Research output: Contribution to journal › Review article › peer-review
Stoichiography and present-day analytical chemistry of solid inorganic substances and materials. / Malakhov, V. V.
In: Journal of Analytical Chemistry, Vol. 72, No. 6, 01.06.2017, p. 583-596.Research output: Contribution to journal › Review article › peer-review
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TY - JOUR
T1 - Stoichiography and present-day analytical chemistry of solid inorganic substances and materials
AU - Malakhov, V. V.
PY - 2017/6/1
Y1 - 2017/6/1
N2 - The article covers factors that determine fundamental difficulties of chemical phase analysis of a mixture of solid phases of inorganic compounds. Stoichiographic principles and methods, novel for analytical chemistry and leading to the efficient solution of the problems of phase analysis, are discussed. Conditions of the selective separation of mixtures of multiphase multielement solid compounds and principles of the new method, fan-like separation, ensuring the extraction of individual phases from unseparated mixtures, are considered. An idea of a complex method of solving analytical problems by stoichiography methods in proposed. The problem of the multiplicity of objects of analysis is discussed and general principles of the efficient solution of problems of the detection and identification of components of complex mixtures of unknown chemical composition are considered.
AB - The article covers factors that determine fundamental difficulties of chemical phase analysis of a mixture of solid phases of inorganic compounds. Stoichiographic principles and methods, novel for analytical chemistry and leading to the efficient solution of the problems of phase analysis, are discussed. Conditions of the selective separation of mixtures of multiphase multielement solid compounds and principles of the new method, fan-like separation, ensuring the extraction of individual phases from unseparated mixtures, are considered. An idea of a complex method of solving analytical problems by stoichiography methods in proposed. The problem of the multiplicity of objects of analysis is discussed and general principles of the efficient solution of problems of the detection and identification of components of complex mixtures of unknown chemical composition are considered.
KW - fan-like separation
KW - method of differential dissolution
KW - phase analysis
KW - stoichiography
UR - http://www.scopus.com/inward/record.url?scp=85019998135&partnerID=8YFLogxK
U2 - 10.1134/S1061934817060090
DO - 10.1134/S1061934817060090
M3 - Review article
AN - SCOPUS:85019998135
VL - 72
SP - 583
EP - 596
JO - Journal of Analytical Chemistry
JF - Journal of Analytical Chemistry
SN - 1061-9348
IS - 6
ER -
ID: 10187863