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Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water. / Gromov, Nikolay V.; Taran, Oxana P.; Semeykina, Viktoria S. et al.

In: Catalysis Letters, Vol. 147, No. 6, 06.2017, p. 1485-1495.

Research output: Contribution to journal › Article › peer-review

Harvard

Gromov, NV, Taran, OP, Semeykina, VS, Danilova, IG, Pestunov, AV, Parkhomchuk, EV & Parmon, VN 2017, 'Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water', Catalysis Letters, vol. 147, no. 6, pp. 1485-1495. https://doi.org/10.1007/s10562-017-2056-y

APA

Gromov, N. V., Taran, O. P., Semeykina, V. S., Danilova, I. G., Pestunov, A. V., Parkhomchuk, E. V., & Parmon, V. N. (2017). Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water. Catalysis Letters, 147(6), 1485-1495. https://doi.org/10.1007/s10562-017-2056-y

Vancouver

Gromov NV, Taran OP, Semeykina VS, Danilova IG, Pestunov AV, Parkhomchuk EV et al. Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water. Catalysis Letters. 2017 Jun;147(6):1485-1495. doi: 10.1007/s10562-017-2056-y

Author

Gromov, Nikolay V. ; Taran, Oxana P. ; Semeykina, Viktoria S. et al. / Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water. In: Catalysis Letters. 2017 ; Vol. 147, No. 6. pp. 1485-1495.

BibTeX

@article{83a2a36bfdd7442ea5bf83d756cb9856,
title = "Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water",
abstract = "Abstract: Solid acid NbOx/ZrO2 catalysts containing 0, 0.5, 1.1 and 2.8 wt.% of Nb were prepared for one–pot hydrolysis-dehydration of mechanically activated cellulose in pure hot water to produce glucose and 5-hydroxymethylfurfural. The catalysts were characterized (XRD, N2 adsorption, ICP-OES, UV–Vis DRS) and tested in cellulose processing at 453 K. The catalytic activity increased as follows: 0.5%Nb/ZrO2 < ZrO2 < < 1.1%Nb/ZrO2 ~ 2.8%Nb/ZrO2. This series was accounted for by the acid-basic properties of ZrO2, by the inhibition of its active sites by monomer niobium species and by the appearance of Br{\o}nsted acidity upon the formation of NbOx-containing polymer structures. The highest glucose and 5-HMF yields (22 and 16 mol%, respectively) were achieved over 2.8%Nb/ZrO2.",
keywords = "5-Hydrohymethylfurfural, Cellulose, Glucose, Hydrolysis-dehydration, Niobium oxide, Zirconia, CRYSTALLINITY, HYDROLYSIS, REACTIVITY, COMPRESSED WATER, ZRO2, NIOBIUM OXIDE CATALYSTS, FRUCTOSE, BIOMASS, DEHYDRATION, EFFICIENT CONVERSION",
author = "Gromov, {Nikolay V.} and Taran, {Oxana P.} and Semeykina, {Viktoria S.} and Danilova, {Irina G.} and Pestunov, {Andrey V.} and Parkhomchuk, {Ekaterina V.} and Parmon, {Valentin N.}",
note = "Publisher Copyright: {\textcopyright} 2017, Springer Science+Business Media New York.",
year = "2017",
month = jun,
doi = "10.1007/s10562-017-2056-y",
language = "English",
volume = "147",
pages = "1485--1495",
journal = "Catalysis Letters",
issn = "1011-372X",
publisher = "Springer Netherlands",
number = "6",

}

RIS

TY - JOUR

T1 - Solid Acidic NbOx/ZrO2 Catalysts for Transformation of Cellulose to Glucose and 5-Hydroxymethylfurfural in Pure Hot Water

AU - Gromov, Nikolay V.

AU - Taran, Oxana P.

AU - Semeykina, Viktoria S.

AU - Danilova, Irina G.

AU - Pestunov, Andrey V.

AU - Parkhomchuk, Ekaterina V.

AU - Parmon, Valentin N.

N1 - Publisher Copyright: © 2017, Springer Science+Business Media New York.

PY - 2017/6

Y1 - 2017/6

N2 - Abstract: Solid acid NbOx/ZrO2 catalysts containing 0, 0.5, 1.1 and 2.8 wt.% of Nb were prepared for one–pot hydrolysis-dehydration of mechanically activated cellulose in pure hot water to produce glucose and 5-hydroxymethylfurfural. The catalysts were characterized (XRD, N2 adsorption, ICP-OES, UV–Vis DRS) and tested in cellulose processing at 453 K. The catalytic activity increased as follows: 0.5%Nb/ZrO2 < ZrO2 < < 1.1%Nb/ZrO2 ~ 2.8%Nb/ZrO2. This series was accounted for by the acid-basic properties of ZrO2, by the inhibition of its active sites by monomer niobium species and by the appearance of Brønsted acidity upon the formation of NbOx-containing polymer structures. The highest glucose and 5-HMF yields (22 and 16 mol%, respectively) were achieved over 2.8%Nb/ZrO2.

AB - Abstract: Solid acid NbOx/ZrO2 catalysts containing 0, 0.5, 1.1 and 2.8 wt.% of Nb were prepared for one–pot hydrolysis-dehydration of mechanically activated cellulose in pure hot water to produce glucose and 5-hydroxymethylfurfural. The catalysts were characterized (XRD, N2 adsorption, ICP-OES, UV–Vis DRS) and tested in cellulose processing at 453 K. The catalytic activity increased as follows: 0.5%Nb/ZrO2 < ZrO2 < < 1.1%Nb/ZrO2 ~ 2.8%Nb/ZrO2. This series was accounted for by the acid-basic properties of ZrO2, by the inhibition of its active sites by monomer niobium species and by the appearance of Brønsted acidity upon the formation of NbOx-containing polymer structures. The highest glucose and 5-HMF yields (22 and 16 mol%, respectively) were achieved over 2.8%Nb/ZrO2.

KW - 5-Hydrohymethylfurfural

KW - Cellulose

KW - Glucose

KW - Hydrolysis-dehydration

KW - Niobium oxide

KW - Zirconia

KW - CRYSTALLINITY

KW - HYDROLYSIS

KW - REACTIVITY

KW - COMPRESSED WATER

KW - ZRO2

KW - NIOBIUM OXIDE CATALYSTS

KW - FRUCTOSE

KW - BIOMASS

KW - DEHYDRATION

KW - EFFICIENT CONVERSION

UR - http://www.scopus.com/inward/record.url?scp=85018364337&partnerID=8YFLogxK

U2 - 10.1007/s10562-017-2056-y

DO - 10.1007/s10562-017-2056-y

M3 - Article

AN - SCOPUS:85018364337

VL - 147

SP - 1485

EP - 1495

JO - Catalysis Letters

JF - Catalysis Letters

SN - 1011-372X

IS - 6

ER -

ID: 8716730