Research output: Contribution to journal › Article › peer-review
SOLID SOLUTIONS OF COMPLEX YTTRIUM AND EUROPIUM BORATES Li6 R(BO3)3 AND LiR 6(BO3)3O5, R = Y, Eu. / Tarasenko, M. S.; Nikolaev, R. E.; Yakovleva, A. M. et al.
In: Journal of Structural Chemistry, Vol. 64, No. 9, 09.2023, p. 1715-1723.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - SOLID SOLUTIONS OF COMPLEX YTTRIUM AND EUROPIUM BORATES Li6 R(BO3)3 AND LiR 6(BO3)3O5, R = Y, Eu
AU - Tarasenko, M. S.
AU - Nikolaev, R. E.
AU - Yakovleva, A. M.
AU - Trifonov, V. A.
AU - Sukhikh, A. S.
AU - Naumov, N. G.
N1 - This work was funded by the Russian Science Foundation (project No. 22-43-02079).
PY - 2023/9
Y1 - 2023/9
N2 - X-ray quality crystals of solid solutions of complex borates Li6 R(BO3)3 and LiR 6(BO3)3O5 (R = Y, Eu) with different europium contents are grown from a Li6 R(BO3)3 melt solution with an addition of 20 mol.% of an yttrium–europium oxide mixture. The structural data show that the Y/Eu distribution over independent positions in the LiR 6(BO3)3O5 crystal is nonuniform; the difference between Eu occupancies reaches 80% and correlates with the Hirshfeld volumes of these sites calculated for LiR 6B3O14.
AB - X-ray quality crystals of solid solutions of complex borates Li6 R(BO3)3 and LiR 6(BO3)3O5 (R = Y, Eu) with different europium contents are grown from a Li6 R(BO3)3 melt solution with an addition of 20 mol.% of an yttrium–europium oxide mixture. The structural data show that the Y/Eu distribution over independent positions in the LiR 6(BO3)3O5 crystal is nonuniform; the difference between Eu occupancies reaches 80% and correlates with the Hirshfeld volumes of these sites calculated for LiR 6B3O14.
KW - borate
KW - crystal structure
KW - europium
KW - yttrium
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85173771653&origin=inward&txGid=552684a1ec684271e961b2e9c10ee103
UR - https://www.mendeley.com/catalogue/2e51bcb2-d7f6-3ae8-bad7-6c47de7c7118/
U2 - 10.1134/S0022476623090147
DO - 10.1134/S0022476623090147
M3 - Article
VL - 64
SP - 1715
EP - 1723
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 9
ER -
ID: 59235250