Research output: Contribution to journal › Article › peer-review
Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophilesviaa 1,2-dithioethane intermediate. / Wang, Yuna; Qi, Zaojuan; Niu, Yanning et al.
In: Chemical Communications, Vol. 57, No. 61, 29.07.2021, p. 7533-7536.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Selective oxidative intermolecular carbosulphenylation of aryl alkenes with thiols and nucleophilesviaa 1,2-dithioethane intermediate
AU - Wang, Yuna
AU - Qi, Zaojuan
AU - Niu, Yanning
AU - Feng, Hua
AU - Benassi, Enrico
AU - Qian, Bo
N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.
PY - 2021/7/29
Y1 - 2021/7/29
N2 - A periodate lithium-oxidized difunctionalisation of aryl alkenes with thiols and electron-rich aromatics was achieved, selectively affording more than thirty carbosulphenylated products. Both experiments and quantum chemical calculations demonstrated the radical-polar nature of the processes, and that 1,2-dithioethane and thiiranium ions might play the role of intermediates.
AB - A periodate lithium-oxidized difunctionalisation of aryl alkenes with thiols and electron-rich aromatics was achieved, selectively affording more than thirty carbosulphenylated products. Both experiments and quantum chemical calculations demonstrated the radical-polar nature of the processes, and that 1,2-dithioethane and thiiranium ions might play the role of intermediates.
UR - http://www.scopus.com/inward/record.url?scp=85111604226&partnerID=8YFLogxK
U2 - 10.1039/d1cc02517a
DO - 10.1039/d1cc02517a
M3 - Article
C2 - 34236369
AN - SCOPUS:85111604226
VL - 57
SP - 7533
EP - 7536
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 61
ER -
ID: 29281809