Research output: Contribution to journal › Article › peer-review
Rice husk derived activated carbon/polyaniline composites as active materials for supercapacitors. / Lebedeva, M. V.; Ayupov, A. B.; Yeletsky, P. M. et al.
In: International Journal of Electrochemical Science, Vol. 13, No. 4, 01.04.2018, p. 3674-3690.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Rice husk derived activated carbon/polyaniline composites as active materials for supercapacitors
AU - Lebedeva, M. V.
AU - Ayupov, A. B.
AU - Yeletsky, P. M.
AU - Parmon, V. N.
PY - 2018/4/1
Y1 - 2018/4/1
N2 - Composite materials (CM) "carbon/polyaniline" were synthesized using porous activated carbon (AC) produced from carbonized rice husk, which has specific surface area 2265 m2g-1 measured by direct BET method . The series of the CM was synthesized by oxidative aniline polymerization method in the presence of the AC in acidic medium; polyaniline (PAni) content was varied from 18 to 60 wt. %. Electrochemical and properties of the CM were investigated by cyclic voltammetry, galvanostatic charge/discharge and stability tests. Results indicate that properties of the composites are governed by ratio of the components: a form of cyclic voltammogram curves and location of specific ox-red polyaniline peaks strongly depend on the PAni amount. Gravimetric capacitance grows with polymer content in the material and reaches maxima 465 F·g-1 in 1M H2SO4 at discharge current density 0.2 A·g-1 for the sample with polyaniline content 60 wt %. However, durability tests show that the most stable is the sample with the lowest (18 wt. %) polyaniline amount.
AB - Composite materials (CM) "carbon/polyaniline" were synthesized using porous activated carbon (AC) produced from carbonized rice husk, which has specific surface area 2265 m2g-1 measured by direct BET method . The series of the CM was synthesized by oxidative aniline polymerization method in the presence of the AC in acidic medium; polyaniline (PAni) content was varied from 18 to 60 wt. %. Electrochemical and properties of the CM were investigated by cyclic voltammetry, galvanostatic charge/discharge and stability tests. Results indicate that properties of the composites are governed by ratio of the components: a form of cyclic voltammogram curves and location of specific ox-red polyaniline peaks strongly depend on the PAni amount. Gravimetric capacitance grows with polymer content in the material and reaches maxima 465 F·g-1 in 1M H2SO4 at discharge current density 0.2 A·g-1 for the sample with polyaniline content 60 wt %. However, durability tests show that the most stable is the sample with the lowest (18 wt. %) polyaniline amount.
KW - Activated carbon
KW - Composite materials
KW - Polyaniline
KW - Rice Husk
KW - Synergetic effect
UR - http://www.scopus.com/inward/record.url?scp=85045025119&partnerID=8YFLogxK
U2 - 10.20964/2018.04.34
DO - 10.20964/2018.04.34
M3 - Article
AN - SCOPUS:85045025119
VL - 13
SP - 3674
EP - 3690
JO - International Journal of Electrochemical Science
JF - International Journal of Electrochemical Science
SN - 1452-3981
IS - 4
ER -
ID: 12414987