Spin-Labeled Linker for the Design of Coordination Polymers

Standard

Spin-Labeled Linker for the Design of Coordination Polymers. / Romanenko, G. V.; Fokin, S. V.; Tolstikov, S. E. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 6, 01.06.2020, p. 906-913.

Research output: Contribution to journal › Article › peer-review

Harvard

Romanenko, GV, Fokin, SV, Tolstikov, SE, Letyagin, GA , Bogomyakov, AS & Ovcharenko, VI 2020, 'Spin-Labeled Linker for the Design of Coordination Polymers', Journal of Structural Chemistry, vol. 61, no. 6, pp. 906-913. https://doi.org/10.1134/S0022476620060104

APA

Romanenko, G. V., Fokin, S. V., Tolstikov, S. E., Letyagin, G. A., Bogomyakov, A. S., & Ovcharenko, V. I. (2020). Spin-Labeled Linker for the Design of Coordination Polymers. Journal of Structural Chemistry, 61(6), 906-913. https://doi.org/10.1134/S0022476620060104

Vancouver

Romanenko GV, Fokin SV, Tolstikov SE, Letyagin GA , Bogomyakov AS, Ovcharenko VI. Spin-Labeled Linker for the Design of Coordination Polymers. Journal of Structural Chemistry. 2020 Jun 1;61(6):906-913. doi: 10.1134/S0022476620060104

Author

Romanenko, G. V. ; Fokin, S. V. ; Tolstikov, S. E. et al. / Spin-Labeled Linker for the Design of Coordination Polymers. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 6. pp. 906-913.

BibTeX

@article{127dba153dd84c4d8888f2e926776068,

title = "Spin-Labeled Linker for the Design of Coordination Polymers",

abstract = "The synthesis of a novel nitronylnitroxyl radical 2-(2,5-di(pyridin-4-yl)phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl (L) and the first Mn(II) complex with it [Mn(NO3)2(L)(H2O)× ×(i-PrOH)] is elaborated and performed. It is found that the complex is formed by polymeric chains in which (NO3)2(H2O)(i-PrOH) fragmentы are linked by L coordinated by N atoms of pyridine rings. The chains are combined into layers by hydrogen bonds between the coordinated water molecules, i-PrOH, and nitrate anions. The layers are joined into a framework by weak C-H⋯O contacts between O atoms of the nitronylnitroxyl fragment and the pyridine C-H group.",

keywords = "coordination polymer, hydrogen bond, manganese, nitroxyl radical, METAL-ORGANIC FRAMEWORKS, RADICALS",

author = "Romanenko, {G. V.} and Fokin, {S. V.} and Tolstikov, {S. E.} and Letyagin, {G. A.} and Bogomyakov, {A. S.} and Ovcharenko, {V. I.}",

year = "2020",

month = jun,

day = "1",

doi = "10.1134/S0022476620060104",

language = "English",

volume = "61",

pages = "906--913",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "6",

}

RIS

TY - JOUR

T1 - Spin-Labeled Linker for the Design of Coordination Polymers

AU - Romanenko, G. V.

AU - Fokin, S. V.

AU - Tolstikov, S. E.

AU - Letyagin, G. A.

AU - Bogomyakov, A. S.

AU - Ovcharenko, V. I.

PY - 2020/6/1

Y1 - 2020/6/1

N2 - The synthesis of a novel nitronylnitroxyl radical 2-(2,5-di(pyridin-4-yl)phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl (L) and the first Mn(II) complex with it [Mn(NO3)2(L)(H2O)× ×(i-PrOH)] is elaborated and performed. It is found that the complex is formed by polymeric chains in which (NO3)2(H2O)(i-PrOH) fragmentы are linked by L coordinated by N atoms of pyridine rings. The chains are combined into layers by hydrogen bonds between the coordinated water molecules, i-PrOH, and nitrate anions. The layers are joined into a framework by weak C-H⋯O contacts between O atoms of the nitronylnitroxyl fragment and the pyridine C-H group.

AB - The synthesis of a novel nitronylnitroxyl radical 2-(2,5-di(pyridin-4-yl)phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl (L) and the first Mn(II) complex with it [Mn(NO3)2(L)(H2O)× ×(i-PrOH)] is elaborated and performed. It is found that the complex is formed by polymeric chains in which (NO3)2(H2O)(i-PrOH) fragmentы are linked by L coordinated by N atoms of pyridine rings. The chains are combined into layers by hydrogen bonds between the coordinated water molecules, i-PrOH, and nitrate anions. The layers are joined into a framework by weak C-H⋯O contacts between O atoms of the nitronylnitroxyl fragment and the pyridine C-H group.

KW - coordination polymer

KW - hydrogen bond

KW - manganese

KW - nitroxyl radical

KW - METAL-ORGANIC FRAMEWORKS

KW - RADICALS

UR - http://www.scopus.com/inward/record.url?scp=85089219500&partnerID=8YFLogxK

U2 - 10.1134/S0022476620060104

DO - 10.1134/S0022476620060104

M3 - Article

AN - SCOPUS:85089219500

VL - 61

SP - 906

EP - 913

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 24955719