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Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates. / Kuznetsov, Artem B.; Kokh, Konstantin A.; Kaneva, Eketerina V. et al.

In: Dalton Transactions, Vol. 50, No. 39, 21.10.2021, p. 13894-13901.

Research output: Contribution to journal › Article › peer-review

Harvard

Kuznetsov, AB, Kokh, KA, Kaneva, EV, Svetlichnyi, VA, Kononova, NG, Shevchenko, VS, Rashchenko, SV & Kokh, AE 2021, 'Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates', Dalton Transactions, vol. 50, no. 39, pp. 13894-13901. https://doi.org/10.1039/d1dt02477a

APA

Kuznetsov, A. B., Kokh, K. A., Kaneva, E. V., Svetlichnyi, V. A., Kononova, N. G., Shevchenko, V. S., Rashchenko, S. V., & Kokh, A. E. (2021). Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates. Dalton Transactions, 50(39), 13894-13901. https://doi.org/10.1039/d1dt02477a

Vancouver

Kuznetsov AB, Kokh KA, Kaneva EV, Svetlichnyi VA, Kononova NG, Shevchenko VS et al. Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates. Dalton Transactions. 2021 Oct 21;50(39):13894-13901. doi: 10.1039/d1dt02477a

Author

Kuznetsov, Artem B. ; Kokh, Konstantin A. ; Kaneva, Eketerina V. et al. / Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates. In: Dalton Transactions. 2021 ; Vol. 50, No. 39. pp. 13894-13901.

BibTeX

@article{57a1fcf1852449b891aa3c1b3e0c0927,
title = "Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates",
abstract = "The EuBO3-ScBO3system was investigated by solid state synthesis and DSC methods. In this system, a new EuSc(BO3)2compound was found. It crystallizes in theR{\=3} space group with unit cell parameters ofa= 4.8939(1) {\AA} andc= 16.2663(5) {\AA}. Whereas another compound in the system EuSc3(BO3)4possesses two modifications: a low-temperature α-C2/c(a= 7.687(1) {\AA},b= 9.810(2) {\AA},c= 12.021(2) {\AA}, andβ= 105.379(4)°) and a high-temperature β-R32 (a= 9.7473(1) {\AA} andc= 7.9205(2) {\AA}). The α-EuSc3(BO3)4crystal was grown with LiBO2-LiF flux, and β-EuSc3(BO3)4was obtained by the solid state synthesis. All of the obtained crystals exhibited typical Eu3+luminescence spectra with peaks at 589 nm, 596 nm, 615 nm, 657 nm and 689 nm, which corresponded to the5D0→7FJ(J= 0, 1, 2 and 4) electron transitions. The strongest peak of luminescence was located at 615 nm and corresponded to the5D0→7F0transition.",
author = "Kuznetsov, {Artem B.} and Kokh, {Konstantin A.} and Kaneva, {Eketerina V.} and Svetlichnyi, {Valery A.} and Kononova, {Nadezda G.} and Shevchenko, {Vyacheslav S.} and Rashchenko, {Sergey V.} and Kokh, {Alexander E.}",
note = "Funding Information: The work was supported by Russian Foundation for basic research: projects # 19-33-90012 and 19-05-00198 and state assignment of IGM SB RAS. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",
year = "2021",
month = oct,
day = "21",
doi = "10.1039/d1dt02477a",
language = "English",
volume = "50",
pages = "13894--13901",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "39",

}

RIS

TY - JOUR

T1 - Study of an EuBO3-ScBO3system and EuSc3(BO3)4, EuSc(BO3)2orthoborates

AU - Kuznetsov, Artem B.

AU - Kokh, Konstantin A.

AU - Kaneva, Eketerina V.

AU - Svetlichnyi, Valery A.

AU - Kononova, Nadezda G.

AU - Shevchenko, Vyacheslav S.

AU - Rashchenko, Sergey V.

AU - Kokh, Alexander E.

N1 - Funding Information: The work was supported by Russian Foundation for basic research: projects # 19-33-90012 and 19-05-00198 and state assignment of IGM SB RAS. Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/10/21

Y1 - 2021/10/21

N2 - The EuBO3-ScBO3system was investigated by solid state synthesis and DSC methods. In this system, a new EuSc(BO3)2compound was found. It crystallizes in theR3̄ space group with unit cell parameters ofa= 4.8939(1) Å andc= 16.2663(5) Å. Whereas another compound in the system EuSc3(BO3)4possesses two modifications: a low-temperature α-C2/c(a= 7.687(1) Å,b= 9.810(2) Å,c= 12.021(2) Å, andβ= 105.379(4)°) and a high-temperature β-R32 (a= 9.7473(1) Å andc= 7.9205(2) Å). The α-EuSc3(BO3)4crystal was grown with LiBO2-LiF flux, and β-EuSc3(BO3)4was obtained by the solid state synthesis. All of the obtained crystals exhibited typical Eu3+luminescence spectra with peaks at 589 nm, 596 nm, 615 nm, 657 nm and 689 nm, which corresponded to the5D0→7FJ(J= 0, 1, 2 and 4) electron transitions. The strongest peak of luminescence was located at 615 nm and corresponded to the5D0→7F0transition.

AB - The EuBO3-ScBO3system was investigated by solid state synthesis and DSC methods. In this system, a new EuSc(BO3)2compound was found. It crystallizes in theR3̄ space group with unit cell parameters ofa= 4.8939(1) Å andc= 16.2663(5) Å. Whereas another compound in the system EuSc3(BO3)4possesses two modifications: a low-temperature α-C2/c(a= 7.687(1) Å,b= 9.810(2) Å,c= 12.021(2) Å, andβ= 105.379(4)°) and a high-temperature β-R32 (a= 9.7473(1) Å andc= 7.9205(2) Å). The α-EuSc3(BO3)4crystal was grown with LiBO2-LiF flux, and β-EuSc3(BO3)4was obtained by the solid state synthesis. All of the obtained crystals exhibited typical Eu3+luminescence spectra with peaks at 589 nm, 596 nm, 615 nm, 657 nm and 689 nm, which corresponded to the5D0→7FJ(J= 0, 1, 2 and 4) electron transitions. The strongest peak of luminescence was located at 615 nm and corresponded to the5D0→7F0transition.

UR - http://www.scopus.com/inward/record.url?scp=85117083253&partnerID=8YFLogxK

U2 - 10.1039/d1dt02477a

DO - 10.1039/d1dt02477a

M3 - Article

C2 - 34528048

AN - SCOPUS:85117083253

VL - 50

SP - 13894

EP - 13901

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 39

ER -

ID: 34463102