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Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates. / Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A.

In: Journal of Structural Chemistry, Vol. 59, No. 7, 01.12.2018, p. 1648-1652.

Research output: Contribution to journal › Article › peer-review

Harvard

Borisov, SV, Pervukhina, NV & Magarill, SA 2018, 'Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates', Journal of Structural Chemistry, vol. 59, no. 7, pp. 1648-1652. https://doi.org/10.1134/S002247661807017X

APA

Borisov, S. V., Pervukhina, N. V., & Magarill, S. A. (2018). Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates. Journal of Structural Chemistry, 59(7), 1648-1652. https://doi.org/10.1134/S002247661807017X

Vancouver

Borisov SV, Pervukhina NV, Magarill SA. Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates. Journal of Structural Chemistry. 2018 Dec 1;59(7):1648-1652. doi: 10.1134/S002247661807017X

Author

Borisov, S. V. ; Pervukhina, N. V. ; Magarill, S. A. / Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 7. pp. 1648-1652.

BibTeX

@article{323554c103e748ab982fa6a00674d708,
title = "Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates",
abstract = "The crystallographic analysis of the orthorhombic (Pnma) structure of Sr3B2SiO8 ≈ (Sr(B,Si)O2.67) shows that its experimentally found symmetry is determined by the geometry of the Sr sublattice where the anion radical without this symmetry simulates it by the statistical averaging of four variants of real configurations. With a reduced fraction of heavy atoms in the triclinic (Р1) structure of Ba3B6Si2O16, the Ba and Si cations whose sublattice determines the presence of additional pseudosymmetry form the skeleton of the structure.",
keywords = "borosilicates, cation sublattices, crystallographic analysis, crystallographic stoichiometry, pseudosymmetry, structure stability, CRYSTALLOGRAPHIC ANALYSIS",
author = "Borisov, {S. V.} and Pervukhina, {N. V.} and Magarill, {S. A.}",
year = "2018",
month = dec,
day = "1",
doi = "10.1134/S002247661807017X",
language = "English",
volume = "59",
pages = "1648--1652",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "7",

}

RIS

TY - JOUR

T1 - Structure-Forming Role of Heavy Cations in Sr3B2SiO8 (Sr(B,Si)O2.67) and Ba3B6Si2O16 Borosilicates

AU - Borisov, S. V.

AU - Pervukhina, N. V.

AU - Magarill, S. A.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The crystallographic analysis of the orthorhombic (Pnma) structure of Sr3B2SiO8 ≈ (Sr(B,Si)O2.67) shows that its experimentally found symmetry is determined by the geometry of the Sr sublattice where the anion radical without this symmetry simulates it by the statistical averaging of four variants of real configurations. With a reduced fraction of heavy atoms in the triclinic (Р1) structure of Ba3B6Si2O16, the Ba and Si cations whose sublattice determines the presence of additional pseudosymmetry form the skeleton of the structure.

AB - The crystallographic analysis of the orthorhombic (Pnma) structure of Sr3B2SiO8 ≈ (Sr(B,Si)O2.67) shows that its experimentally found symmetry is determined by the geometry of the Sr sublattice where the anion radical without this symmetry simulates it by the statistical averaging of four variants of real configurations. With a reduced fraction of heavy atoms in the triclinic (Р1) structure of Ba3B6Si2O16, the Ba and Si cations whose sublattice determines the presence of additional pseudosymmetry form the skeleton of the structure.

KW - borosilicates

KW - cation sublattices

KW - crystallographic analysis

KW - crystallographic stoichiometry

KW - pseudosymmetry

KW - structure stability

KW - CRYSTALLOGRAPHIC ANALYSIS

UR - http://www.scopus.com/inward/record.url?scp=85058441334&partnerID=8YFLogxK

U2 - 10.1134/S002247661807017X

DO - 10.1134/S002247661807017X

M3 - Article

AN - SCOPUS:85058441334

VL - 59

SP - 1648

EP - 1652

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 17879048