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Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen. / Matyshak, V. A.; Il’ichev, A. N.; Sil’chenkova, O. N. et al.

In: Kinetics and Catalysis, Vol. 58, No. 2, 03.2017, p. 198-210.

Research output: Contribution to journal › Article › peer-review

Harvard

Matyshak, VA, Il’ichev, AN, Sil’chenkova, ON, Sadykov, VA & Korchak, VN 2017, 'Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen', Kinetics and Catalysis, vol. 58, no. 2, pp. 198-210. https://doi.org/10.1134/S0023158417020082

APA

Matyshak, V. A., Il’ichev, A. N., Sil’chenkova, O. N., Sadykov, V. A., & Korchak, V. N. (2017). Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen. Kinetics and Catalysis, 58(2), 198-210. https://doi.org/10.1134/S0023158417020082

Vancouver

Matyshak VA, Il’ichev AN, Sil’chenkova ON, Sadykov VA, Korchak VN. Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen. Kinetics and Catalysis. 2017 Mar;58(2):198-210. doi: 10.1134/S0023158417020082

Author

Matyshak, V. A. ; Il’ichev, A. N. ; Sil’chenkova, O. N. et al. / Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen. In: Kinetics and Catalysis. 2017 ; Vol. 58, No. 2. pp. 198-210.

BibTeX

@article{b89db3f057d24ed8885cd3af55f82084,
title = "Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen",
abstract = "It has been demonstrated by quantitative spectrokinetic measurements that, on the surface of zirconia stabilized as a tetragonal phase, the rate-limiting step of the selective catalytic reduction of nitrogen oxides (SCR of NOx) with propylene is the interaction of surface nitrates with C3H6 yielding organic nitro compounds. It is hypothesized that propylene reacts not with the nitrates themselves but with the activated complex NO2 ads whose structure is intermediate between the structures of the monodentate NO3 − and NO2 species. Deep C3H6 oxidation exerts an adverse effect on the rate of the SCR of NOx with propylene, and the interaction between O2 and NO, which yields NO2 and NO3 − stimulates further nitrogen reduction to N2. The effect of the reaction between oxygen and O2N−CnHm on the NOx reduction rate is variable and is determined by the C3H6/NOx ratio. A generalized scheme of the SCR of NOx with propylene on the surface of ZrO2 partially stabilized as a tetragonal phase has been developed by comparing experimental data of this study and data available from the literature.",
keywords = "adsorption of NO, and their mixtures with O, CH, properties of surface complexes, selective catalytic reduction of NO, zirconia catalysts, C3H6, REACTION PATHS, PROPENE, COMPLEXES, DIOXIDE, IR, adsorption of NOx, and their mixtures with O-2, selective catalytic reduction of NOx, ALUMINA, SELECTIVE CATALYTIC-REDUCTION, NO(X), NITROGEN-OXIDES",
author = "Matyshak, {V. A.} and Il{\textquoteright}ichev, {A. N.} and Sil{\textquoteright}chenkova, {O. N.} and Sadykov, {V. A.} and Korchak, {V. N.}",
year = "2017",
month = mar,
doi = "10.1134/S0023158417020082",
language = "English",
volume = "58",
pages = "198--210",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Spectrokinetic study of the mechanism of NOx reduction with propylene over ZrO2 in excess oxygen

AU - Matyshak, V. A.

AU - Il’ichev, A. N.

AU - Sil’chenkova, O. N.

AU - Sadykov, V. A.

AU - Korchak, V. N.

PY - 2017/3

Y1 - 2017/3

N2 - It has been demonstrated by quantitative spectrokinetic measurements that, on the surface of zirconia stabilized as a tetragonal phase, the rate-limiting step of the selective catalytic reduction of nitrogen oxides (SCR of NOx) with propylene is the interaction of surface nitrates with C3H6 yielding organic nitro compounds. It is hypothesized that propylene reacts not with the nitrates themselves but with the activated complex NO2 ads whose structure is intermediate between the structures of the monodentate NO3 − and NO2 species. Deep C3H6 oxidation exerts an adverse effect on the rate of the SCR of NOx with propylene, and the interaction between O2 and NO, which yields NO2 and NO3 − stimulates further nitrogen reduction to N2. The effect of the reaction between oxygen and O2N−CnHm on the NOx reduction rate is variable and is determined by the C3H6/NOx ratio. A generalized scheme of the SCR of NOx with propylene on the surface of ZrO2 partially stabilized as a tetragonal phase has been developed by comparing experimental data of this study and data available from the literature.

AB - It has been demonstrated by quantitative spectrokinetic measurements that, on the surface of zirconia stabilized as a tetragonal phase, the rate-limiting step of the selective catalytic reduction of nitrogen oxides (SCR of NOx) with propylene is the interaction of surface nitrates with C3H6 yielding organic nitro compounds. It is hypothesized that propylene reacts not with the nitrates themselves but with the activated complex NO2 ads whose structure is intermediate between the structures of the monodentate NO3 − and NO2 species. Deep C3H6 oxidation exerts an adverse effect on the rate of the SCR of NOx with propylene, and the interaction between O2 and NO, which yields NO2 and NO3 − stimulates further nitrogen reduction to N2. The effect of the reaction between oxygen and O2N−CnHm on the NOx reduction rate is variable and is determined by the C3H6/NOx ratio. A generalized scheme of the SCR of NOx with propylene on the surface of ZrO2 partially stabilized as a tetragonal phase has been developed by comparing experimental data of this study and data available from the literature.

KW - adsorption of NO

KW - and their mixtures with O

KW - CH

KW - properties of surface complexes

KW - selective catalytic reduction of NO

KW - zirconia catalysts

KW - C3H6

KW - REACTION PATHS

KW - PROPENE

KW - COMPLEXES

KW - DIOXIDE

KW - IR

KW - adsorption of NOx

KW - and their mixtures with O-2

KW - selective catalytic reduction of NOx

KW - ALUMINA

KW - SELECTIVE CATALYTIC-REDUCTION

KW - NO(X)

KW - NITROGEN-OXIDES

UR - http://www.scopus.com/inward/record.url?scp=85017587910&partnerID=8YFLogxK

U2 - 10.1134/S0023158417020082

DO - 10.1134/S0023158417020082

M3 - Article

AN - SCOPUS:85017587910

VL - 58

SP - 198

EP - 210

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 2

ER -

ID: 10264475