Research output: Contribution to journal › Article › peer-review
Reactions of aromatic compounds with xenon difluoride. / Bardin, V. V.; Adonin, N. Yu.
In: Russian Journal of Organic Chemistry, Vol. 52, No. 10, 2016, p. 1400-1407.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Reactions of aromatic compounds with xenon difluoride
AU - Bardin, V. V.
AU - Adonin, N. Yu
PY - 2016
Y1 - 2016
N2 - Reactions of substituted benzenes C6H5R (R = Me, F, Cl, Br, CF3, NO2) with xenon difluoride in the presence of boron trifluoride–diethyl ether complex in weakly acidic (1,1,1,3,3-pentafluorobutane) and weakly basic media (acetonitrile) have been studied. These reactions lead to the formation of fluorobenzene derivatives FC6H4R (isomer mixture) together with isomeric difluorobenzenes and fluorinated and non-fluorinated biphenyls. The results have been compared with previously reported data obtained in other solvents using other catalysts.
AB - Reactions of substituted benzenes C6H5R (R = Me, F, Cl, Br, CF3, NO2) with xenon difluoride in the presence of boron trifluoride–diethyl ether complex in weakly acidic (1,1,1,3,3-pentafluorobutane) and weakly basic media (acetonitrile) have been studied. These reactions lead to the formation of fluorobenzene derivatives FC6H4R (isomer mixture) together with isomeric difluorobenzenes and fluorinated and non-fluorinated biphenyls. The results have been compared with previously reported data obtained in other solvents using other catalysts.
UR - http://www.scopus.com/inward/record.url?scp=84996479908&partnerID=8YFLogxK
U2 - 10.1134/S1070428016100055
DO - 10.1134/S1070428016100055
M3 - Article
AN - SCOPUS:84996479908
VL - 52
SP - 1400
EP - 1407
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 10
ER -
ID: 25412828