Standard

Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module. / Zazhigalov, S. V.; Rogozhnikov, V. N.; Snytnikov, P. V. et al.

In: Chemical Engineering and Processing - Process Intensification, Vol. 150, 107876, 04.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Zazhigalov, SV, Rogozhnikov, VN, Snytnikov, PV, Potemkin, DI, Simonov, PA, Shilov, VA, Ruban, NV, Kulikov, AV, Zagoruiko, AN & Sobyanin, VA 2020, 'Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module', Chemical Engineering and Processing - Process Intensification, vol. 150, 107876. https://doi.org/10.1016/j.cep.2020.107876

APA

Zazhigalov, S. V., Rogozhnikov, V. N., Snytnikov, P. V., Potemkin, D. I., Simonov, P. A., Shilov, V. A., Ruban, N. V., Kulikov, A. V., Zagoruiko, A. N., & Sobyanin, V. A. (2020). Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module. Chemical Engineering and Processing - Process Intensification, 150, [107876]. https://doi.org/10.1016/j.cep.2020.107876

Vancouver

Zazhigalov SV, Rogozhnikov VN, Snytnikov PV, Potemkin DI, Simonov PA, Shilov VA et al. Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module. Chemical Engineering and Processing - Process Intensification. 2020 Apr;150:107876. doi: 10.1016/j.cep.2020.107876

Author

Zazhigalov, S. V. ; Rogozhnikov, V. N. ; Snytnikov, P. V. et al. / Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module. In: Chemical Engineering and Processing - Process Intensification. 2020 ; Vol. 150.

BibTeX

@article{7bbd7cfdb80f46969259202cf195ab31,
title = "Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module",
abstract = "The study was dedicated to the mathematical modeling of the catalytic autothermal reforming (ATR) of diesel fuel – effective method for hydrogen production. The structured wire mesh Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl catalyst was tested in pilot scale reactor and showed high efficiency in studied diesel autothermal reaction conditions. The process simulation was carried out by commercial software COMSOL Multiphysics in 2D axisymmetric geometry. The catalyst module was simulated as homogeneous porous medium. Reaction model included diesel oxidation, diesel steam reforming, water-gas shift reaction, CO methanation, CO oxidation and hydrogen oxidation. Fitting the experimental results including product distribution and temperature profile allowed to define the kinetic parameters corresponding to the best fit. The suggested simple quasi-homogeneous model describes experimental results (module temperature and outlet gas composition) with a good accuracy and could be used for process optimization and up-scaling.",
keywords = "Autothermal reforming, Diesel, rhodium, Structured catalyst, wire metal mesh, Zirconia-ceria, SYSTEM, RICH GAS-PRODUCTION, DESIGN, NATURAL-GAS, REACTOR, RH, FUEL, HYDROGEN-PRODUCTION, N-DODECANE, PARTIAL OXIDATION",
author = "Zazhigalov, {S. V.} and Rogozhnikov, {V. N.} and Snytnikov, {P. V.} and Potemkin, {D. I.} and Simonov, {P. A.} and Shilov, {V. A.} and Ruban, {N. V.} and Kulikov, {A. V.} and Zagoruiko, {A. N.} and Sobyanin, {V. A.}",
year = "2020",
month = apr,
doi = "10.1016/j.cep.2020.107876",
language = "English",
volume = "150",
journal = "Chemical Engineering and Processing - Process Intensification",
issn = "0255-2701",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Simulation of diesel autothermal reforming over Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl wire mesh honeycomb catalytic module

AU - Zazhigalov, S. V.

AU - Rogozhnikov, V. N.

AU - Snytnikov, P. V.

AU - Potemkin, D. I.

AU - Simonov, P. A.

AU - Shilov, V. A.

AU - Ruban, N. V.

AU - Kulikov, A. V.

AU - Zagoruiko, A. N.

AU - Sobyanin, V. A.

PY - 2020/4

Y1 - 2020/4

N2 - The study was dedicated to the mathematical modeling of the catalytic autothermal reforming (ATR) of diesel fuel – effective method for hydrogen production. The structured wire mesh Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl catalyst was tested in pilot scale reactor and showed high efficiency in studied diesel autothermal reaction conditions. The process simulation was carried out by commercial software COMSOL Multiphysics in 2D axisymmetric geometry. The catalyst module was simulated as homogeneous porous medium. Reaction model included diesel oxidation, diesel steam reforming, water-gas shift reaction, CO methanation, CO oxidation and hydrogen oxidation. Fitting the experimental results including product distribution and temperature profile allowed to define the kinetic parameters corresponding to the best fit. The suggested simple quasi-homogeneous model describes experimental results (module temperature and outlet gas composition) with a good accuracy and could be used for process optimization and up-scaling.

AB - The study was dedicated to the mathematical modeling of the catalytic autothermal reforming (ATR) of diesel fuel – effective method for hydrogen production. The structured wire mesh Rh/Ce0.75Zr0.25O2-δ-η-Al2O3/FeCrAl catalyst was tested in pilot scale reactor and showed high efficiency in studied diesel autothermal reaction conditions. The process simulation was carried out by commercial software COMSOL Multiphysics in 2D axisymmetric geometry. The catalyst module was simulated as homogeneous porous medium. Reaction model included diesel oxidation, diesel steam reforming, water-gas shift reaction, CO methanation, CO oxidation and hydrogen oxidation. Fitting the experimental results including product distribution and temperature profile allowed to define the kinetic parameters corresponding to the best fit. The suggested simple quasi-homogeneous model describes experimental results (module temperature and outlet gas composition) with a good accuracy and could be used for process optimization and up-scaling.

KW - Autothermal reforming

KW - Diesel

KW - rhodium

KW - Structured catalyst

KW - wire metal mesh

KW - Zirconia-ceria

KW - SYSTEM

KW - RICH GAS-PRODUCTION

KW - DESIGN

KW - NATURAL-GAS

KW - REACTOR

KW - RH

KW - FUEL

KW - HYDROGEN-PRODUCTION

KW - N-DODECANE

KW - PARTIAL OXIDATION

UR - http://www.scopus.com/inward/record.url?scp=85080992160&partnerID=8YFLogxK

U2 - 10.1016/j.cep.2020.107876

DO - 10.1016/j.cep.2020.107876

M3 - Article

AN - SCOPUS:85080992160

VL - 150

JO - Chemical Engineering and Processing - Process Intensification

JF - Chemical Engineering and Processing - Process Intensification

SN - 0255-2701

M1 - 107876

ER -

ID: 23719611