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Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand. / Romashev, N. F.; Mirzaeva, I. V.; Bakaev, I. V. et al.

In: Journal of Structural Chemistry, Vol. 63, No. 2, 5, 02.2022, p. 242-251.

Research output: Contribution to journal › Article › peer-review

Harvard

Romashev, NF, Mirzaeva, IV, Bakaev, IV, Komlyagina, VI, Komarov, VY, Fomenko, IS & Gushchin, AL 2022, 'Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand', Journal of Structural Chemistry, vol. 63, no. 2, 5, pp. 242-251. https://doi.org/10.1134/S0022476622020056

APA

Romashev, N. F., Mirzaeva, I. V., Bakaev, I. V., Komlyagina, V. I., Komarov, V. Y., Fomenko, I. S., & Gushchin, A. L. (2022). Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand. Journal of Structural Chemistry, 63(2), 242-251. [5]. https://doi.org/10.1134/S0022476622020056

Vancouver

Romashev NF, Mirzaeva IV, Bakaev IV, Komlyagina VI, Komarov VY, Fomenko IS et al. Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand. Journal of Structural Chemistry. 2022 Feb;63(2):242-251. 5. doi: 10.1134/S0022476622020056

Author

Romashev, N. F. ; Mirzaeva, I. V. ; Bakaev, I. V. et al. / Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand. In: Journal of Structural Chemistry. 2022 ; Vol. 63, No. 2. pp. 242-251.

BibTeX

@article{02cd9cff033244558f2916441b91a2c5,
title = "Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand",
abstract = "By the interaction of [Rh2(COE)4(μ-Cl)2] (COE = cyclooctene) with 1,2-bis[(2,6-diisopropyl phenyl)imino]acenaphthene (dpp-bian) new binuclear complex [Rh2(dpp-bian)2(μ-Cl)2]·2.72CH2Cl2 is obtained. The crystal structure is determined by the single crystal X-ray diffraction analysis. Compound 1·2.72CH2Cl2 crystallizes in the orthorhombic crystal system (space group Pnma) with unit cell parameters a = 51.200(3) {\AA}, b = 22.3795(13) {\AA}, c = 12.8631(8) {\AA}, V = 14739.0(16) {\AA}3, R = 0.0536. Each rhodium atom has a distorted square-planar environment formed by two dpp-bian N atoms and two bridging Cl atoms. Density functional theory calculations predict the existence of two isomers of the [Rh2(dpp-bian)2(μ-Cl)2] complex with similar formation energies.",
keywords = "acenaphthene-1,2-diimine, binuclear complexes, DFT calculations, rhodium, X-ray crystallography",
author = "Romashev, {N. F.} and Mirzaeva, {I. V.} and Bakaev, {I. V.} and Komlyagina, {V. I.} and Komarov, {V. Yu} and Fomenko, {I. S.} and Gushchin, {A. L.}",
note = "Funding Information: The work was supported by RFBR and the Government of the Novosibirsk Oblast{\textquoteright}, project No. 19-43-543022. Funding Information: The authors acknowledge the support of the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8). Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",
year = "2022",
month = feb,
doi = "10.1134/S0022476622020056",
language = "English",
volume = "63",
pages = "242--251",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Structure of a binuclear rhodium(I) complex with the acenaphthene- 1,2-diimine ligand

AU - Romashev, N. F.

AU - Mirzaeva, I. V.

AU - Bakaev, I. V.

AU - Komlyagina, V. I.

AU - Komarov, V. Yu

AU - Fomenko, I. S.

AU - Gushchin, A. L.

N1 - Funding Information: The work was supported by RFBR and the Government of the Novosibirsk Oblast’, project No. 19-43-543022. Funding Information: The authors acknowledge the support of the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8). Publisher Copyright: © 2022, Pleiades Publishing, Ltd.

PY - 2022/2

Y1 - 2022/2

N2 - By the interaction of [Rh2(COE)4(μ-Cl)2] (COE = cyclooctene) with 1,2-bis[(2,6-diisopropyl phenyl)imino]acenaphthene (dpp-bian) new binuclear complex [Rh2(dpp-bian)2(μ-Cl)2]·2.72CH2Cl2 is obtained. The crystal structure is determined by the single crystal X-ray diffraction analysis. Compound 1·2.72CH2Cl2 crystallizes in the orthorhombic crystal system (space group Pnma) with unit cell parameters a = 51.200(3) Å, b = 22.3795(13) Å, c = 12.8631(8) Å, V = 14739.0(16) Å3, R = 0.0536. Each rhodium atom has a distorted square-planar environment formed by two dpp-bian N atoms and two bridging Cl atoms. Density functional theory calculations predict the existence of two isomers of the [Rh2(dpp-bian)2(μ-Cl)2] complex with similar formation energies.

AB - By the interaction of [Rh2(COE)4(μ-Cl)2] (COE = cyclooctene) with 1,2-bis[(2,6-diisopropyl phenyl)imino]acenaphthene (dpp-bian) new binuclear complex [Rh2(dpp-bian)2(μ-Cl)2]·2.72CH2Cl2 is obtained. The crystal structure is determined by the single crystal X-ray diffraction analysis. Compound 1·2.72CH2Cl2 crystallizes in the orthorhombic crystal system (space group Pnma) with unit cell parameters a = 51.200(3) Å, b = 22.3795(13) Å, c = 12.8631(8) Å, V = 14739.0(16) Å3, R = 0.0536. Each rhodium atom has a distorted square-planar environment formed by two dpp-bian N atoms and two bridging Cl atoms. Density functional theory calculations predict the existence of two isomers of the [Rh2(dpp-bian)2(μ-Cl)2] complex with similar formation energies.

KW - acenaphthene-1,2-diimine

KW - binuclear complexes

KW - DFT calculations

KW - rhodium

KW - X-ray crystallography

UR - http://www.scopus.com/inward/record.url?scp=85126203854&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/fa4d0142-f225-3b96-afe9-9f51f509ad86/

U2 - 10.1134/S0022476622020056

DO - 10.1134/S0022476622020056

M3 - Article

AN - SCOPUS:85126203854

VL - 63

SP - 242

EP - 251

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

M1 - 5

ER -

ID: 35690303