Standard

Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium. / Klyuchenko, Maxim; Kadirov, Pulat; Kuznetsova, Anastasiya et al.

19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY. ed. / JA Seijas; MPV Tato; SK Lin. MDPI AG, 2015.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review

Harvard

Klyuchenko, M, Kadirov, P, Kuznetsova, A & Potapov, A 2015, Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium. in JA Seijas, MPV Tato & SK Lin (eds), 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY. MDPI AG, 19th International Electronic Conference on Synthetic Organic Chemistry, 01.11.2015. https://doi.org/10.3390/ecsoc-19-a039

APA

Klyuchenko, M., Kadirov, P., Kuznetsova, A., & Potapov, A. (2015). Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium. In JA. Seijas, MPV. Tato, & SK. Lin (Eds.), 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY MDPI AG. https://doi.org/10.3390/ecsoc-19-a039

Vancouver

Klyuchenko M, Kadirov P, Kuznetsova A, Potapov A. Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium. In Seijas JA, Tato MPV, Lin SK, editors, 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY. MDPI AG. 2015 doi: 10.3390/ecsoc-19-a039

Author

Klyuchenko, Maxim ; Kadirov, Pulat ; Kuznetsova, Anastasiya et al. / Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium. 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY. editor / JA Seijas ; MPV Tato ; SK Lin. MDPI AG, 2015.

BibTeX

@inproceedings{09c83d91862749999415019f4151606a,
title = "Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium",
abstract = "Influence of reagent ratio on the composition of products of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium (potassium hydroxide - dimethyl sulfoxide) was investigated using GC/MS technique. It was found that nucleophilic substitution reaction is always accompanied by elimination reactions (dehydrobromination and debromination). In addition to 1,1,2,2-tetra(azol-1-yl)ethane, 1,1,2-tri(azol-1-yl)ethenes and 1,2-di(azol-1-yl)ethenes, as well as 1,2-di(azol-1-yl)-1-bromoethenes were detected. Reaction pathway that explains the formation of all major products was proposed.",
keywords = "imidazole, triazole, terabromoethane, superbasic medium, nucleophilic substitution, elimination, COMPLEXES, LIGANDS, DESIGN",
author = "Maxim Klyuchenko and Pulat Kadirov and Anastasiya Kuznetsova and Andrei Potapov",
year = "2015",
doi = "10.3390/ecsoc-19-a039",
language = "English",
editor = "JA Seijas and MPV Tato and SK Lin",
booktitle = "19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY",
publisher = "MDPI AG",
address = "Switzerland",
note = "19th International Electronic Conference on Synthetic Organic Chemistry ; Conference date: 01-11-2015 Through 30-11-2015",

}

RIS

TY - GEN

T1 - Study of product composition of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium

AU - Klyuchenko, Maxim

AU - Kadirov, Pulat

AU - Kuznetsova, Anastasiya

AU - Potapov, Andrei

PY - 2015

Y1 - 2015

N2 - Influence of reagent ratio on the composition of products of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium (potassium hydroxide - dimethyl sulfoxide) was investigated using GC/MS technique. It was found that nucleophilic substitution reaction is always accompanied by elimination reactions (dehydrobromination and debromination). In addition to 1,1,2,2-tetra(azol-1-yl)ethane, 1,1,2-tri(azol-1-yl)ethenes and 1,2-di(azol-1-yl)ethenes, as well as 1,2-di(azol-1-yl)-1-bromoethenes were detected. Reaction pathway that explains the formation of all major products was proposed.

AB - Influence of reagent ratio on the composition of products of the reaction between 1,1,2,2-tetrabromoethane and imidazole or 1,2,4-triazole in a superbasic medium (potassium hydroxide - dimethyl sulfoxide) was investigated using GC/MS technique. It was found that nucleophilic substitution reaction is always accompanied by elimination reactions (dehydrobromination and debromination). In addition to 1,1,2,2-tetra(azol-1-yl)ethane, 1,1,2-tri(azol-1-yl)ethenes and 1,2-di(azol-1-yl)ethenes, as well as 1,2-di(azol-1-yl)-1-bromoethenes were detected. Reaction pathway that explains the formation of all major products was proposed.

KW - imidazole

KW - triazole

KW - terabromoethane

KW - superbasic medium

KW - nucleophilic substitution

KW - elimination

KW - COMPLEXES

KW - LIGANDS

KW - DESIGN

U2 - 10.3390/ecsoc-19-a039

DO - 10.3390/ecsoc-19-a039

M3 - Conference contribution

BT - 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY

A2 - Seijas, JA

A2 - Tato, MPV

A2 - Lin, SK

PB - MDPI AG

T2 - 19th International Electronic Conference on Synthetic Organic Chemistry

Y2 - 1 November 2015 through 30 November 2015

ER -

ID: 25399078