Research output: Contribution to journal › Article › peer-review
Regeneration of Rh/Ce0.75Zr0.25O2 – δ/θ-Al2O3/FeCrAl Catalyst after Autothermal Reforming of Diesel Fuel. / Shilov, V. A.; Rogozhnikov, V. N.; Potemkin, D. I. et al.
In: Kinetics and Catalysis, Vol. 64, No. 2, 04.2023, p. 215-220.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Regeneration of Rh/Ce0.75Zr0.25O2 – δ/θ-Al2O3/FeCrAl Catalyst after Autothermal Reforming of Diesel Fuel
AU - Shilov, V. A.
AU - Rogozhnikov, V. N.
AU - Potemkin, D. I.
AU - Snytnikov, P. V.
N1 - This study was supported by the Russian Science Foundation (grant no. 19-19-00257, https://rscf.ru/project/19-19-00257 ). Публикация для корректировки.
PY - 2023/4
Y1 - 2023/4
N2 - The formation of soot (coke) on the surface of a structured Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl catalyst in the course of autothermal reforming of diesel fuel into synthesis gas was studied. The SEM analysis revealed the formation of fibrous carbon particles of 5–50 µm in size on the catalyst surface. It was found that the process of coke formation occurred on the catalytic coating surface and caused no exfoliation and/or damage of the catalytic layer; the carbon deposits were readily oxidized during catalyst regeneration by oxygen or water vapor. Intense oxidation of soot with oxygen began at a temperature of 450°C; a major portion of carbon deposits was oxidized even before the reactor furnace reached an operating temperature of the autothermal reforming of diesel fuel (750°C). Water vapor also oxidized carbon deposits but less efficiently than oxygen. The catalyst regeneration with water vapor proceeded actively at a temperature of 750°C, and this fact indicated the possibility of catalyst self-regeneration in the autothermal reforming of diesel fuel, which is performed with an excess of water.
AB - The formation of soot (coke) on the surface of a structured Rh/Ce0.75Zr0.25O2/Al2O3/FeCrAl catalyst in the course of autothermal reforming of diesel fuel into synthesis gas was studied. The SEM analysis revealed the formation of fibrous carbon particles of 5–50 µm in size on the catalyst surface. It was found that the process of coke formation occurred on the catalytic coating surface and caused no exfoliation and/or damage of the catalytic layer; the carbon deposits were readily oxidized during catalyst regeneration by oxygen or water vapor. Intense oxidation of soot with oxygen began at a temperature of 450°C; a major portion of carbon deposits was oxidized even before the reactor furnace reached an operating temperature of the autothermal reforming of diesel fuel (750°C). Water vapor also oxidized carbon deposits but less efficiently than oxygen. The catalyst regeneration with water vapor proceeded actively at a temperature of 750°C, and this fact indicated the possibility of catalyst self-regeneration in the autothermal reforming of diesel fuel, which is performed with an excess of water.
KW - autothermal reforming
KW - diesel fuel
KW - fuel cell
KW - hydrogen
KW - regeneration
KW - structured catalyst
KW - synthesis gas
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85162041203&origin=inward&txGid=2088e65c8af9c5e321ab5b401708f313
UR - https://www.mendeley.com/catalogue/b98574c2-f045-302d-9695-1779adb8fbf3/
U2 - 10.1134/S0023158423020076
DO - 10.1134/S0023158423020076
M3 - Article
VL - 64
SP - 215
EP - 220
JO - Kinetics and Catalysis
JF - Kinetics and Catalysis
SN - 0023-1584
IS - 2
ER -
ID: 59647829