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Structural Properties of Glass-Forming Ethanol and Glycerol From O–H Vibrational Spectra. / Zykova, V. A.; Surovtsev, N. V.

In: Journal of Structural Chemistry, Vol. 59, No. 2, 01.03.2018, p. 321-327.

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Zykova VA, Surovtsev NV. Structural Properties of Glass-Forming Ethanol and Glycerol From O–H Vibrational Spectra. Journal of Structural Chemistry. 2018 Mar 1;59(2):321-327. doi: 10.1134/S0022476618020099

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Zykova, V. A. ; Surovtsev, N. V. / Structural Properties of Glass-Forming Ethanol and Glycerol From O–H Vibrational Spectra. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 2. pp. 321-327.

BibTeX

@article{c231f797153744308d49a29f070ae2a1,
title = "Structural Properties of Glass-Forming Ethanol and Glycerol From O–H Vibrational Spectra",
abstract = "The O–H stretching vibrations of hydrogen-bonded glass formers (ethanol and glycerol) are studied by Raman scattering in a temperature range where the liquid state changes from low-viscous to solid. Several characteristic bands exhibiting different temperature behavior can be distinguished in the O–H vibrational spectrum of ethanol. The appearance of an additional band on cooling ethanol below 220 K is related to the appearance of locally favored structures. No notable manifestations of these features are detected in the spectra of glycerol.",
keywords = "locally favored structures, O–H vibrations, Raman scattering, structure of glass-forming liquids",
author = "Zykova, {V. A.} and Surovtsev, {N. V.}",
year = "2018",
month = mar,
day = "1",
doi = "10.1134/S0022476618020099",
language = "English",
volume = "59",
pages = "321--327",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Structural Properties of Glass-Forming Ethanol and Glycerol From O–H Vibrational Spectra

AU - Zykova, V. A.

AU - Surovtsev, N. V.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The O–H stretching vibrations of hydrogen-bonded glass formers (ethanol and glycerol) are studied by Raman scattering in a temperature range where the liquid state changes from low-viscous to solid. Several characteristic bands exhibiting different temperature behavior can be distinguished in the O–H vibrational spectrum of ethanol. The appearance of an additional band on cooling ethanol below 220 K is related to the appearance of locally favored structures. No notable manifestations of these features are detected in the spectra of glycerol.

AB - The O–H stretching vibrations of hydrogen-bonded glass formers (ethanol and glycerol) are studied by Raman scattering in a temperature range where the liquid state changes from low-viscous to solid. Several characteristic bands exhibiting different temperature behavior can be distinguished in the O–H vibrational spectrum of ethanol. The appearance of an additional band on cooling ethanol below 220 K is related to the appearance of locally favored structures. No notable manifestations of these features are detected in the spectra of glycerol.

KW - locally favored structures

KW - O–H vibrations

KW - Raman scattering

KW - structure of glass-forming liquids

UR - http://www.scopus.com/inward/record.url?scp=85048144426&partnerID=8YFLogxK

U2 - 10.1134/S0022476618020099

DO - 10.1134/S0022476618020099

M3 - Article

AN - SCOPUS:85048144426

VL - 59

SP - 321

EP - 327

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 13794733