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Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium. / Mezhenkova, T. V.; Komarov, V. V.; Karpov, V. M. et al.

In: Russian Journal of Organic Chemistry, Vol. 57, No. 8, 5, 08.2021, p. 1256-1267.

Research output: Contribution to journal › Article › peer-review

Harvard

Mezhenkova, TV, Komarov, VV, Karpov, VM, Sinyakov, VR, Zonov, YV & Krasnov, VI 2021, 'Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium', Russian Journal of Organic Chemistry, vol. 57, no. 8, 5, pp. 1256-1267. https://doi.org/10.1134/S1070428021080042

APA

Mezhenkova, T. V., Komarov, V. V., Karpov, V. M., Sinyakov, V. R., Zonov, Y. V., & Krasnov, V. I. (2021). Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium. Russian Journal of Organic Chemistry, 57(8), 1256-1267. [5]. https://doi.org/10.1134/S1070428021080042

Vancouver

Mezhenkova TV, Komarov VV, Karpov VM, Sinyakov VR, Zonov YV, Krasnov VI. Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium. Russian Journal of Organic Chemistry. 2021 Aug;57(8):1256-1267. 5. doi: 10.1134/S1070428021080042

Author

Mezhenkova, T. V. ; Komarov, V. V. ; Karpov, V. M. et al. / Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium. In: Russian Journal of Organic Chemistry. 2021 ; Vol. 57, No. 8. pp. 1256-1267.

BibTeX

@article{1155425cf2ee4370b443b07023ab67ad,
title = "Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium",
abstract = "The reaction of perfluorobenzocyclobutene (1 mol) with isomeric tetrafluorobenzenes (2 mol) in an SbF5 medium resulted in the isolation of 1,2-bis(tetrafluorophenyl)perfluorocyclobutene after treatment of the reaction mixtures with HF and of (3,4,5,6-tetrafluorobenzen-1,2-diyl)bis[(tetrafluorophenyl)methanones] after hydrolysis of the reaction mixtures. Along with these products, the reactions with 1,2,4,5- and 1,2,3,4-tetrafluorobenzenes give 4,5,6,7-tetrafluoro-1,3,3-tris(tetrafluorophenyl)-1,3-dihydro-2-benzofuran-1-ols, and the reaction with 1,2,3,4-tetrafluorobenzene affords {2-[bis(2,3,4,5-tetrafluorophenyl)methyl]-3,4,5,6-tetrafluorophenyl}(2,3,4,5-tetrafluorophenyl)methanone.",
keywords = "antimony pentafluoride, cation, perfluorocyclobutene, skeletal transformations, tetrafluorobenzene",
author = "Mezhenkova, {T. V.} and Komarov, {V. V.} and Karpov, {V. M.} and Sinyakov, {V. R.} and Zonov, {Ya V.} and Krasnov, {V. I.}",
note = "Funding Information: The authors are grateful to the Chemical Research Center for Collective Use, Siberian Branch, Russian Academy of Sciences, for spectral and analytical measurements. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = aug,
doi = "10.1134/S1070428021080042",
language = "English",
volume = "57",
pages = "1256--1267",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "8",

}

RIS

TY - JOUR

T1 - Reaction of Perfluorobenzocyclobutene with Isomeric Tetrafluorobenzenes in an SbF5 Medium

AU - Mezhenkova, T. V.

AU - Komarov, V. V.

AU - Karpov, V. M.

AU - Sinyakov, V. R.

AU - Zonov, Ya V.

AU - Krasnov, V. I.

N1 - Funding Information: The authors are grateful to the Chemical Research Center for Collective Use, Siberian Branch, Russian Academy of Sciences, for spectral and analytical measurements. Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/8

Y1 - 2021/8

N2 - The reaction of perfluorobenzocyclobutene (1 mol) with isomeric tetrafluorobenzenes (2 mol) in an SbF5 medium resulted in the isolation of 1,2-bis(tetrafluorophenyl)perfluorocyclobutene after treatment of the reaction mixtures with HF and of (3,4,5,6-tetrafluorobenzen-1,2-diyl)bis[(tetrafluorophenyl)methanones] after hydrolysis of the reaction mixtures. Along with these products, the reactions with 1,2,4,5- and 1,2,3,4-tetrafluorobenzenes give 4,5,6,7-tetrafluoro-1,3,3-tris(tetrafluorophenyl)-1,3-dihydro-2-benzofuran-1-ols, and the reaction with 1,2,3,4-tetrafluorobenzene affords {2-[bis(2,3,4,5-tetrafluorophenyl)methyl]-3,4,5,6-tetrafluorophenyl}(2,3,4,5-tetrafluorophenyl)methanone.

AB - The reaction of perfluorobenzocyclobutene (1 mol) with isomeric tetrafluorobenzenes (2 mol) in an SbF5 medium resulted in the isolation of 1,2-bis(tetrafluorophenyl)perfluorocyclobutene after treatment of the reaction mixtures with HF and of (3,4,5,6-tetrafluorobenzen-1,2-diyl)bis[(tetrafluorophenyl)methanones] after hydrolysis of the reaction mixtures. Along with these products, the reactions with 1,2,4,5- and 1,2,3,4-tetrafluorobenzenes give 4,5,6,7-tetrafluoro-1,3,3-tris(tetrafluorophenyl)-1,3-dihydro-2-benzofuran-1-ols, and the reaction with 1,2,3,4-tetrafluorobenzene affords {2-[bis(2,3,4,5-tetrafluorophenyl)methyl]-3,4,5,6-tetrafluorophenyl}(2,3,4,5-tetrafluorophenyl)methanone.

KW - antimony pentafluoride

KW - cation

KW - perfluorocyclobutene

KW - skeletal transformations

KW - tetrafluorobenzene

UR - http://www.scopus.com/inward/record.url?scp=85115784627&partnerID=8YFLogxK

U2 - 10.1134/S1070428021080042

DO - 10.1134/S1070428021080042

M3 - Article

AN - SCOPUS:85115784627

VL - 57

SP - 1256

EP - 1267

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 8

M1 - 5

ER -

ID: 34349919