Reaction of several resveratrol glycoside derivatives with hypochlorites in various media

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Reaction of several resveratrol glycoside derivatives with hypochlorites in various media. / Rogachev, A. D.; Komarova, N. I.; Pozdeeva, A. V. et al.

In: Chemistry of Natural Compounds, Vol. 48, No. 1, 03.2012, p. 1-7.

Research output: Contribution to journal › Article › peer-review

Harvard

Rogachev, AD, Komarova, NI, Pozdeeva, AV, Korchagina, DV, Vasil'Ev, VG, Salakhutdinov, NF & Tolstikov, GA 2012, 'Reaction of several resveratrol glycoside derivatives with hypochlorites in various media', Chemistry of Natural Compounds, vol. 48, no. 1, pp. 1-7. https://doi.org/10.1007/s10600-012-0146-z

APA

Rogachev, A. D., Komarova, N. I., Pozdeeva, A. V., Korchagina, D. V., Vasil'Ev, V. G., Salakhutdinov, N. F., & Tolstikov, G. A. (2012). Reaction of several resveratrol glycoside derivatives with hypochlorites in various media. Chemistry of Natural Compounds, 48(1), 1-7. https://doi.org/10.1007/s10600-012-0146-z

Vancouver

Rogachev AD, Komarova NI, Pozdeeva AV, Korchagina DV, Vasil'Ev VG, Salakhutdinov NF et al. Reaction of several resveratrol glycoside derivatives with hypochlorites in various media. Chemistry of Natural Compounds. 2012 Mar;48(1):1-7. doi: 10.1007/s10600-012-0146-z

Author

Rogachev, A. D. ; Komarova, N. I. ; Pozdeeva, A. V. et al. / Reaction of several resveratrol glycoside derivatives with hypochlorites in various media. In: Chemistry of Natural Compounds. 2012 ; Vol. 48, No. 1. pp. 1-7.

BibTeX

@article{9153bf07d22a46038bd1a71cd2236f97,

title = "Reaction of several resveratrol glycoside derivatives with hypochlorites in various media",

abstract = "The reactions of pterostilbenoside (trans-3,5-dimethoxystilben-4′-O- β-D-glucoside) and Ar-O-Tr derivatives of resveratroloside (3,5-dihydroxystilben-4′-O-β-D-glucoside) and pinostilbenoside (3-methoxy-5-hydroxystilben-4′-O-β-D-glucoside) with NaOCl and t-BuOCl in the presence of the stable nitroxyl radical TEMPO were studied in various media. It was found that the principal product of pterostilbenoside transformation was its 2,6-dichloroderivative, a part of which was oxidized to form 2,6-dichloropterostilbene glucuronide. Trityl ethers of resveratroloside and pinostilbenoside reacted with the hypochlorites to form mixtures of products.",

keywords = "hypochlorites, oxidation, resveratrol, stilbene glycosides, TEMPO, triphenylmethyl ethers",

author = "Rogachev, {A. D.} and Komarova, {N. I.} and Pozdeeva, {A. V.} and Korchagina, {D. V.} and Vasil'Ev, {V. G.} and Salakhutdinov, {N. F.} and Tolstikov, {G. A.}",

year = "2012",

month = mar,

doi = "10.1007/s10600-012-0146-z",

language = "English",

volume = "48",

pages = "1--7",

journal = "Chemistry of Natural Compounds",

issn = "0009-3130",

publisher = "Springer New York",

number = "1",

}

RIS

TY - JOUR

T1 - Reaction of several resveratrol glycoside derivatives with hypochlorites in various media

AU - Rogachev, A. D.

AU - Komarova, N. I.

AU - Pozdeeva, A. V.

AU - Korchagina, D. V.

AU - Vasil'Ev, V. G.

AU - Salakhutdinov, N. F.

AU - Tolstikov, G. A.

PY - 2012/3

Y1 - 2012/3

N2 - The reactions of pterostilbenoside (trans-3,5-dimethoxystilben-4′-O- β-D-glucoside) and Ar-O-Tr derivatives of resveratroloside (3,5-dihydroxystilben-4′-O-β-D-glucoside) and pinostilbenoside (3-methoxy-5-hydroxystilben-4′-O-β-D-glucoside) with NaOCl and t-BuOCl in the presence of the stable nitroxyl radical TEMPO were studied in various media. It was found that the principal product of pterostilbenoside transformation was its 2,6-dichloroderivative, a part of which was oxidized to form 2,6-dichloropterostilbene glucuronide. Trityl ethers of resveratroloside and pinostilbenoside reacted with the hypochlorites to form mixtures of products.

AB - The reactions of pterostilbenoside (trans-3,5-dimethoxystilben-4′-O- β-D-glucoside) and Ar-O-Tr derivatives of resveratroloside (3,5-dihydroxystilben-4′-O-β-D-glucoside) and pinostilbenoside (3-methoxy-5-hydroxystilben-4′-O-β-D-glucoside) with NaOCl and t-BuOCl in the presence of the stable nitroxyl radical TEMPO were studied in various media. It was found that the principal product of pterostilbenoside transformation was its 2,6-dichloroderivative, a part of which was oxidized to form 2,6-dichloropterostilbene glucuronide. Trityl ethers of resveratroloside and pinostilbenoside reacted with the hypochlorites to form mixtures of products.

KW - hypochlorites

KW - oxidation

KW - resveratrol

KW - stilbene glycosides

KW - TEMPO

KW - triphenylmethyl ethers

UR - http://www.scopus.com/inward/record.url?scp=84858318611&partnerID=8YFLogxK

U2 - 10.1007/s10600-012-0146-z

DO - 10.1007/s10600-012-0146-z

M3 - Article

AN - SCOPUS:84858318611

VL - 48

SP - 1

EP - 7

JO - Chemistry of Natural Compounds

JF - Chemistry of Natural Compounds

SN - 0009-3130

IS - 1

ER -

ID: 26770506