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Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations. / Ikeya, Noboru; Nasibulov, Egor A.; Ivanov, Konstantin L. et al.

In: Molecular Physics, Vol. 117, No. 19, 02.10.2019, p. 2604-2617.

Research output: Contribution to journal › Article › peer-review

Harvard

Ikeya, N, Nasibulov, EA, Ivanov, KL, Maeda, K & Woodward, JR 2019, 'Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations', Molecular Physics, vol. 117, no. 19, pp. 2604-2617. https://doi.org/10.1080/00268976.2018.1559954

APA

Ikeya, N., Nasibulov, E. A., Ivanov, K. L., Maeda, K., & Woodward, J. R. (2019). Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations. Molecular Physics, 117(19), 2604-2617. https://doi.org/10.1080/00268976.2018.1559954

Vancouver

Ikeya N, Nasibulov EA, Ivanov KL, Maeda K, Woodward JR. Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations. Molecular Physics. 2019 Oct 2;117(19):2604-2617. doi: 10.1080/00268976.2018.1559954

Author

Ikeya, Noboru ; Nasibulov, Egor A. ; Ivanov, Konstantin L. et al. / Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations. In: Molecular Physics. 2019 ; Vol. 117, No. 19. pp. 2604-2617.

BibTeX

@article{62376707b25341a0a6981835047f5479,
title = "Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations",
abstract = "In this work, we propose to extend the scope of single-molecule spectroscopy to spin chemistry investigations of single radical pairs. A consistent theory of single-molecule spectroscopy on single radical pairs is proposed, which allows one to show that bunching phenomena are affected by singlet–triplet interconversion in radical pairs, which is, in turn, affected by local and external magnetic fields. A detailed study on the feasibility of such experiments with single flavin adenine dinucleotide, FAD, molecules is presented. We conclude that the observation of magnetic field effects on single FAD molecules is feasible but experimentally challenging for measurements on integrated fluorescence intensity and fluorescence event statistics.",
keywords = "flavin adenine dinucleotide, magnetic field effects, radical pairs, Single molecule spectroscopy, CONSISTENT, OPTICAL-DETECTION, FLUORESCENCE SPECTROSCOPY, KINETICS, MAGNETIC-RESONANCE, CHEMISTRY, DYNAMICS, ABSORPTION",
author = "Noboru Ikeya and Nasibulov, {Egor A.} and Ivanov, {Konstantin L.} and Kiminori Maeda and Woodward, {Jonathan R.}",
year = "2019",
month = oct,
day = "2",
doi = "10.1080/00268976.2018.1559954",
language = "English",
volume = "117",
pages = "2604--2617",
journal = "Molecular Physics",
issn = "0026-8976",
publisher = "Taylor and Francis Ltd.",
number = "19",

}

RIS

TY - JOUR

T1 - Single-molecule spectroscopy of radical pairs, a theoretical treatment and experimental considerations

AU - Ikeya, Noboru

AU - Nasibulov, Egor A.

AU - Ivanov, Konstantin L.

AU - Maeda, Kiminori

AU - Woodward, Jonathan R.

PY - 2019/10/2

Y1 - 2019/10/2

N2 - In this work, we propose to extend the scope of single-molecule spectroscopy to spin chemistry investigations of single radical pairs. A consistent theory of single-molecule spectroscopy on single radical pairs is proposed, which allows one to show that bunching phenomena are affected by singlet–triplet interconversion in radical pairs, which is, in turn, affected by local and external magnetic fields. A detailed study on the feasibility of such experiments with single flavin adenine dinucleotide, FAD, molecules is presented. We conclude that the observation of magnetic field effects on single FAD molecules is feasible but experimentally challenging for measurements on integrated fluorescence intensity and fluorescence event statistics.

AB - In this work, we propose to extend the scope of single-molecule spectroscopy to spin chemistry investigations of single radical pairs. A consistent theory of single-molecule spectroscopy on single radical pairs is proposed, which allows one to show that bunching phenomena are affected by singlet–triplet interconversion in radical pairs, which is, in turn, affected by local and external magnetic fields. A detailed study on the feasibility of such experiments with single flavin adenine dinucleotide, FAD, molecules is presented. We conclude that the observation of magnetic field effects on single FAD molecules is feasible but experimentally challenging for measurements on integrated fluorescence intensity and fluorescence event statistics.

KW - flavin adenine dinucleotide

KW - magnetic field effects

KW - radical pairs

KW - Single molecule spectroscopy

KW - CONSISTENT

KW - OPTICAL-DETECTION

KW - FLUORESCENCE SPECTROSCOPY

KW - KINETICS

KW - MAGNETIC-RESONANCE

KW - CHEMISTRY

KW - DYNAMICS

KW - ABSORPTION

UR - http://www.scopus.com/inward/record.url?scp=85059063625&partnerID=8YFLogxK

U2 - 10.1080/00268976.2018.1559954

DO - 10.1080/00268976.2018.1559954

M3 - Article

AN - SCOPUS:85059063625

VL - 117

SP - 2604

EP - 2617

JO - Molecular Physics

JF - Molecular Physics

SN - 0026-8976

IS - 19

ER -

ID: 18065602