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Steam-Assisted Synthesis of Hierarchical Fe-Silicalite-1: A Novel Heterogeneous Fenton Catalyst. / Bragina, A. A.; Babina, K. A.; Kuleshov, D. V. et al.

In: Petroleum Chemistry, Vol. 63, No. 2, 02.2023, p. 158-166.

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Bragina, A. A. ; Babina, K. A. ; Kuleshov, D. V. et al. / Steam-Assisted Synthesis of Hierarchical Fe-Silicalite-1: A Novel Heterogeneous Fenton Catalyst. In: Petroleum Chemistry. 2023 ; Vol. 63, No. 2. pp. 158-166.

BibTeX

@article{35259abbaf884a30acc9780e46697212,
title = "Steam-Assisted Synthesis of Hierarchical Fe-Silicalite-1: A Novel Heterogeneous Fenton Catalyst",
abstract = "Three types of heterogeneous Fenton catalysts based on Fe-silicalite-1 were synthesized: (1) microcrystals with an average size of 5 μm (m-FeZ); (2) a hierarchical porous sample consisting of 100–200 nm nanocrystals prepared using a dry polystyrene latex template (h-FeZ); and (3) three hierarchical porous samples consisting of 30–50 nm nanocrystals prepared by steam-assisted crystallization (n-FeZ-1,2,3). The synthesis procedure for n-FeZ-1 and n-FeZ-2 included gel pretreatment at 90°C for 72 h. This pretreatment specifically involved introducing Fe into the reaction mixture after (for n-FeZ-1) and before (for n-FeZ-2) the gel aging. The samples were tested as heterogeneous Fenton catalysts in H2O2-mediated total oxidation of ethanol. The performance of the heterogeneous catalysts was compared with a conventional homogeneous Fenton catalyst.",
keywords = "Fe-silicalite-1, heterogeneous Fenton system, hierarchical zeolites, steam-assisted crystallization, water decontamination, zeolites",
author = "Bragina, {A. A.} and Babina, {K. A.} and Kuleshov, {D. V.} and Lysikov, {A. I.} and Parkhomchuk, {E. V.}",
note = "This study was carried out within the State Program of BIC SB RAS (project No. AAAA-A21-121011490008-3). Публикация для корректировки.",
year = "2023",
month = feb,
doi = "10.1134/S0965544123020202",
language = "English",
volume = "63",
pages = "158--166",
journal = "Petroleum Chemistry",
issn = "0965-5441",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Steam-Assisted Synthesis of Hierarchical Fe-Silicalite-1: A Novel Heterogeneous Fenton Catalyst

AU - Bragina, A. A.

AU - Babina, K. A.

AU - Kuleshov, D. V.

AU - Lysikov, A. I.

AU - Parkhomchuk, E. V.

N1 - This study was carried out within the State Program of BIC SB RAS (project No. AAAA-A21-121011490008-3). Публикация для корректировки.

PY - 2023/2

Y1 - 2023/2

N2 - Three types of heterogeneous Fenton catalysts based on Fe-silicalite-1 were synthesized: (1) microcrystals with an average size of 5 μm (m-FeZ); (2) a hierarchical porous sample consisting of 100–200 nm nanocrystals prepared using a dry polystyrene latex template (h-FeZ); and (3) three hierarchical porous samples consisting of 30–50 nm nanocrystals prepared by steam-assisted crystallization (n-FeZ-1,2,3). The synthesis procedure for n-FeZ-1 and n-FeZ-2 included gel pretreatment at 90°C for 72 h. This pretreatment specifically involved introducing Fe into the reaction mixture after (for n-FeZ-1) and before (for n-FeZ-2) the gel aging. The samples were tested as heterogeneous Fenton catalysts in H2O2-mediated total oxidation of ethanol. The performance of the heterogeneous catalysts was compared with a conventional homogeneous Fenton catalyst.

AB - Three types of heterogeneous Fenton catalysts based on Fe-silicalite-1 were synthesized: (1) microcrystals with an average size of 5 μm (m-FeZ); (2) a hierarchical porous sample consisting of 100–200 nm nanocrystals prepared using a dry polystyrene latex template (h-FeZ); and (3) three hierarchical porous samples consisting of 30–50 nm nanocrystals prepared by steam-assisted crystallization (n-FeZ-1,2,3). The synthesis procedure for n-FeZ-1 and n-FeZ-2 included gel pretreatment at 90°C for 72 h. This pretreatment specifically involved introducing Fe into the reaction mixture after (for n-FeZ-1) and before (for n-FeZ-2) the gel aging. The samples were tested as heterogeneous Fenton catalysts in H2O2-mediated total oxidation of ethanol. The performance of the heterogeneous catalysts was compared with a conventional homogeneous Fenton catalyst.

KW - Fe-silicalite-1

KW - heterogeneous Fenton system

KW - hierarchical zeolites

KW - steam-assisted crystallization

KW - water decontamination

KW - zeolites

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85153729445&origin=inward&txGid=4b28267cd9a4490f78aa867c23d74324

UR - https://www.mendeley.com/catalogue/17af117f-9aa9-3eb7-969b-87b4139090cd/

U2 - 10.1134/S0965544123020202

DO - 10.1134/S0965544123020202

M3 - Article

VL - 63

SP - 158

EP - 166

JO - Petroleum Chemistry

JF - Petroleum Chemistry

SN - 0965-5441

IS - 2

ER -

ID: 59278051