Research output: Contribution to journal › Article › peer-review
Reaction Operators for Radical Pairs. the Exactly Solvable Model. / Purtov, Petr A.
In: Zeitschrift fur Physikalische Chemie, Vol. 231, No. 2, 01.02.2017, p. 225-238.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Reaction Operators for Radical Pairs. the Exactly Solvable Model
AU - Purtov, Petr A.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - In the present work, the reaction operator for radical pairs of the main equation of spin chemistry has been modified on the basis of an exactly solvable model. The model contains both the reversible and irreversible transitions. For this model, expression for the reaction operator is more complex due to the expanded basis of spin states. The reaction operator of a phenomenological equation is a particular case of a more general approach and only in the limiting case of the completely irreversible recombination process, these operators coincide.
AB - In the present work, the reaction operator for radical pairs of the main equation of spin chemistry has been modified on the basis of an exactly solvable model. The model contains both the reversible and irreversible transitions. For this model, expression for the reaction operator is more complex due to the expanded basis of spin states. The reaction operator of a phenomenological equation is a particular case of a more general approach and only in the limiting case of the completely irreversible recombination process, these operators coincide.
KW - basic equation
KW - electron transfer
KW - recombination
KW - spin chemistry
UR - http://www.scopus.com/inward/record.url?scp=85012240369&partnerID=8YFLogxK
U2 - 10.1515/zpch-2016-0834
DO - 10.1515/zpch-2016-0834
M3 - Article
AN - SCOPUS:85012240369
VL - 231
SP - 225
EP - 238
JO - Zeitschrift fur Physikalische Chemie
JF - Zeitschrift fur Physikalische Chemie
SN - 0942-9352
IS - 2
ER -
ID: 9053018