Standard

Solid-state NaBH4 composites for hydrogen generation : Catalytic activity of nickel and cobalt catalysts. / Netskina, O. V.; Tayban, E. S.; Rogov, V. A. et al.

In: International Journal of Hydrogen Energy, Vol. 46, No. 7, 27.01.2021, p. 5459-5471.

Research output: Contribution to journal › Article › peer-review

Harvard

Netskina, OV, Tayban, ES, Rogov, VA, Ozerova, AM, Mukha, SA, Simagina, VI & Komova, OV 2021, 'Solid-state NaBH4 composites for hydrogen generation: Catalytic activity of nickel and cobalt catalysts', International Journal of Hydrogen Energy, vol. 46, no. 7, pp. 5459-5471. https://doi.org/10.1016/j.ijhydene.2020.11.078

APA

Netskina, O. V., Tayban, E. S., Rogov, V. A., Ozerova, A. M., Mukha, S. A., Simagina, V. I., & Komova, O. V. (2021). Solid-state NaBH4 composites for hydrogen generation: Catalytic activity of nickel and cobalt catalysts. International Journal of Hydrogen Energy, 46(7), 5459-5471. https://doi.org/10.1016/j.ijhydene.2020.11.078

Vancouver

Netskina OV, Tayban ES, Rogov VA, Ozerova AM, Mukha SA, Simagina VI et al. Solid-state NaBH4 composites for hydrogen generation: Catalytic activity of nickel and cobalt catalysts. International Journal of Hydrogen Energy. 2021 Jan 27;46(7):5459-5471. Epub 2020 Dec 4. doi: 10.1016/j.ijhydene.2020.11.078

Author

Netskina, O. V. ; Tayban, E. S. ; Rogov, V. A. et al. / Solid-state NaBH4 composites for hydrogen generation : Catalytic activity of nickel and cobalt catalysts. In: International Journal of Hydrogen Energy. 2021 ; Vol. 46, No. 7. pp. 5459-5471.

BibTeX

@article{4b44060f9cab4ea9a0ad275bb6738bed,
title = "Solid-state NaBH4 composites for hydrogen generation: Catalytic activity of nickel and cobalt catalysts",
abstract = "Hydrogen generation from tablets of sodium borohydride with chlorides of nickel and cobalt was studied. The nickel catalysts were shown to be less active in the borohydride hydrolysis than the cobalt catalysts. One of the reasons for the lower activity of the nickel catalyst was the presence of hydrogen on its surface, which hampered the adsorption of reactants. The addition of cobalt to the nickel catalyst increases the hydrogen generation rate. This is due to the introduction of active metal with low adsorption capacity for hydrogen and the higher dispersion of the active component.",
keywords = "Catalyst, Cobalt, Hydrolysis, Kinetics, Nickel, Sodium borohydride, FUEL-CELL GENERATORS, STORAGE, BORON, HEAT-TREATMENT, NI-B, TEMPERATURE, SODIUM-BOROHYDRIDE HYDROLYSIS, BORIDE, ALKALINE-SOLUTION, NANOCOMPOSITE",
author = "Netskina, {O. V.} and Tayban, {E. S.} and Rogov, {V. A.} and Ozerova, {A. M.} and Mukha, {S. A.} and Simagina, {V. I.} and Komova, {O. V.}",
note = "Publisher Copyright: {\textcopyright} 2020 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = jan,
day = "27",
doi = "10.1016/j.ijhydene.2020.11.078",
language = "English",
volume = "46",
pages = "5459--5471",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
number = "7",

}

RIS

TY - JOUR

T1 - Solid-state NaBH4 composites for hydrogen generation

T2 - Catalytic activity of nickel and cobalt catalysts

AU - Netskina, O. V.

AU - Tayban, E. S.

AU - Rogov, V. A.

AU - Ozerova, A. M.

AU - Mukha, S. A.

AU - Simagina, V. I.

AU - Komova, O. V.

N1 - Publisher Copyright: © 2020 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1/27

Y1 - 2021/1/27

N2 - Hydrogen generation from tablets of sodium borohydride with chlorides of nickel and cobalt was studied. The nickel catalysts were shown to be less active in the borohydride hydrolysis than the cobalt catalysts. One of the reasons for the lower activity of the nickel catalyst was the presence of hydrogen on its surface, which hampered the adsorption of reactants. The addition of cobalt to the nickel catalyst increases the hydrogen generation rate. This is due to the introduction of active metal with low adsorption capacity for hydrogen and the higher dispersion of the active component.

AB - Hydrogen generation from tablets of sodium borohydride with chlorides of nickel and cobalt was studied. The nickel catalysts were shown to be less active in the borohydride hydrolysis than the cobalt catalysts. One of the reasons for the lower activity of the nickel catalyst was the presence of hydrogen on its surface, which hampered the adsorption of reactants. The addition of cobalt to the nickel catalyst increases the hydrogen generation rate. This is due to the introduction of active metal with low adsorption capacity for hydrogen and the higher dispersion of the active component.

KW - Catalyst

KW - Cobalt

KW - Hydrolysis

KW - Kinetics

KW - Nickel

KW - Sodium borohydride

KW - FUEL-CELL GENERATORS

KW - STORAGE

KW - BORON

KW - HEAT-TREATMENT

KW - NI-B

KW - TEMPERATURE

KW - SODIUM-BOROHYDRIDE HYDROLYSIS

KW - BORIDE

KW - ALKALINE-SOLUTION

KW - NANOCOMPOSITE

UR - http://www.scopus.com/inward/record.url?scp=85097238117&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2020.11.078

DO - 10.1016/j.ijhydene.2020.11.078

M3 - Article

AN - SCOPUS:85097238117

VL - 46

SP - 5459

EP - 5471

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 7

ER -

ID: 26203789