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Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole. / Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A. et al.

In: Inorganic Chemistry, Vol. 60, No. 19, 04.10.2021, p. 14687-14696.

Research output: Contribution to journal › Article › peer-review

Harvard

Konovalov, DI, Ivanov, AA, Vorotnikov, YA, Kuratieva, NV, Eltsov, IV, Kovalenko, KA & Shestopalov, MA 2021, 'Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole', Inorganic Chemistry, vol. 60, no. 19, pp. 14687-14696. https://doi.org/10.1021/acs.inorgchem.1c01771

APA

Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Kuratieva, N. V., Eltsov, I. V., Kovalenko, K. A., & Shestopalov, M. A. (2021). Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole. Inorganic Chemistry, 60(19), 14687-14696. https://doi.org/10.1021/acs.inorgchem.1c01771

Vancouver

Konovalov DI, Ivanov AA, Vorotnikov YA, Kuratieva NV, Eltsov IV, Kovalenko KA et al. Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole. Inorganic Chemistry. 2021 Oct 4;60(19):14687-14696. Epub 2021 Sept 13. doi: 10.1021/acs.inorgchem.1c01771

Author

Konovalov, Dmitry I. ; Ivanov, Anton A. ; Vorotnikov, Yuri A. et al. / Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole. In: Inorganic Chemistry. 2021 ; Vol. 60, No. 19. pp. 14687-14696.

BibTeX

@article{078250c8c0494532998ab8515dc0ab91,
title = "Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole",
abstract = "Substitution of apical halide ligands in [{Re6Sei8}Xa6]3- (X = Cl, Br) by benzimidazole (bimzH) accompanied by a self-assembly process leads to the formation of microporous Re6-based hydrogen-bonded organic frameworks (Re6-HOFs) constructed on N-H···X hydrogen bonds and π- π-stacking interactions between bimzH ligands. Re6-HOFs demonstrate sorption properties with a Brunauer-Emmett-Teller surface area of up to 443 m2 g-1 and luminescence with a quantum yield and an emission lifetime of up to 0.16 and 16 μs, respectively. The compounds obtained complement small groups of transition-metal cluster-based HOFs, which are a perspective for the development of multifunctional frameworks. ",
author = "Konovalov, {Dmitry I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Kuratieva, {Natalia V.} and Eltsov, {Ilia V.} and Kovalenko, {Konstantin A.} and Shestopalov, {Michael A.}",
note = "Funding Information: The work was supported by the Russian Science Foundation (Grant 20-73-00147) and the Ministry of Science and Higher Education of the Russian Federation (Grants 121031700321-3 and 121031700313-8). Publisher Copyright: {\textcopyright}",
year = "2021",
month = oct,
day = "4",
doi = "10.1021/acs.inorgchem.1c01771",
language = "English",
volume = "60",
pages = "14687--14696",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "19",

}

RIS

TY - JOUR

T1 - Self-Assembled Microporous M-HOFs Based on an Octahedral Rhenium Cluster with Benzimidazole

AU - Konovalov, Dmitry I.

AU - Ivanov, Anton A.

AU - Vorotnikov, Yuri A.

AU - Kuratieva, Natalia V.

AU - Eltsov, Ilia V.

AU - Kovalenko, Konstantin A.

AU - Shestopalov, Michael A.

N1 - Funding Information: The work was supported by the Russian Science Foundation (Grant 20-73-00147) and the Ministry of Science and Higher Education of the Russian Federation (Grants 121031700321-3 and 121031700313-8). Publisher Copyright: ©

PY - 2021/10/4

Y1 - 2021/10/4

N2 - Substitution of apical halide ligands in [{Re6Sei8}Xa6]3- (X = Cl, Br) by benzimidazole (bimzH) accompanied by a self-assembly process leads to the formation of microporous Re6-based hydrogen-bonded organic frameworks (Re6-HOFs) constructed on N-H···X hydrogen bonds and π- π-stacking interactions between bimzH ligands. Re6-HOFs demonstrate sorption properties with a Brunauer-Emmett-Teller surface area of up to 443 m2 g-1 and luminescence with a quantum yield and an emission lifetime of up to 0.16 and 16 μs, respectively. The compounds obtained complement small groups of transition-metal cluster-based HOFs, which are a perspective for the development of multifunctional frameworks.

AB - Substitution of apical halide ligands in [{Re6Sei8}Xa6]3- (X = Cl, Br) by benzimidazole (bimzH) accompanied by a self-assembly process leads to the formation of microporous Re6-based hydrogen-bonded organic frameworks (Re6-HOFs) constructed on N-H···X hydrogen bonds and π- π-stacking interactions between bimzH ligands. Re6-HOFs demonstrate sorption properties with a Brunauer-Emmett-Teller surface area of up to 443 m2 g-1 and luminescence with a quantum yield and an emission lifetime of up to 0.16 and 16 μs, respectively. The compounds obtained complement small groups of transition-metal cluster-based HOFs, which are a perspective for the development of multifunctional frameworks.

UR - http://www.scopus.com/inward/record.url?scp=85115913429&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.1c01771

DO - 10.1021/acs.inorgchem.1c01771

M3 - Article

C2 - 34516105

AN - SCOPUS:85115913429

VL - 60

SP - 14687

EP - 14696

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 19

ER -

ID: 34348562