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Structure and Properties of Ni(II) Complexes with Heptanedione-3.5. / Zhezhera, M.; Kochelakov, D. V.; Stabnikov, P. A. et al.

In: Journal of Structural Chemistry, Vol. 65, No. 12, 12.2024, p. 2406-2419.

Research output: Contribution to journal › Article › peer-review

Harvard

Zhezhera, M, Kochelakov, DV, Stabnikov, PA & Vikulova, ES 2024, 'Structure and Properties of Ni(II) Complexes with Heptanedione-3.5', Journal of Structural Chemistry, vol. 65, no. 12, pp. 2406-2419. https://doi.org/10.1134/S0022476624120059

APA

Zhezhera, M., Kochelakov, D. V., Stabnikov, P. A., & Vikulova, E. S. (2024). Structure and Properties of Ni(II) Complexes with Heptanedione-3.5. Journal of Structural Chemistry, 65(12), 2406-2419. https://doi.org/10.1134/S0022476624120059

Vancouver

Zhezhera M, Kochelakov DV, Stabnikov PA, Vikulova ES. Structure and Properties of Ni(II) Complexes with Heptanedione-3.5. Journal of Structural Chemistry. 2024 Dec;65(12):2406-2419. doi: 10.1134/S0022476624120059

Author

Zhezhera, M. ; Kochelakov, D. V. ; Stabnikov, P. A. et al. / Structure and Properties of Ni(II) Complexes with Heptanedione-3.5. In: Journal of Structural Chemistry. 2024 ; Vol. 65, No. 12. pp. 2406-2419.

BibTeX

@article{4e2cf66319294af3afc7f2ab4f440af8,
title = "Structure and Properties of Ni(II) Complexes with Heptanedione-3.5",
abstract = "The influence of the size of the β-diketonate ligand substituent on the structure and thermal properties of volatile Ni(II) complexes is determined. To this aim, a corresponding heptanedione-3.5 (Hhd) derivative is prepared. The structures of [Ni3(hd)6] and its derivatives [Ni4(OMe)4(hd)4(MeOH)4] and [Ni3(OH) (hd)5(H2O)]2 are studied by XRD. The trinuclear complex is similar to its simplest β-diketonate analogue. Such a tetranuclear structure is typical for mixed-ligand alkoxy-β-diketonate divalent metal complexes, whereas the hexuclear structure is unique. Thermal properties of Ni(II) β-diketonates in the series L = RC(O)CHC(O)R, R = Me, Et, tBu are compared by the thermogravimetry method.",
keywords = "XRD, mixed-ligand complexes, nickel(II), non-fluorinated β-diketonates, oligonuclear complexes, volatile precursors",
author = "M. Zhezhera and Kochelakov, {D. V.} and Stabnikov, {P. A.} and Vikulova, {E. S.}",
year = "2024",
month = dec,
doi = "10.1134/S0022476624120059",
language = "English",
volume = "65",
pages = "2406--2419",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "12",

}

RIS

TY - JOUR

T1 - Structure and Properties of Ni(II) Complexes with Heptanedione-3.5

AU - Zhezhera, M.

AU - Kochelakov, D. V.

AU - Stabnikov, P. A.

AU - Vikulova, E. S.

PY - 2024/12

Y1 - 2024/12

N2 - The influence of the size of the β-diketonate ligand substituent on the structure and thermal properties of volatile Ni(II) complexes is determined. To this aim, a corresponding heptanedione-3.5 (Hhd) derivative is prepared. The structures of [Ni3(hd)6] and its derivatives [Ni4(OMe)4(hd)4(MeOH)4] and [Ni3(OH) (hd)5(H2O)]2 are studied by XRD. The trinuclear complex is similar to its simplest β-diketonate analogue. Such a tetranuclear structure is typical for mixed-ligand alkoxy-β-diketonate divalent metal complexes, whereas the hexuclear structure is unique. Thermal properties of Ni(II) β-diketonates in the series L = RC(O)CHC(O)R, R = Me, Et, tBu are compared by the thermogravimetry method.

AB - The influence of the size of the β-diketonate ligand substituent on the structure and thermal properties of volatile Ni(II) complexes is determined. To this aim, a corresponding heptanedione-3.5 (Hhd) derivative is prepared. The structures of [Ni3(hd)6] and its derivatives [Ni4(OMe)4(hd)4(MeOH)4] and [Ni3(OH) (hd)5(H2O)]2 are studied by XRD. The trinuclear complex is similar to its simplest β-diketonate analogue. Such a tetranuclear structure is typical for mixed-ligand alkoxy-β-diketonate divalent metal complexes, whereas the hexuclear structure is unique. Thermal properties of Ni(II) β-diketonates in the series L = RC(O)CHC(O)R, R = Me, Et, tBu are compared by the thermogravimetry method.

KW - XRD

KW - mixed-ligand complexes

KW - nickel(II)

KW - non-fluorinated β-diketonates

KW - oligonuclear complexes

KW - volatile precursors

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85213262606&origin=inward&txGid=cd1e5c53e81c7045d51944fcdae332dc

UR - https://www.mendeley.com/catalogue/673b1416-161d-3f74-bdb0-f45ef05a5645/

U2 - 10.1134/S0022476624120059

DO - 10.1134/S0022476624120059

M3 - Article

VL - 65

SP - 2406

EP - 2419

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

ID: 61405194