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Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates : Design and performance. / Sadykov, V.; Mezentseva, N.; Fedorova, Yu et al.

In: Catalysis Today, Vol. 251, 01.08.2015, p. 19-27.

Research output: Contribution to journalArticlepeer-review

Harvard

Sadykov, V, Mezentseva, N, Fedorova, Y, Lukashevich, A, Pelipenko, V, Kuzmin, V, Simonov, M, Ishchenko, A, Vostrikov, Z, Bobrova, L, Sadovskaya, E, Muzykantov, V, Zadesenets, A, Smorygo, O, Roger, AC & Parkhomenko, K 2015, 'Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates: Design and performance', Catalysis Today, vol. 251, pp. 19-27. https://doi.org/10.1016/j.cattod.2014.10.045

APA

Sadykov, V., Mezentseva, N., Fedorova, Y., Lukashevich, A., Pelipenko, V., Kuzmin, V., Simonov, M., Ishchenko, A., Vostrikov, Z., Bobrova, L., Sadovskaya, E., Muzykantov, V., Zadesenets, A., Smorygo, O., Roger, A. C., & Parkhomenko, K. (2015). Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates: Design and performance. Catalysis Today, 251, 19-27. https://doi.org/10.1016/j.cattod.2014.10.045

Vancouver

Sadykov V, Mezentseva N, Fedorova Y, Lukashevich A, Pelipenko V, Kuzmin V et al. Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates: Design and performance. Catalysis Today. 2015 Aug 1;251:19-27. doi: 10.1016/j.cattod.2014.10.045

Author

Sadykov, V. ; Mezentseva, N. ; Fedorova, Yu et al. / Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates : Design and performance. In: Catalysis Today. 2015 ; Vol. 251. pp. 19-27.

BibTeX

@article{0c827a325e4f4a0fa74835b9bf3c7c9d,
title = "Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates: Design and performance",
abstract = "Catalysts for biofuels reforming based on two types of nanocomposite active components (Ni + Ru/La0.8Pr0.2Mn0.2Cr0.8O3/Y0.08Zr0.92O2-δ, Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2) supported on microchannel substrates (Ni-Al alloy foam plates, Fechraloy plates protected by a thin corundum layer) were developed. Applied procedures for the active components loading on substrates provide thermochemical stability of supported layers of active components in tough operation conditions not affecting their reactivity/catalytic activity. Effects of the nature of nanocomposite active component, type of fuel (ethanol, ethyl acetate, acetone and glycerol), feed composition and contact time on the yield of syngas/byproducts and performance stability are considered and compared with results of calculations of the equilibrium composition of reaction mixtures. For nanocomposite active components with a high oxygen mobility and reactivity, reforming of such typical fuel as ethanol is described by the step-wise red-ox mechanism. Preliminary results of the mathematical modelling of the ethanol steam reforming on a stack of microchannel Fechraloy plates loaded with Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2 active component revealed that this process can be satisfactorily described by the isothermal model without any impact of the heat/mass transfer.",
keywords = "Biofuels reforming, Catalytic performance, Microchannel and foam substrates, Perovskite-like and fluorite-like oxide supports, Ru-Ni alloy nanoparticles, Structured catalysts",
author = "V. Sadykov and N. Mezentseva and Yu Fedorova and A. Lukashevich and V. Pelipenko and V. Kuzmin and M. Simonov and A. Ishchenko and Z. Vostrikov and L. Bobrova and E. Sadovskaya and V. Muzykantov and A. Zadesenets and O. Smorygo and Roger, {A. C.} and K. Parkhomenko",
year = "2015",
month = aug,
day = "1",
doi = "10.1016/j.cattod.2014.10.045",
language = "English",
volume = "251",
pages = "19--27",
journal = "Catalysis Today",
issn = "0920-5861",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Structured catalysts for steam/autothermal reforming of biofuels on heat-conducting substrates

T2 - Design and performance

AU - Sadykov, V.

AU - Mezentseva, N.

AU - Fedorova, Yu

AU - Lukashevich, A.

AU - Pelipenko, V.

AU - Kuzmin, V.

AU - Simonov, M.

AU - Ishchenko, A.

AU - Vostrikov, Z.

AU - Bobrova, L.

AU - Sadovskaya, E.

AU - Muzykantov, V.

AU - Zadesenets, A.

AU - Smorygo, O.

AU - Roger, A. C.

AU - Parkhomenko, K.

PY - 2015/8/1

Y1 - 2015/8/1

N2 - Catalysts for biofuels reforming based on two types of nanocomposite active components (Ni + Ru/La0.8Pr0.2Mn0.2Cr0.8O3/Y0.08Zr0.92O2-δ, Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2) supported on microchannel substrates (Ni-Al alloy foam plates, Fechraloy plates protected by a thin corundum layer) were developed. Applied procedures for the active components loading on substrates provide thermochemical stability of supported layers of active components in tough operation conditions not affecting their reactivity/catalytic activity. Effects of the nature of nanocomposite active component, type of fuel (ethanol, ethyl acetate, acetone and glycerol), feed composition and contact time on the yield of syngas/byproducts and performance stability are considered and compared with results of calculations of the equilibrium composition of reaction mixtures. For nanocomposite active components with a high oxygen mobility and reactivity, reforming of such typical fuel as ethanol is described by the step-wise red-ox mechanism. Preliminary results of the mathematical modelling of the ethanol steam reforming on a stack of microchannel Fechraloy plates loaded with Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2 active component revealed that this process can be satisfactorily described by the isothermal model without any impact of the heat/mass transfer.

AB - Catalysts for biofuels reforming based on two types of nanocomposite active components (Ni + Ru/La0.8Pr0.2Mn0.2Cr0.8O3/Y0.08Zr0.92O2-δ, Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2) supported on microchannel substrates (Ni-Al alloy foam plates, Fechraloy plates protected by a thin corundum layer) were developed. Applied procedures for the active components loading on substrates provide thermochemical stability of supported layers of active components in tough operation conditions not affecting their reactivity/catalytic activity. Effects of the nature of nanocomposite active component, type of fuel (ethanol, ethyl acetate, acetone and glycerol), feed composition and contact time on the yield of syngas/byproducts and performance stability are considered and compared with results of calculations of the equilibrium composition of reaction mixtures. For nanocomposite active components with a high oxygen mobility and reactivity, reforming of such typical fuel as ethanol is described by the step-wise red-ox mechanism. Preliminary results of the mathematical modelling of the ethanol steam reforming on a stack of microchannel Fechraloy plates loaded with Ni + Ru/Sm0.15Pr0.15Ce0.35Zr0.35O2 active component revealed that this process can be satisfactorily described by the isothermal model without any impact of the heat/mass transfer.

KW - Biofuels reforming

KW - Catalytic performance

KW - Microchannel and foam substrates

KW - Perovskite-like and fluorite-like oxide supports

KW - Ru-Ni alloy nanoparticles

KW - Structured catalysts

UR - http://www.scopus.com/inward/record.url?scp=84929121164&partnerID=8YFLogxK

U2 - 10.1016/j.cattod.2014.10.045

DO - 10.1016/j.cattod.2014.10.045

M3 - Article

AN - SCOPUS:84929121164

VL - 251

SP - 19

EP - 27

JO - Catalysis Today

JF - Catalysis Today

SN - 0920-5861

ER -

ID: 25396718