Research output: Contribution to journal › Article › peer-review
Ruthenium promoted cobalt–alumina catalysts for the synthesis of high-molecular-weight solid hydrocarbons from CO and hydrogen. / Kungurova, O. A.; Shtertser, N. V.; Chermashentseva, G. K. et al.
In: Catalysis in Industry, Vol. 9, No. 1, 01.01.2017, p. 23-30.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Ruthenium promoted cobalt–alumina catalysts for the synthesis of high-molecular-weight solid hydrocarbons from CO and hydrogen
AU - Kungurova, O. A.
AU - Shtertser, N. V.
AU - Chermashentseva, G. K.
AU - Simentsova, I. I.
AU - Khassin, A. A.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - The effect of the ruthenium promotion of Fischer–Tropsch (FT) cobalt–alumina catalysts on the temperature of catalyst activation reduction and catalytic properties in the FT process is studied. The addition of 0.2–1 wt % of ruthenium reduces the temperature of reduction activation from 500 to 330–350°C while preserving the catalytic activity and selectivity toward C5+ products in FT synthesis. FT ruthenium-promoted Co–Al catalysts are more selective toward higher hydrocarbons; the experimental value of parameter αASF of the distribution of paraffinic products for ruthenium-promoted catalysts is 0.93–0.94, allowing us to estimate the selectivity toward C20+ synthetic waxes to be 48 wt %, and the selectivity toward C35+ waxes to be 23 wt %. Ruthenium-promoted catalysts also exhibit high selectivity toward olefins.
AB - The effect of the ruthenium promotion of Fischer–Tropsch (FT) cobalt–alumina catalysts on the temperature of catalyst activation reduction and catalytic properties in the FT process is studied. The addition of 0.2–1 wt % of ruthenium reduces the temperature of reduction activation from 500 to 330–350°C while preserving the catalytic activity and selectivity toward C5+ products in FT synthesis. FT ruthenium-promoted Co–Al catalysts are more selective toward higher hydrocarbons; the experimental value of parameter αASF of the distribution of paraffinic products for ruthenium-promoted catalysts is 0.93–0.94, allowing us to estimate the selectivity toward C20+ synthetic waxes to be 48 wt %, and the selectivity toward C35+ waxes to be 23 wt %. Ruthenium-promoted catalysts also exhibit high selectivity toward olefins.
KW - cobalt catalysts
KW - Fischer–Tropsch synthesis
KW - promotion
KW - reductive activation
KW - ruthenium
KW - OXIDE
KW - PRODUCT DISTRIBUTION
KW - STATE
KW - REDUCIBILITY
KW - SUPPORT
KW - Fischer-Tropsch synthesis
KW - KINETICS
KW - GAS
KW - FISCHER-TROPSCH SYNTHESIS
UR - http://www.scopus.com/inward/record.url?scp=85017164440&partnerID=8YFLogxK
U2 - 10.1134/S2070050417010081
DO - 10.1134/S2070050417010081
M3 - Article
AN - SCOPUS:85017164440
VL - 9
SP - 23
EP - 30
JO - Catalysis in Industry
JF - Catalysis in Industry
SN - 2070-0504
IS - 1
ER -
ID: 10265562