Research output: Contribution to journal › Article › peer-review
Selective oxidation of CO in the presence of propylene over Ag/MCM-41 catalyst. / Mamontov, G. V.; Gorbunova, A. S.; Vyshegorodtseva, E. V. et al.
In: Catalysis Today, Vol. 333, 01.08.2019, p. 245-250.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Selective oxidation of CO in the presence of propylene over Ag/MCM-41 catalyst
AU - Mamontov, G. V.
AU - Gorbunova, A. S.
AU - Vyshegorodtseva, E. V.
AU - Zaikovskii, V. I.
AU - Vodyankina, O. V.
N1 - Publisher Copyright: © 2018 Elsevier B.V.
PY - 2019/8/1
Y1 - 2019/8/1
N2 - Ag/MCM-41 catalyst is prepared by impregnation technique and characterized by low-temperature N2 sorption, XRD, TPR and TEM methods. The ordered structure of mesoporous silicate MCM-41 is used as a nanoreactor to synthesize and stabilize small Ag nanoparticles. Two types of Ag particles are shown to form in Ag/MCM-41 catalyst: ultrasmall (<3 nm) inside pores of support and large (4–8 nm) on the external surface of the MCM-41. Catalytic tests in oxidation mixture containing 1% CO and 1% propylene show that Ag/MCM-41 catalyst can be used for selective oxidation of CO in the presence of propylene from 91 °C (CO conversion > 98%) to 217 °C (conversion of propylene < 5%). The catalyst can be used for purification of hydrocarbons from CO by selective oxidation of second.
AB - Ag/MCM-41 catalyst is prepared by impregnation technique and characterized by low-temperature N2 sorption, XRD, TPR and TEM methods. The ordered structure of mesoporous silicate MCM-41 is used as a nanoreactor to synthesize and stabilize small Ag nanoparticles. Two types of Ag particles are shown to form in Ag/MCM-41 catalyst: ultrasmall (<3 nm) inside pores of support and large (4–8 nm) on the external surface of the MCM-41. Catalytic tests in oxidation mixture containing 1% CO and 1% propylene show that Ag/MCM-41 catalyst can be used for selective oxidation of CO in the presence of propylene from 91 °C (CO conversion > 98%) to 217 °C (conversion of propylene < 5%). The catalyst can be used for purification of hydrocarbons from CO by selective oxidation of second.
KW - Ag/MCM-41 catalyst
KW - Purification of propylene
KW - Selective CO oxidation
KW - Ultrasmall Ag particles
KW - SILVER
KW - MOLECULAR-SIEVES
KW - MCM-41
KW - ADSORPTION
KW - PRETREATMENT CONDITIONS
KW - PREFERENTIAL OXIDATION
KW - AG/SIO2 CATALYSTS
KW - CARBON-MONOXIDE OXIDATION
KW - RECENT PROGRESS
KW - ETHYLENE HYDROGENATION
UR - http://www.scopus.com/inward/record.url?scp=85046730270&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2018.05.015
DO - 10.1016/j.cattod.2018.05.015
M3 - Article
AN - SCOPUS:85046730270
VL - 333
SP - 245
EP - 250
JO - Catalysis Today
JF - Catalysis Today
SN - 0920-5861
ER -
ID: 13360567