Research output: Contribution to journal › Article › peer-review
Reactions of polyfluorinated chalcones with hydroxylamine and subsequent intramolecular cyclization. / Gavrilov, I. N.; Orlova, N. A.; Demakov, P. A. et al.
In: Journal of Fluorine Chemistry, Vol. 292, 110591, 07.2026.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Reactions of polyfluorinated chalcones with hydroxylamine and subsequent intramolecular cyclization
AU - Gavrilov, I. N.
AU - Orlova, N. A.
AU - Demakov, P. A.
AU - Rybalova, T. V.
PY - 2026/7
Y1 - 2026/7
N2 - Polyfluorinated chalcones react with hydroxylamine hydrochloride to form oximes, 3-hydroxylaminooximes, dihydroquinoline and benzisoxazole derivatives, depending on the chalcone structure and the reaction conditions. The last two structure types are formed as a result of intramolecular cyclization by replacing the ortho-fluorine atom in the perfluoro phenyl ring next to the carbonyl group.
AB - Polyfluorinated chalcones react with hydroxylamine hydrochloride to form oximes, 3-hydroxylaminooximes, dihydroquinoline and benzisoxazole derivatives, depending on the chalcone structure and the reaction conditions. The last two structure types are formed as a result of intramolecular cyclization by replacing the ortho-fluorine atom in the perfluoro phenyl ring next to the carbonyl group.
KW - Benzisoxazole
KW - Dihydroquinolines
KW - Oximes
KW - Polyfluorinated chalcones
KW - Reactions with hydroxylamine
UR - https://www.scopus.com/pages/publications/105042587340
UR - https://www.mendeley.com/catalogue/125f8db2-3b2d-308f-9d88-e42cc6826f94/
U2 - 10.1016/j.jfluchem.2026.110591
DO - 10.1016/j.jfluchem.2026.110591
M3 - Article
VL - 292
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
M1 - 110591
ER -
ID: 80162472