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State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation. / Kibis, L. S.; Svintsitskiy, D. A.; Ovsyuk, I. Yu. et al.

In: Journal of Structural Chemistry, Vol. 66, No. 2, 10.03.2025, p. 320-337.

Research output: Contribution to journal › Article › peer-review

Harvard

Kibis, LS, Svintsitskiy, DA, Ovsyuk, IY, Romanenko, AV, Kardash, TY, Stonkus, OA, Slavinskaya, EM & Boronin, AI 2025, 'State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation', Journal of Structural Chemistry, vol. 66, no. 2, pp. 320-337. https://doi.org/10.1134/S0022476625020106

APA

Kibis, L. S., Svintsitskiy, D. A., Ovsyuk, I. Y., Romanenko, A. V., Kardash, T. Y., Stonkus, O. A., Slavinskaya, E. M., & Boronin, A. I. (2025). State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation. Journal of Structural Chemistry, 66(2), 320-337. https://doi.org/10.1134/S0022476625020106

Vancouver

Kibis LS, Svintsitskiy DA, Ovsyuk IY, Romanenko AV, Kardash TY, Stonkus OA et al. State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation. Journal of Structural Chemistry. 2025 Mar 10;66(2):320-337. doi: 10.1134/S0022476625020106

Author

Kibis, L. S. ; Svintsitskiy, D. A. ; Ovsyuk, I. Yu. et al. / State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation. In: Journal of Structural Chemistry. 2025 ; Vol. 66, No. 2. pp. 320-337.

BibTeX

@article{cb61a33abbbb4c68b7c2684db643e4d0,
title = "State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation",
abstract = "Abstract: Fundamental research is essential for developing new generation catalysts and optimizing the characteristics of existing catalytic systems, because it allows establishing key parameters determining the activity and selectivity of the studied reactions. In this work, the activity of supported platinum-titanium catalysts in the selective oxidation of ammonia is studied. The influence of modifying additives (potassium chloride and tungsten oxide) on the physicochemical and catalytic properties of the Pt/TiO2 system is considered. Structural methods such as powder XRD and transmission electron microscopy showed that the studied catalysts contain highly dispersed platinum particles. The effect of oxidation-reduction treatment on the oxidation state of platinum on the surface of modified and unmodified catalysts is determined by ex situ X-ray photoelectron spectroscopy. It is shown that doping the samples by tungsten oxide and potassium chloride stabilizes the metallic platinum state and the oxidized Pt2+ state, respectively. The correlation between the active component state and catalytic properties shows that the activity of samples below 180 °C improves upon the introduction of tungsten oxide and their selectivity to molecular nitrogen below 250 °C increases upon the introduction of potassium chloride.",
keywords = "NH3–SCO, XPS, platinum, selective oxidation of ammonia, titanium oxide",
author = "Kibis, {L. S.} and Svintsitskiy, {D. A.} and Ovsyuk, {I. Yu.} and Romanenko, {A. V.} and Kardash, {T. Y.} and Stonkus, {O. A.} and Slavinskaya, {E. M.} and Boronin, {A. I.}",
note = "This work was funded by the Russian Science Foundation (project No. 23-23-00322, January 12, 2023). State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation / L. S. Kibis, D. A. Svintsitskiy, I. Yu. Ovsyuk [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 2. – P. 320-337. – DOI 10.1134/S0022476625020106.",
year = "2025",
month = mar,
day = "10",
doi = "10.1134/S0022476625020106",
language = "English",
volume = "66",
pages = "320--337",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer",
number = "2",

}

RIS

TY - JOUR

T1 - State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation

AU - Kibis, L. S.

AU - Svintsitskiy, D. A.

AU - Ovsyuk, I. Yu.

AU - Romanenko, A. V.

AU - Kardash, T. Y.

AU - Stonkus, O. A.

AU - Slavinskaya, E. M.

AU - Boronin, A. I.

N1 - This work was funded by the Russian Science Foundation (project No. 23-23-00322, January 12, 2023). State of the Active Component and Catalytic Properties of Modified Platinum-Titanium Catalysts for Selective Ammonia Oxidation / L. S. Kibis, D. A. Svintsitskiy, I. Yu. Ovsyuk [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 2. – P. 320-337. – DOI 10.1134/S0022476625020106.

PY - 2025/3/10

Y1 - 2025/3/10

N2 - Abstract: Fundamental research is essential for developing new generation catalysts and optimizing the characteristics of existing catalytic systems, because it allows establishing key parameters determining the activity and selectivity of the studied reactions. In this work, the activity of supported platinum-titanium catalysts in the selective oxidation of ammonia is studied. The influence of modifying additives (potassium chloride and tungsten oxide) on the physicochemical and catalytic properties of the Pt/TiO2 system is considered. Structural methods such as powder XRD and transmission electron microscopy showed that the studied catalysts contain highly dispersed platinum particles. The effect of oxidation-reduction treatment on the oxidation state of platinum on the surface of modified and unmodified catalysts is determined by ex situ X-ray photoelectron spectroscopy. It is shown that doping the samples by tungsten oxide and potassium chloride stabilizes the metallic platinum state and the oxidized Pt2+ state, respectively. The correlation between the active component state and catalytic properties shows that the activity of samples below 180 °C improves upon the introduction of tungsten oxide and their selectivity to molecular nitrogen below 250 °C increases upon the introduction of potassium chloride.

AB - Abstract: Fundamental research is essential for developing new generation catalysts and optimizing the characteristics of existing catalytic systems, because it allows establishing key parameters determining the activity and selectivity of the studied reactions. In this work, the activity of supported platinum-titanium catalysts in the selective oxidation of ammonia is studied. The influence of modifying additives (potassium chloride and tungsten oxide) on the physicochemical and catalytic properties of the Pt/TiO2 system is considered. Structural methods such as powder XRD and transmission electron microscopy showed that the studied catalysts contain highly dispersed platinum particles. The effect of oxidation-reduction treatment on the oxidation state of platinum on the surface of modified and unmodified catalysts is determined by ex situ X-ray photoelectron spectroscopy. It is shown that doping the samples by tungsten oxide and potassium chloride stabilizes the metallic platinum state and the oxidized Pt2+ state, respectively. The correlation between the active component state and catalytic properties shows that the activity of samples below 180 °C improves upon the introduction of tungsten oxide and their selectivity to molecular nitrogen below 250 °C increases upon the introduction of potassium chloride.

KW - NH3–SCO

KW - XPS

KW - platinum

KW - selective oxidation of ammonia

KW - titanium oxide

UR - https://www.mendeley.com/catalogue/3fbb9f2b-d025-38d6-a38f-c5e497b41ead/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-86000766849&origin=inward&txGid=b6aac307de4de6a4cb46fae2c0f34ca2

UR - https://www.elibrary.ru/item.asp?id=80438834

U2 - 10.1134/S0022476625020106

DO - 10.1134/S0022476625020106

M3 - Article

VL - 66

SP - 320

EP - 337

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 65066911