Standard

Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis. / Chaikina, M. V.; Bulina, N. V.; Prosanov, I. Yu et al.

In: Inorganic Materials, Vol. 56, No. 4, 01.04.2020, p. 402-408.

Research output: Contribution to journal › Article › peer-review

Harvard

Chaikina, MV, Bulina, NV, Prosanov, IY, Vinokurova, OB & Ishchenko, AV 2020, 'Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis', Inorganic Materials, vol. 56, no. 4, pp. 402-408. https://doi.org/10.1134/S0020168520040044

APA

Chaikina, M. V., Bulina, N. V., Prosanov, I. Y., Vinokurova, O. B., & Ishchenko, A. V. (2020). Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis. Inorganic Materials, 56(4), 402-408. https://doi.org/10.1134/S0020168520040044

Vancouver

Chaikina MV, Bulina NV, Prosanov IY, Vinokurova OB, Ishchenko AV. Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis. Inorganic Materials. 2020 Apr 1;56(4):402-408. doi: 10.1134/S0020168520040044

Author

Chaikina, M. V. ; Bulina, N. V. ; Prosanov, I. Yu et al. / Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis. In: Inorganic Materials. 2020 ; Vol. 56, No. 4. pp. 402-408.

BibTeX

@article{b2266284a8a9484993536c2fcd3600b7,
title = "Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis",
abstract = "Zinc-substituted hydroxyapatite samples with a preset degree of substitution (Са10 – хZnx(PO4)6(OH)2, x = 0.1–2.0) have been synthesized by a mechanochemical method. The composition of starting components ((Zn(H2PO4)2 ⋅ 2Н2О and ZnO) and water of crystallization have been shown to influence the apatite structure formation process and the degree of zinc substitution for calcium in the mechanochemical synthesis and annealing processes. When ZnO was used as a dopant, beta-tricalcium phosphate was observed to form as a reaction intermediate directly in the mill after 5–10 min of the reaction mixture milling and disappear after 20 min of milling. The final synthesis product—zinc-substituted hydroxyapatite—remains single-phase for x ≤ 0.8 in the case of Zn(H2PO4)2 ⋅ 2Н2О and x ≤ 0.25 in the case of ZnO. After annealing, the zinc-substituted hydroxyapatite is single-phase only in the case of zinc phosphate using at x ≤ 0.1.",
keywords = "hydroxyapatite, mechanochemical synthesis, zinc, CRYSTALLIZATION, INSERTION, MECHANISM, CRYSTAL-STRUCTURE, CALCIUM",
author = "Chaikina, {M. V.} and Bulina, {N. V.} and Prosanov, {I. Yu} and Vinokurova, {O. B.} and Ishchenko, {A. V.}",
year = "2020",
month = apr,
day = "1",
doi = "10.1134/S0020168520040044",
language = "English",
volume = "56",
pages = "402--408",
journal = "Inorganic Materials",
issn = "0020-1685",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Structure Formation of Zinc-Substituted Hydroxyapatite during Mechanochemical Synthesis

AU - Chaikina, M. V.

AU - Bulina, N. V.

AU - Prosanov, I. Yu

AU - Vinokurova, O. B.

AU - Ishchenko, A. V.

PY - 2020/4/1

Y1 - 2020/4/1

N2 - Zinc-substituted hydroxyapatite samples with a preset degree of substitution (Са10 – хZnx(PO4)6(OH)2, x = 0.1–2.0) have been synthesized by a mechanochemical method. The composition of starting components ((Zn(H2PO4)2 ⋅ 2Н2О and ZnO) and water of crystallization have been shown to influence the apatite structure formation process and the degree of zinc substitution for calcium in the mechanochemical synthesis and annealing processes. When ZnO was used as a dopant, beta-tricalcium phosphate was observed to form as a reaction intermediate directly in the mill after 5–10 min of the reaction mixture milling and disappear after 20 min of milling. The final synthesis product—zinc-substituted hydroxyapatite—remains single-phase for x ≤ 0.8 in the case of Zn(H2PO4)2 ⋅ 2Н2О and x ≤ 0.25 in the case of ZnO. After annealing, the zinc-substituted hydroxyapatite is single-phase only in the case of zinc phosphate using at x ≤ 0.1.

AB - Zinc-substituted hydroxyapatite samples with a preset degree of substitution (Са10 – хZnx(PO4)6(OH)2, x = 0.1–2.0) have been synthesized by a mechanochemical method. The composition of starting components ((Zn(H2PO4)2 ⋅ 2Н2О and ZnO) and water of crystallization have been shown to influence the apatite structure formation process and the degree of zinc substitution for calcium in the mechanochemical synthesis and annealing processes. When ZnO was used as a dopant, beta-tricalcium phosphate was observed to form as a reaction intermediate directly in the mill after 5–10 min of the reaction mixture milling and disappear after 20 min of milling. The final synthesis product—zinc-substituted hydroxyapatite—remains single-phase for x ≤ 0.8 in the case of Zn(H2PO4)2 ⋅ 2Н2О and x ≤ 0.25 in the case of ZnO. After annealing, the zinc-substituted hydroxyapatite is single-phase only in the case of zinc phosphate using at x ≤ 0.1.

KW - hydroxyapatite

KW - mechanochemical synthesis

KW - zinc

KW - CRYSTALLIZATION

KW - INSERTION

KW - MECHANISM

KW - CRYSTAL-STRUCTURE

KW - CALCIUM

UR - http://www.scopus.com/inward/record.url?scp=85084005649&partnerID=8YFLogxK

U2 - 10.1134/S0020168520040044

DO - 10.1134/S0020168520040044

M3 - Article

AN - SCOPUS:85084005649

VL - 56

SP - 402

EP - 408

JO - Inorganic Materials

JF - Inorganic Materials

SN - 0020-1685

IS - 4

ER -

ID: 24230389