Radiation-Generated Recombination Exciplexes of Phenylethynyl-Substituted Polyfluorobiphenyls

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Radiation-Generated Recombination Exciplexes of Phenylethynyl-Substituted Polyfluorobiphenyls. / Nikul’shin, P. V.; Filippova, E. A.; Fedunov, R. G. et al.

In: High Energy Chemistry, Vol. 57, No. Suppl 3, 12.2023, p. S445-S454.

Research output: Contribution to journal › Article › peer-review

Author

Nikul’shin, P. V. ; Filippova, E. A. ; Fedunov, R. G. et al. / Radiation-Generated Recombination Exciplexes of Phenylethynyl-Substituted Polyfluorobiphenyls. In: High Energy Chemistry. 2023 ; Vol. 57, No. Suppl 3. pp. S445-S454.

BibTeX

@article{fd787134598043a3a5d3ad318231c726,

title = "Radiation-Generated Recombination Exciplexes of Phenylethynyl-Substituted Polyfluorobiphenyls",

abstract = "The work examines the possibilities of generating optically inaccessible exciplexes by radiation chemistry techniques and describing them using quantum chemical methods. Two new target compounds were synthesized, and their luminescent properties were characterized. Using radiation-induced luminescence methods, the formation of exciplexes with N,N-dimethylaniline from these compounds as a result of recombination of a radical ion pair in a nonpolar solution was shown, and their luminescent characteristics were studied. Bound excited states for three possible exciplex structures and their corresponding emission spectra were calculated, and the optimal exciplex structure was shown to agree with experiment.",

author = "Nikul{\textquoteright}shin, {P. V.} and Filippova, {E. A.} and Fedunov, {R. G.} and Kuibida, {L. V.} and Glebov, {E. M.} and Stass, {D. V.}",

note = "This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained. Публикация для корректировки.",

year = "2023",

month = dec,

doi = "10.1134/S0018143923090102",

language = "English",

volume = "57",

pages = "S445--S454",

journal = "High Energy Chemistry",

issn = "0018-1439",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "Suppl 3",

}

RIS

TY - JOUR

T1 - Radiation-Generated Recombination Exciplexes of Phenylethynyl-Substituted Polyfluorobiphenyls

AU - Nikul’shin, P. V.

AU - Filippova, E. A.

AU - Fedunov, R. G.

AU - Kuibida, L. V.

AU - Glebov, E. M.

AU - Stass, D. V.

N1 - This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained. Публикация для корректировки.

PY - 2023/12

Y1 - 2023/12

N2 - The work examines the possibilities of generating optically inaccessible exciplexes by radiation chemistry techniques and describing them using quantum chemical methods. Two new target compounds were synthesized, and their luminescent properties were characterized. Using radiation-induced luminescence methods, the formation of exciplexes with N,N-dimethylaniline from these compounds as a result of recombination of a radical ion pair in a nonpolar solution was shown, and their luminescent characteristics were studied. Bound excited states for three possible exciplex structures and their corresponding emission spectra were calculated, and the optimal exciplex structure was shown to agree with experiment.

AB - The work examines the possibilities of generating optically inaccessible exciplexes by radiation chemistry techniques and describing them using quantum chemical methods. Two new target compounds were synthesized, and their luminescent properties were characterized. Using radiation-induced luminescence methods, the formation of exciplexes with N,N-dimethylaniline from these compounds as a result of recombination of a radical ion pair in a nonpolar solution was shown, and their luminescent characteristics were studied. Bound excited states for three possible exciplex structures and their corresponding emission spectra were calculated, and the optimal exciplex structure was shown to agree with experiment.

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85186141126&origin=inward&txGid=be21badc66cdd851020dc85a676fafd6

UR - https://www.mendeley.com/catalogue/e4b26635-230a-3609-8177-e39746e028d0/

U2 - 10.1134/S0018143923090102

DO - 10.1134/S0018143923090102

M3 - Article

VL - 57

SP - S445-S454

JO - High Energy Chemistry

JF - High Energy Chemistry

SN - 0018-1439

IS - Suppl 3

ER -

ID: 59727447