Single-Site Heterogeneous Catalysts

Standard

Single-Site Heterogeneous Catalysts : From Synthesis to NMR Signal Enhancement. / Burueva, Dudari B.; Kovtunova, Larisa M.; Bukhtiyarov, Valerii I. et al.

In: Chemistry - A European Journal, Vol. 25, No. 6, 28.01.2019, p. 1420-1431.

Research output: Contribution to journal › Review article › peer-review

Harvard

Burueva, DB , Kovtunova, LM , Bukhtiyarov, VI, Kovtunov, KV & Koptyug, IV 2019, 'Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement', Chemistry - A European Journal, vol. 25, no. 6, pp. 1420-1431. https://doi.org/10.1002/chem.201803515

APA

Burueva, D. B., Kovtunova, L. M., Bukhtiyarov, V. I., Kovtunov, K. V., & Koptyug, I. V. (2019). Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement. Chemistry - A European Journal, 25(6), 1420-1431. https://doi.org/10.1002/chem.201803515

Vancouver

Burueva DB , Kovtunova LM , Bukhtiyarov VI, Kovtunov KV, Koptyug IV. Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement. Chemistry - A European Journal. 2019 Jan 28;25(6):1420-1431. doi: 10.1002/chem.201803515

Author

Burueva, Dudari B. ; Kovtunova, Larisa M. ; Bukhtiyarov, Valerii I. et al. / Single-Site Heterogeneous Catalysts : From Synthesis to NMR Signal Enhancement. In: Chemistry - A European Journal. 2019 ; Vol. 25, No. 6. pp. 1420-1431.

BibTeX

@article{c58486f6f3504f148bbcb2cb4f8a0fcb,

title = "Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement",

abstract = "Catalysts with well-defined, single, active centers are of great importance and their utilization allows the gap between homo- and heterogeneous catalysis to be bridged and, importantly, the main selectivity problem of heterogeneous catalysis and the main separation challenge of homogeneous catalysis to be overcome. Moreover, the use of single-site catalysts allows the NMR signal to be significantly enhanced through the pairwise addition of two hydrogen atoms from a parahydrogen molecule to an unsaturated substrate. This review covers the fundamentals of the synthesis of single-site catalysts and shows the new aspects of their applications in both modern catalysis and the field of parahydrogen-based hyperpolarization. The different novel aspects of the formation and utilization of single-site catalysts, along with the possibility of NMR signal enhancement observations are described.",

keywords = "heterogeneous catalysis, homogeneous catalysis, imaging agents, NMR spectroscopy, supported catalysts, SURFACE ORGANOMETALLIC CHEMISTRY, SUPPORT INTERACTIONS, METAL-ORGANIC FRAMEWORK, C-H ACTIVATION, PREFERENTIAL OXIDATION, SELECTIVE PROPANE DEHYDROGENATION, SUZUKI-MIYAURA, HYDROGEN INDUCED POLARIZATION, PARAHYDROGEN-INDUCED POLARIZATION, IN-A-BOTTLE",

author = "Burueva, {Dudari B.} and Kovtunova, {Larisa M.} and Bukhtiyarov, {Valerii I.} and Kovtunov, {Kirill V.} and Koptyug, {Igor V.}",

note = "{\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2019",

month = jan,

day = "28",

doi = "10.1002/chem.201803515",

language = "English",

volume = "25",

pages = "1420--1431",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "6",

}

RIS

TY - JOUR

T1 - Single-Site Heterogeneous Catalysts

T2 - From Synthesis to NMR Signal Enhancement

AU - Burueva, Dudari B.

AU - Kovtunova, Larisa M.

AU - Bukhtiyarov, Valerii I.

AU - Kovtunov, Kirill V.

AU - Koptyug, Igor V.

PY - 2019/1/28

Y1 - 2019/1/28

N2 - Catalysts with well-defined, single, active centers are of great importance and their utilization allows the gap between homo- and heterogeneous catalysis to be bridged and, importantly, the main selectivity problem of heterogeneous catalysis and the main separation challenge of homogeneous catalysis to be overcome. Moreover, the use of single-site catalysts allows the NMR signal to be significantly enhanced through the pairwise addition of two hydrogen atoms from a parahydrogen molecule to an unsaturated substrate. This review covers the fundamentals of the synthesis of single-site catalysts and shows the new aspects of their applications in both modern catalysis and the field of parahydrogen-based hyperpolarization. The different novel aspects of the formation and utilization of single-site catalysts, along with the possibility of NMR signal enhancement observations are described.

AB - Catalysts with well-defined, single, active centers are of great importance and their utilization allows the gap between homo- and heterogeneous catalysis to be bridged and, importantly, the main selectivity problem of heterogeneous catalysis and the main separation challenge of homogeneous catalysis to be overcome. Moreover, the use of single-site catalysts allows the NMR signal to be significantly enhanced through the pairwise addition of two hydrogen atoms from a parahydrogen molecule to an unsaturated substrate. This review covers the fundamentals of the synthesis of single-site catalysts and shows the new aspects of their applications in both modern catalysis and the field of parahydrogen-based hyperpolarization. The different novel aspects of the formation and utilization of single-site catalysts, along with the possibility of NMR signal enhancement observations are described.

KW - heterogeneous catalysis

KW - homogeneous catalysis

KW - imaging agents

KW - NMR spectroscopy

KW - supported catalysts

KW - SURFACE ORGANOMETALLIC CHEMISTRY

KW - SUPPORT INTERACTIONS

KW - METAL-ORGANIC FRAMEWORK

KW - C-H ACTIVATION

KW - PREFERENTIAL OXIDATION

KW - SELECTIVE PROPANE DEHYDROGENATION

KW - SUZUKI-MIYAURA

KW - HYDROGEN INDUCED POLARIZATION

KW - PARAHYDROGEN-INDUCED POLARIZATION

KW - IN-A-BOTTLE

UR - http://www.scopus.com/inward/record.url?scp=85056829703&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1cdfd246-320a-3a01-9bce-6ba329f9200f/

U2 - 10.1002/chem.201803515

DO - 10.1002/chem.201803515

M3 - Review article

C2 - 30095187

AN - SCOPUS:85056829703

VL - 25

SP - 1420

EP - 1431

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 6

ER -

ID: 17509270