Research output: Contribution to journal › Article › peer-review
Same spectral signature in liquid-state and solid-state 1H photo-CIDNP NMR spectra of cyclohexanone. / Panov, Mikhail; Bielytskyi, Pavlo; Gräsing, Daniel et al.
In: Molecular Physics, Vol. 117, No. 19, 02.10.2019, p. 2756-2761.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Same spectral signature in liquid-state and solid-state 1H photo-CIDNP NMR spectra of cyclohexanone
AU - Panov, Mikhail
AU - Bielytskyi, Pavlo
AU - Gräsing, Daniel
AU - Yurkovskaya, Alexandra
AU - Matysik, Jörg
N1 - Publisher Copyright: © 2018, © 2018 Informa UK Limited, trading as Taylor & Francis Group.
PY - 2019/10/2
Y1 - 2019/10/2
N2 - For the first time, a 1H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d8 under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by 1H liquid-state photo-CIDNP NMR.
AB - For the first time, a 1H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d8 under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by 1H liquid-state photo-CIDNP NMR.
KW - aliphatic ketones
KW - Biradicals
KW - exchange interaction
KW - hyperpolarisation
KW - magic-angle spinning
KW - MAS
KW - norrish type I photo-reaction
KW - PHOTOSYNTHETIC REACTION CENTERS
KW - BACTERIA
KW - MECHANISM
KW - ELECTRON-DONOR
KW - MAGNETIC-FIELD DEPENDENCE
KW - PHASE
KW - DYNAMIC NUCLEAR-POLARIZATION
KW - BIRADICALS
KW - MAS NMR
UR - http://www.scopus.com/inward/record.url?scp=85071370928&partnerID=8YFLogxK
U2 - 10.1080/00268976.2018.1512722
DO - 10.1080/00268976.2018.1512722
M3 - Article
AN - SCOPUS:85071370928
VL - 117
SP - 2756
EP - 2761
JO - Molecular Physics
JF - Molecular Physics
SN - 0026-8976
IS - 19
ER -
ID: 21346166