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Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes. / Mikhailov, Artem A.; Wenger, Emmanuel; Kostin, Gennadiy A. et al.

In: Chemistry - A European Journal, Vol. 25, No. 31, 04.06.2019, p. 7569-7574.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhailov, AA, Wenger, E, Kostin, GA & Schaniel, D 2019, 'Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes', Chemistry - A European Journal, vol. 25, no. 31, pp. 7569-7574. https://doi.org/10.1002/chem.201901205

APA

Mikhailov, A. A., Wenger, E., Kostin, G. A., & Schaniel, D. (2019). Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes. Chemistry - A European Journal, 25(31), 7569-7574. https://doi.org/10.1002/chem.201901205

Vancouver

Mikhailov AA, Wenger E, Kostin GA, Schaniel D. Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes. Chemistry - A European Journal. 2019 Jun 4;25(31):7569-7574. doi: 10.1002/chem.201901205

Author

Mikhailov, Artem A. ; Wenger, Emmanuel ; Kostin, Gennadiy A. et al. / Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes. In: Chemistry - A European Journal. 2019 ; Vol. 25, No. 31. pp. 7569-7574.

BibTeX

@article{2d9f54abe39a4eafa2533c055eddea9a,
title = "Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes",
abstract = " The conditions for the photogeneration of NO linkage isomers at room temperature are studied. By pulsed laser irradiation in the blue spectral range, the long-lived Ru−ON isomer can be generated at room temperature, which is crucial for potential applications, such as holography and data storage. By using static and time-resolved spectroscopy (UV/Vis and IR), we give evidence that the liftime of the Ru−(η 2 -(NO)) isomer is a decisive parameter for the formation of the Ru−ON isomer at high temperature owing to a two-step isomerization mechanism Ru−NO→Ru−(η 2 -(NO))→Ru−ON. Furthermore, we report the low-temperature structures for each isomer, which were revealed by photocrystallography. ",
keywords = "nitrosyl, photochemistry, photocrystallography, ruthenium, UV/Vis spectroscopy, MECHANISM, METASTABLE STATES",
author = "Mikhailov, {Artem A.} and Emmanuel Wenger and Kostin, {Gennadiy A.} and Dominik Schaniel",
note = "{\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2019",
month = jun,
day = "4",
doi = "10.1002/chem.201901205",
language = "English",
volume = "25",
pages = "7569--7574",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "31",

}

RIS

TY - JOUR

T1 - Room-Temperature Photogeneration of Nitrosyl Linkage Isomers in Ruthenium Nitrosyl Complexes

AU - Mikhailov, Artem A.

AU - Wenger, Emmanuel

AU - Kostin, Gennadiy A.

AU - Schaniel, Dominik

N1 - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2019/6/4

Y1 - 2019/6/4

N2 - The conditions for the photogeneration of NO linkage isomers at room temperature are studied. By pulsed laser irradiation in the blue spectral range, the long-lived Ru−ON isomer can be generated at room temperature, which is crucial for potential applications, such as holography and data storage. By using static and time-resolved spectroscopy (UV/Vis and IR), we give evidence that the liftime of the Ru−(η 2 -(NO)) isomer is a decisive parameter for the formation of the Ru−ON isomer at high temperature owing to a two-step isomerization mechanism Ru−NO→Ru−(η 2 -(NO))→Ru−ON. Furthermore, we report the low-temperature structures for each isomer, which were revealed by photocrystallography.

AB - The conditions for the photogeneration of NO linkage isomers at room temperature are studied. By pulsed laser irradiation in the blue spectral range, the long-lived Ru−ON isomer can be generated at room temperature, which is crucial for potential applications, such as holography and data storage. By using static and time-resolved spectroscopy (UV/Vis and IR), we give evidence that the liftime of the Ru−(η 2 -(NO)) isomer is a decisive parameter for the formation of the Ru−ON isomer at high temperature owing to a two-step isomerization mechanism Ru−NO→Ru−(η 2 -(NO))→Ru−ON. Furthermore, we report the low-temperature structures for each isomer, which were revealed by photocrystallography.

KW - nitrosyl

KW - photochemistry

KW - photocrystallography

KW - ruthenium

KW - UV/Vis spectroscopy

KW - MECHANISM

KW - METASTABLE STATES

UR - http://www.scopus.com/inward/record.url?scp=85065478888&partnerID=8YFLogxK

U2 - 10.1002/chem.201901205

DO - 10.1002/chem.201901205

M3 - Article

C2 - 30957917

AN - SCOPUS:85065478888

VL - 25

SP - 7569

EP - 7574

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 31

ER -

ID: 20160682