Standard

Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning. / Rogozhnikov, V. N.; Potemkin, D. I.; Pakharukova, V. P. et al.

In: International Journal of Hydrogen Energy, Vol. 46, No. 72, 19.10.2021, p. 35853-35865.

Research output: Contribution to journal › Article › peer-review

Harvard

Rogozhnikov, VN, Potemkin, DI, Pakharukova, VP, Belyaev, VD, Nedolivko, VV, Glotov, AP, Sobyanin, VA & Snytnikov, PV 2021, 'Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning', International Journal of Hydrogen Energy, vol. 46, no. 72, pp. 35853-35865. https://doi.org/10.1016/j.ijhydene.2021.03.164

APA

Rogozhnikov, V. N., Potemkin, D. I., Pakharukova, V. P., Belyaev, V. D., Nedolivko, V. V., Glotov, A. P., Sobyanin, V. A., & Snytnikov, P. V. (2021). Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning. International Journal of Hydrogen Energy, 46(72), 35853-35865. https://doi.org/10.1016/j.ijhydene.2021.03.164

Vancouver

Rogozhnikov VN, Potemkin DI, Pakharukova VP, Belyaev VD, Nedolivko VV, Glotov AP et al. Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning. International Journal of Hydrogen Energy. 2021 Oct 19;46(72):35853-35865. Epub 2021 Apr 16. doi: 10.1016/j.ijhydene.2021.03.164

Author

Rogozhnikov, V. N. ; Potemkin, D. I. ; Pakharukova, V. P. et al. / Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning. In: International Journal of Hydrogen Energy. 2021 ; Vol. 46, No. 72. pp. 35853-35865.

BibTeX

@article{162fbb279f6c49269330e6cdab39a4f6,
title = "Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning",
abstract = "A number of mixed oxide Ce0.75Zr0.25O2 supports were prepared, tested for reproducibility, and characterized by physicochemical methods. The most reproducible preparation method was adapted for depositing the mixed oxide on a FeCrAlloy mesh substrate coated by a protective alumina layer. Based on the obtained structured Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl support, the Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl and Pt/Ce0.75Zr0.25O2/Al2O3/FeCrAl catalysts were prepared and tested in the reactions of partial oxidation of LPG and deep oxidation of anode gases, respectively. Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl provided complete conversion of LPG into synthesis gas of a composition close to the equilibrium one. Pt/Ce0.75Zr0.25O2/Al2O3/FeCrAl provided complete conversion of all components of the anode gases at GHSV = 20,000–40,000 h−1; however, at higher GHSV values, methane conversion decreased. The studies on the effect of methane content on deep oxidation of anode off gases showed that methane conversion began to decrease at a 1.5-fold excess of methane and dropped to 50% at a 10-fold excess of methane.",
keywords = "Anode gases, Oxidation, Preparation, Structured catalysts, Synthesis gas",
author = "Rogozhnikov, {V. N.} and Potemkin, {D. I.} and Pakharukova, {V. P.} and Belyaev, {V. D.} and Nedolivko, {V. V.} and Glotov, {A. P.} and Sobyanin, {V. A.} and Snytnikov, {P. V.}",
note = "Funding Information: This work (in the part of samples characterization) was partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011390009-1 ). Dr. V.N. Rogozhnikov acknowledge Russian Foundation for Basic Research (Project № 19-33-60057 «Perspektiva») for the financial support (in the part of samples synthesis and catalytic experiments). Publisher Copyright: {\textcopyright} 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = oct,
day = "19",
doi = "10.1016/j.ijhydene.2021.03.164",
language = "English",
volume = "46",
pages = "35853--35865",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
number = "72",

}

RIS

TY - JOUR

T1 - Structured catalysts for the conversion of liquefied petroleum gas to hydrogen-rich gas and for anode off-gas afterburning

AU - Rogozhnikov, V. N.

AU - Potemkin, D. I.

AU - Pakharukova, V. P.

AU - Belyaev, V. D.

AU - Nedolivko, V. V.

AU - Glotov, A. P.

AU - Sobyanin, V. A.

AU - Snytnikov, P. V.

N1 - Funding Information: This work (in the part of samples characterization) was partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011390009-1 ). Dr. V.N. Rogozhnikov acknowledge Russian Foundation for Basic Research (Project № 19-33-60057 «Perspektiva») for the financial support (in the part of samples synthesis and catalytic experiments). Publisher Copyright: © 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/10/19

Y1 - 2021/10/19

N2 - A number of mixed oxide Ce0.75Zr0.25O2 supports were prepared, tested for reproducibility, and characterized by physicochemical methods. The most reproducible preparation method was adapted for depositing the mixed oxide on a FeCrAlloy mesh substrate coated by a protective alumina layer. Based on the obtained structured Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl support, the Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl and Pt/Ce0.75Zr0.25O2/Al2O3/FeCrAl catalysts were prepared and tested in the reactions of partial oxidation of LPG and deep oxidation of anode gases, respectively. Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl provided complete conversion of LPG into synthesis gas of a composition close to the equilibrium one. Pt/Ce0.75Zr0.25O2/Al2O3/FeCrAl provided complete conversion of all components of the anode gases at GHSV = 20,000–40,000 h−1; however, at higher GHSV values, methane conversion decreased. The studies on the effect of methane content on deep oxidation of anode off gases showed that methane conversion began to decrease at a 1.5-fold excess of methane and dropped to 50% at a 10-fold excess of methane.

AB - A number of mixed oxide Ce0.75Zr0.25O2 supports were prepared, tested for reproducibility, and characterized by physicochemical methods. The most reproducible preparation method was adapted for depositing the mixed oxide on a FeCrAlloy mesh substrate coated by a protective alumina layer. Based on the obtained structured Ce0.75Zr0.25O2/θ-Al2O3/FeCrAl support, the Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl and Pt/Ce0.75Zr0.25O2/Al2O3/FeCrAl catalysts were prepared and tested in the reactions of partial oxidation of LPG and deep oxidation of anode gases, respectively. Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl provided complete conversion of LPG into synthesis gas of a composition close to the equilibrium one. Pt/Ce0.75Zr0.25O2/Al2O3/FeCrAl provided complete conversion of all components of the anode gases at GHSV = 20,000–40,000 h−1; however, at higher GHSV values, methane conversion decreased. The studies on the effect of methane content on deep oxidation of anode off gases showed that methane conversion began to decrease at a 1.5-fold excess of methane and dropped to 50% at a 10-fold excess of methane.

KW - Anode gases

KW - Oxidation

KW - Preparation

KW - Structured catalysts

KW - Synthesis gas

UR - http://www.scopus.com/inward/record.url?scp=85104594177&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2021.03.164

DO - 10.1016/j.ijhydene.2021.03.164

M3 - Article

AN - SCOPUS:85104594177

VL - 46

SP - 35853

EP - 35865

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 72

ER -

ID: 28464741