Research output: Contribution to journal › Article › peer-review
Sorption of Neutral Red Dye by Enterosorbent Polysorb MP from AOT Microemulsion in n-Decane. / Demidova, M. G.; Podlipskaya, T. Yu; Shaparenko, N. O. et al.
In: Colloid Journal, Vol. 87, No. 2, 14.05.2025, p. 192-200.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Sorption of Neutral Red Dye by Enterosorbent Polysorb MP from AOT Microemulsion in n-Decane
AU - Demidova, M. G.
AU - Podlipskaya, T. Yu
AU - Shaparenko, N. O.
AU - Barakina, M. K.
AU - Tatarchuk, V. V.
AU - Bulavchenko, A. I.
N1 - This work was supported by the Russian Foundation for Basic Research (project no. 20-03-00017) and the Ministry of Science and Higher Education of the Russian Federation (project no. 121031700315-2).
PY - 2025/5/14
Y1 - 2025/5/14
N2 - Abstract: Neutral cationic red dye has been sorbed by Polysorb MP from a 0.25 mol/L AOT microemulsion in n-decane at different contents of the aqueous pseudophase. The maximum sorption capacity of the sorbent in the microemulsion is an order of magnitude higher than that in the water phase and amounts to 55 mg/g. A drastic drop in the degree of extraction upon increasing water content in the microemulsion from 1 to 8 vol % and the reversibility of the sorption processes have been revealed. Anionic dyes are not extracted by Polysorb in the same systems. As the water content increases, the zeta-potential of SiO2 particles decreases from 18 to 1 mV. On the basis of the obtained dependencies, a cation-exchange mechanism has been proposed for the sorption from the microemulsion, with this mechanism involving the exchange of sodium and neutral red dye cations between micelles adsorbed on the surface of particles and micelles contained in the bulk of the microemulsion.
AB - Abstract: Neutral cationic red dye has been sorbed by Polysorb MP from a 0.25 mol/L AOT microemulsion in n-decane at different contents of the aqueous pseudophase. The maximum sorption capacity of the sorbent in the microemulsion is an order of magnitude higher than that in the water phase and amounts to 55 mg/g. A drastic drop in the degree of extraction upon increasing water content in the microemulsion from 1 to 8 vol % and the reversibility of the sorption processes have been revealed. Anionic dyes are not extracted by Polysorb in the same systems. As the water content increases, the zeta-potential of SiO2 particles decreases from 18 to 1 mV. On the basis of the obtained dependencies, a cation-exchange mechanism has been proposed for the sorption from the microemulsion, with this mechanism involving the exchange of sodium and neutral red dye cations between micelles adsorbed on the surface of particles and micelles contained in the bulk of the microemulsion.
KW - adsorption
KW - electrokinetic potential
KW - microemulsions
KW - silica nanoparticles
KW - sodium bis(2-ethylhexyl) sulfosuccinate
UR - https://www.mendeley.com/catalogue/e2da8b59-7b59-303a-ad54-67f81f4709c7/
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105005023326&origin=inward&txGid=5c42b465eea383625fb5f54ff3869f74
U2 - 10.1134/S1061933X24601392
DO - 10.1134/S1061933X24601392
M3 - Article
VL - 87
SP - 192
EP - 200
JO - Colloid Journal
JF - Colloid Journal
SN - 1061-933X
IS - 2
ER -
ID: 66684625