Research output: Contribution to journal › Article › peer-review
Stereoselectivity of formation of monoterpene – Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with α-amino acid derivatives. / Marenin, K. S.; Gatilov, Yu V.; Agafontsev, A. M. et al.
In: Steroids, Vol. 117, 01.01.2017, p. 112-119.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Stereoselectivity of formation of monoterpene – Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with α-amino acid derivatives
AU - Marenin, K. S.
AU - Gatilov, Yu V.
AU - Agafontsev, A. M.
AU - Tkachev, A. V.
N1 - Copyright © 2016 Elsevier Inc. All rights reserved.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (−)-α-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene–amino acids hybrids, which belong to the series of α-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene–amino acids hybrids, with diastereomeric excess varying from 0 to 100%.
AB - Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (−)-α-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene–amino acids hybrids, which belong to the series of α-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene–amino acids hybrids, with diastereomeric excess varying from 0 to 100%.
KW - (+)-3-Carene
KW - (−)-α-Pinene
KW - Amino acids
KW - Diastereoselectivity
KW - Nitroso chlorides
KW - Magnetic Resonance Spectroscopy
KW - Amino Acids/chemistry
KW - Stereoisomerism
KW - Monoterpenes/chemistry
KW - Terpenes/chemistry
KW - COORDINATION CHEMISTRY
KW - ZN-II
KW - NATURAL MONOTERPENES
KW - CRYSTAL-STRUCTURES
KW - ALDEHYDES
KW - H2L1
KW - (+)-3-CARENE
KW - BINUCLEAR COMPLEXES
KW - (-)-alpha-Pinene
KW - LIGANDS
KW - II COMPLEXES
UR - http://www.scopus.com/inward/record.url?scp=85006753312&partnerID=8YFLogxK
U2 - 10.1016/j.steroids.2016.09.016
DO - 10.1016/j.steroids.2016.09.016
M3 - Article
C2 - 27693094
AN - SCOPUS:85006753312
VL - 117
SP - 112
EP - 119
JO - Steroids
JF - Steroids
SN - 0039-128X
ER -
ID: 10318133