Research output: Contribution to journal › Article › peer-review
Studies on Thermodynamic Properties of FOX-7 and Its Five Closed-Loop Derivatives. / Muravyev, Nikita V.; Pivkina, Alla N.; Kiselev, Vitaly G.
In: Journal of Chemical and Engineering Data, Vol. 60, No. 7, 09.07.2015, p. 2057-2061.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Studies on Thermodynamic Properties of FOX-7 and Its Five Closed-Loop Derivatives
AU - Muravyev, Nikita V.
AU - Pivkina, Alla N.
AU - Kiselev, Vitaly G.
PY - 2015/7/9
Y1 - 2015/7/9
N2 - Combustion heats of FOX-7 and its five closed-loop derivatives were determined and the standard molar enthalpies of formation (δfH°m) were obtained. The sequence of combustion heat for the six compounds is DNDH > MDNZ > DNDX > DNDZ > DDNI > FOX-7. Combustion heat tends to rise with the increase of the number of C atoms in the molecule. Specific heat capacities were measured, and the standard molar heat capacities of the six compounds are (176.59, 205.41, 207.76, 218.89, 217.76, and 215.40) J·mol-1·K-1, respectively. The specific heat capacity presents an opposite change rule with combustion heat. To the isomers and the introduction of hydroxyl group, the change rule is the same. Moreover, the introduction of hydroxyl group can markedly decrease the combustion heat and specific heat capacity.
AB - Combustion heats of FOX-7 and its five closed-loop derivatives were determined and the standard molar enthalpies of formation (δfH°m) were obtained. The sequence of combustion heat for the six compounds is DNDH > MDNZ > DNDX > DNDZ > DDNI > FOX-7. Combustion heat tends to rise with the increase of the number of C atoms in the molecule. Specific heat capacities were measured, and the standard molar heat capacities of the six compounds are (176.59, 205.41, 207.76, 218.89, 217.76, and 215.40) J·mol-1·K-1, respectively. The specific heat capacity presents an opposite change rule with combustion heat. To the isomers and the introduction of hydroxyl group, the change rule is the same. Moreover, the introduction of hydroxyl group can markedly decrease the combustion heat and specific heat capacity.
KW - THERMOLYSIS
UR - http://www.scopus.com/inward/record.url?scp=85015944013&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.5b00021
DO - 10.1021/acs.jced.5b00021
M3 - Article
AN - SCOPUS:85015944013
VL - 60
SP - 2057
EP - 2061
JO - Journal of Chemical & Engineering Data
JF - Journal of Chemical & Engineering Data
SN - 0021-9568
IS - 7
ER -
ID: 8673156