Recent progress in catalytic oxygenation of aromatic C–H groups with the environmentally benign oxidants H2O2 and O2

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Recent progress in catalytic oxygenation of aromatic C–H groups with the environmentally benign oxidants H₂O₂ and O₂. / Ottenbacher, Roman V.; Talsi, Evgenii P.; Bryliakov, Konstantin P.

In: Applied Organometallic Chemistry, Vol. 34, No. 11, e5900, 01.11.2020.

Research output: Contribution to journal › Review article › peer-review

BibTeX

@article{46c92f85f67a49108199a980a3202988,

title = "Recent progress in catalytic oxygenation of aromatic C–H groups with the environmentally benign oxidants H2O2 and O2",

abstract = "Developing efficient approaches for the selective oxygenation of aromatic C–H groups has been a challenging goal, interesting from both fundamental and practical perspectives. Designing catalyst systems for the direct production of phenol from benzene holds significant practical promise; on the contrary, novel strategies for the late-stage selective introduction of oxygen into aromatic rings of complex organic molecules could be useful for the synthesis of fine chemicals, including biologically active compounds. Another aspect of the overall picture is toughening environmental constraints, resulting in a steady increase in the number of catalyst systems relying on environmentally benign oxidants such as H2O2 and O2. Overall, today, the realm of selective catalytic aromatic C–H oxidations is developing rapidly. This review summarizes the progress made in homo- and heterogeneous catalyst systems of aromatic C–H oxygenations with hydrogen peroxide and molecular oxygen, achieved in the last decade.",

keywords = "aromatic oxidation, C–H activation, electrophilic substitution, hydrogen peroxide, oxygen, vitamin K, SELECTIVE OXIDATION, ONE-POT SYNTHESIS, hydrogen peroxide, vitamin K-3, electrophilic substitution, BENZENE HYDROXYLATION, P-BENZOQUINONES, C-H activation, EFFICIENT OXIDATION, PHASE HYDROXYLATION, aromatic oxidation, AEROBIC OXIDATION, HYDROGEN-PEROXIDE, DIRECT HYDROXYLATION, oxygen, HETEROGENEOUS CATALYST, aromatic oxidation, C–H activation, electrophilic substitution, hydrogen peroxide, oxygen, vitamin K3",

author = "Ottenbacher, {Roman V.} and Talsi, {Evgenii P.} and Bryliakov, {Konstantin P.}",

year = "2020",

month = nov,

day = "1",

doi = "10.1002/aoc.5900",

language = "English",

volume = "34",

journal = "Applied Organometallic Chemistry",

issn = "0268-2605",

publisher = "John Wiley and Sons Ltd",

number = "11",

}

RIS

TY - JOUR

T1 - Recent progress in catalytic oxygenation of aromatic C–H groups with the environmentally benign oxidants H2O2 and O2

AU - Ottenbacher, Roman V.

AU - Talsi, Evgenii P.

AU - Bryliakov, Konstantin P.

PY - 2020/11/1

Y1 - 2020/11/1

N2 - Developing efficient approaches for the selective oxygenation of aromatic C–H groups has been a challenging goal, interesting from both fundamental and practical perspectives. Designing catalyst systems for the direct production of phenol from benzene holds significant practical promise; on the contrary, novel strategies for the late-stage selective introduction of oxygen into aromatic rings of complex organic molecules could be useful for the synthesis of fine chemicals, including biologically active compounds. Another aspect of the overall picture is toughening environmental constraints, resulting in a steady increase in the number of catalyst systems relying on environmentally benign oxidants such as H2O2 and O2. Overall, today, the realm of selective catalytic aromatic C–H oxidations is developing rapidly. This review summarizes the progress made in homo- and heterogeneous catalyst systems of aromatic C–H oxygenations with hydrogen peroxide and molecular oxygen, achieved in the last decade.

AB - Developing efficient approaches for the selective oxygenation of aromatic C–H groups has been a challenging goal, interesting from both fundamental and practical perspectives. Designing catalyst systems for the direct production of phenol from benzene holds significant practical promise; on the contrary, novel strategies for the late-stage selective introduction of oxygen into aromatic rings of complex organic molecules could be useful for the synthesis of fine chemicals, including biologically active compounds. Another aspect of the overall picture is toughening environmental constraints, resulting in a steady increase in the number of catalyst systems relying on environmentally benign oxidants such as H2O2 and O2. Overall, today, the realm of selective catalytic aromatic C–H oxidations is developing rapidly. This review summarizes the progress made in homo- and heterogeneous catalyst systems of aromatic C–H oxygenations with hydrogen peroxide and molecular oxygen, achieved in the last decade.

KW - aromatic oxidation, C–H activation, electrophilic substitution, hydrogen peroxide, oxygen, vitamin K

KW - SELECTIVE OXIDATION

KW - ONE-POT SYNTHESIS

KW - hydrogen peroxide

KW - vitamin K-3

KW - electrophilic substitution

KW - BENZENE HYDROXYLATION

KW - P-BENZOQUINONES

KW - C-H activation

KW - EFFICIENT OXIDATION

KW - PHASE HYDROXYLATION

KW - aromatic oxidation

KW - AEROBIC OXIDATION

KW - HYDROGEN-PEROXIDE

KW - DIRECT HYDROXYLATION

KW - oxygen

KW - HETEROGENEOUS CATALYST

KW - aromatic oxidation, C–H activation, electrophilic substitution, hydrogen peroxide, oxygen, vitamin K3

UR - http://www.scopus.com/inward/record.url?scp=85087691058&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b6fea51e-1d85-3de3-8438-3314be73b6d6/

U2 - 10.1002/aoc.5900

DO - 10.1002/aoc.5900

M3 - Review article

AN - SCOPUS:85087691058

VL - 34

JO - Applied Organometallic Chemistry

JF - Applied Organometallic Chemistry

SN - 0268-2605

IS - 11

M1 - e5900

ER -

ID: 24736329