

AN - SCOPUS:85124515505

VL - 905

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

M1 - 164162

ER -

ID: 35538572