Standard

Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing. / Ruban, N. V.; Potemkin, D. I.; Rogozhnikov, V. N. et al.

In: International Journal of Hydrogen Energy, Vol. 46, No. 72, 19.10.2021, p. 35840-35852.

Research output: Contribution to journal › Article › peer-review

Harvard

Ruban, NV, Potemkin, DI, Rogozhnikov, VN, Shefer, KI, Snytnikov, PV & Sobyanin, VA 2021, 'Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing', International Journal of Hydrogen Energy, vol. 46, no. 72, pp. 35840-35852. https://doi.org/10.1016/j.ijhydene.2021.01.183

APA

Ruban, N. V., Potemkin, D. I., Rogozhnikov, V. N., Shefer, K. I., Snytnikov, P. V., & Sobyanin, V. A. (2021). Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing. International Journal of Hydrogen Energy, 46(72), 35840-35852. https://doi.org/10.1016/j.ijhydene.2021.01.183

Vancouver

Ruban NV, Potemkin DI, Rogozhnikov VN, Shefer KI, Snytnikov PV, Sobyanin VA. Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing. International Journal of Hydrogen Energy. 2021 Oct 19;46(72):35840-35852. Epub 2021 Feb 25. doi: 10.1016/j.ijhydene.2021.01.183

Author

Ruban, N. V. ; Potemkin, D. I. ; Rogozhnikov, V. N. et al. / Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing. In: International Journal of Hydrogen Energy. 2021 ; Vol. 46, No. 72. pp. 35840-35852.

BibTeX

@article{0b9bf5da98db44df9caa8de27afb2b30,
title = "Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing",
abstract = "Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl FeCrAlloy wire mesh supported catalysts were prepared via multistep procedure. They were characterized by XRD, SEM and TEM techniques. A comparative study of autothermal reforming (ATR) of isooctane and simulated gasoline (blends of isooctane, ortho-xylene and naphthalene) over Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl was performed. Both catalysts showed excellent performance in ATR of isooctane at molar ratios of O2:C = 0.51 and H2O:C = 2.59, T = 750°С and GHSV = 10000 h−1. In the ATR of isooctane – o-xylene blend in presence of Rh–Ni-containing catalyst carbon formation was observed. Rh-containing catalyst demonstrated rather good activity and stability even in the case of isooctane – o-xylene – naphthalene blend.",
keywords = "Autothermal reforming, Gasoline, Isooctane, Nickel, Rhodium, Syngas",
author = "Ruban, {N. V.} and Potemkin, {D. I.} and Rogozhnikov, {V. N.} and Shefer, {K. I.} and Snytnikov, {P. V.} and Sobyanin, {V. A.}",
note = "Funding Information: In the part of catalyst characterization and experiments with aromatic compounds, the work was supported by the Russian Science Foundation under the project № 19-19-00257 . In the part of experiments with pure isooctane the work was supported by Russian Foundation for Basic Research under the project № 20-33-90162 (N.V. Ruban). The experiments were carried out using facilities of the shared research center “National center of investigation of catalysts” at Boreskov Institute of Catalysis. Publisher Copyright: {\textcopyright} 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = oct,
day = "19",
doi = "10.1016/j.ijhydene.2021.01.183",
language = "English",
volume = "46",
pages = "35840--35852",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
number = "72",

}

RIS

TY - JOUR

T1 - Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing

AU - Ruban, N. V.

AU - Potemkin, D. I.

AU - Rogozhnikov, V. N.

AU - Shefer, K. I.

AU - Snytnikov, P. V.

AU - Sobyanin, V. A.

N1 - Funding Information: In the part of catalyst characterization and experiments with aromatic compounds, the work was supported by the Russian Science Foundation under the project № 19-19-00257 . In the part of experiments with pure isooctane the work was supported by Russian Foundation for Basic Research under the project № 20-33-90162 (N.V. Ruban). The experiments were carried out using facilities of the shared research center “National center of investigation of catalysts” at Boreskov Institute of Catalysis. Publisher Copyright: © 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/10/19

Y1 - 2021/10/19

N2 - Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl FeCrAlloy wire mesh supported catalysts were prepared via multistep procedure. They were characterized by XRD, SEM and TEM techniques. A comparative study of autothermal reforming (ATR) of isooctane and simulated gasoline (blends of isooctane, ortho-xylene and naphthalene) over Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl was performed. Both catalysts showed excellent performance in ATR of isooctane at molar ratios of O2:C = 0.51 and H2O:C = 2.59, T = 750°С and GHSV = 10000 h−1. In the ATR of isooctane – o-xylene blend in presence of Rh–Ni-containing catalyst carbon formation was observed. Rh-containing catalyst demonstrated rather good activity and stability even in the case of isooctane – o-xylene – naphthalene blend.

AB - Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl FeCrAlloy wire mesh supported catalysts were prepared via multistep procedure. They were characterized by XRD, SEM and TEM techniques. A comparative study of autothermal reforming (ATR) of isooctane and simulated gasoline (blends of isooctane, ortho-xylene and naphthalene) over Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl was performed. Both catalysts showed excellent performance in ATR of isooctane at molar ratios of O2:C = 0.51 and H2O:C = 2.59, T = 750°С and GHSV = 10000 h−1. In the ATR of isooctane – o-xylene blend in presence of Rh–Ni-containing catalyst carbon formation was observed. Rh-containing catalyst demonstrated rather good activity and stability even in the case of isooctane – o-xylene – naphthalene blend.

KW - Autothermal reforming

KW - Gasoline

KW - Isooctane

KW - Nickel

KW - Rhodium

KW - Syngas

UR - http://www.scopus.com/inward/record.url?scp=85101513329&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2021.01.183

DO - 10.1016/j.ijhydene.2021.01.183

M3 - Article

AN - SCOPUS:85101513329

VL - 46

SP - 35840

EP - 35852

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 72

ER -

ID: 28011912