Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5

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Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF₅. / Mezhenkova, T. V.; Sinyakov, V. R.; Karpov, V. M. et al.

In: Russian Journal of Organic Chemistry, Vol. 56, No. 3, 03.2020, p. 429-435.

Research output: Contribution to journal › Article › peer-review

Author

Mezhenkova, T. V. ; Sinyakov, V. R. ; Karpov, V. M. et al. / Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF₅. In: Russian Journal of Organic Chemistry. 2020 ; Vol. 56, No. 3. pp. 429-435.

BibTeX

@article{e2eb3647446945c7b0b2a7166059fd51,

title = "Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5",

abstract = "Abstract: The reaction of perfluoro(1,2-diethylbenzocyclobutene) with1,2,4,5-tetrafluorobenzene in SbF5, followed byhydrolysis, gave products resulting from expansion of the tetrafluorophenyl ringto cycloheptatriene. The title compound reacted with 1,2,3,5-tetrafluorobenzeneto form products of opening of the four-membered ring. A similar reaction with1,2,3,4-tetrafluorobenzene involved opening of the cyclobutane ring togetherwith the formation of perfluoro(9,10-diethyl-9.10-dihydroanthracene)derivatives.",

keywords = "antimony pentafluoride, cation, perfluoro(1,2-diethylcyclobutabenzene), skeletal transformations, tetrafluorobenzene, perfluoro(1, PENTAFLUOROBENZENE RING, 2-diethylcyclobutabenzene), EXPANSION, FLUORINE-CONTAINING CARBOCATIONS",

author = "Mezhenkova, {T. V.} and Sinyakov, {V. R.} and Karpov, {V. M.} and Zonov, {Ya V.}",

year = "2020",

month = mar,

doi = "10.1134/S1070428020030100",

language = "English",

volume = "56",

pages = "429--435",

journal = "Russian Journal of Organic Chemistry",

issn = "1070-4280",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "3",

}

RIS

TY - JOUR

T1 - Skeletal Transformations of the Arylation Products of Perfluoro(1,2-diethylbenzocyclobutene) with Tetrafluorobenzenes in the Presence of SbF5

AU - Mezhenkova, T. V.

AU - Sinyakov, V. R.

AU - Karpov, V. M.

AU - Zonov, Ya V.

PY - 2020/3

Y1 - 2020/3

N2 - Abstract: The reaction of perfluoro(1,2-diethylbenzocyclobutene) with1,2,4,5-tetrafluorobenzene in SbF5, followed byhydrolysis, gave products resulting from expansion of the tetrafluorophenyl ringto cycloheptatriene. The title compound reacted with 1,2,3,5-tetrafluorobenzeneto form products of opening of the four-membered ring. A similar reaction with1,2,3,4-tetrafluorobenzene involved opening of the cyclobutane ring togetherwith the formation of perfluoro(9,10-diethyl-9.10-dihydroanthracene)derivatives.

AB - Abstract: The reaction of perfluoro(1,2-diethylbenzocyclobutene) with1,2,4,5-tetrafluorobenzene in SbF5, followed byhydrolysis, gave products resulting from expansion of the tetrafluorophenyl ringto cycloheptatriene. The title compound reacted with 1,2,3,5-tetrafluorobenzeneto form products of opening of the four-membered ring. A similar reaction with1,2,3,4-tetrafluorobenzene involved opening of the cyclobutane ring togetherwith the formation of perfluoro(9,10-diethyl-9.10-dihydroanthracene)derivatives.

KW - antimony pentafluoride

KW - cation

KW - perfluoro(1,2-diethylcyclobutabenzene)

KW - skeletal transformations

KW - tetrafluorobenzene

KW - perfluoro(1

KW - PENTAFLUOROBENZENE RING

KW - 2-diethylcyclobutabenzene)

KW - EXPANSION

KW - FLUORINE-CONTAINING CARBOCATIONS

UR - http://www.scopus.com/inward/record.url?scp=85083672795&partnerID=8YFLogxK

U2 - 10.1134/S1070428020030100

DO - 10.1134/S1070428020030100

M3 - Article

AN - SCOPUS:85083672795

VL - 56

SP - 429

EP - 435

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 3

ER -

ID: 24093967