Research output: Contribution to journal › Article › peer-review
Rule, Not Exclusion : Formation of Dichlorine-Containing Supramolecular Complexes with Chlorometalates(IV). / Usoltsev, Andrey N.; Korobeynikov, Nikita A.; Kolesov, Boris A. et al.
In: Inorganic Chemistry, Vol. 60, No. 6, 15.03.2021, p. 4171-4177.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Rule, Not Exclusion
T2 - Formation of Dichlorine-Containing Supramolecular Complexes with Chlorometalates(IV)
AU - Usoltsev, Andrey N.
AU - Korobeynikov, Nikita A.
AU - Kolesov, Boris A.
AU - Novikov, Alexander S.
AU - Samsonenko, Denis G.
AU - Fedin, Vladimir P.
AU - Sokolov, Maxim N.
AU - Adonin, Sergey A.
N1 - Publisher Copyright: © 2021 American Chemical Society. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/3/15
Y1 - 2021/3/15
N2 - Supramolecular derivatives of chlorostannate(IV) and -plumbate(IV) with {Cl2} units, Cat2{[MCl6](Cl2)x} (1-5; M = Sn, Pb, cat = 1-methylpyridinium (1-MePy), tetramethylammonium (TMA)) were prepared and characterized by X-ray diffractometry and Raman spectroscopy. In particular, the TMA-containing complexes demonstrate remarkable thermal stability, releasing Cl2 only at elevated temperatures.
AB - Supramolecular derivatives of chlorostannate(IV) and -plumbate(IV) with {Cl2} units, Cat2{[MCl6](Cl2)x} (1-5; M = Sn, Pb, cat = 1-methylpyridinium (1-MePy), tetramethylammonium (TMA)) were prepared and characterized by X-ray diffractometry and Raman spectroscopy. In particular, the TMA-containing complexes demonstrate remarkable thermal stability, releasing Cl2 only at elevated temperatures.
UR - http://www.scopus.com/inward/record.url?scp=85102964583&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.1c00436
DO - 10.1021/acs.inorgchem.1c00436
M3 - Article
C2 - 33626273
AN - SCOPUS:85102964583
VL - 60
SP - 4171
EP - 4177
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 6
ER -
ID: 28142901