Research output: Contribution to journal › Article › peer-review
Quartz crystal microbalance in the active mode as a tool to modify sensor surface for higher selectivity and sensitivity. / Dultsev, Fedor N.
In: Sensors and Actuators, B: Chemical, Vol. 239, 01.02.2017, p. 494-500.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Quartz crystal microbalance in the active mode as a tool to modify sensor surface for higher selectivity and sensitivity
AU - Dultsev, Fedor N.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - Oscillating quartz crystal microbalance (QCM) surface was used to increase the rates of reactions on this surface. It is demonstrated that the rate of the formation of chemisorbed monolayer increases when the surface oscillates, so the time necessary for surface modification decreases from 20 h to 20 min. During surface oscillation, the molecules bound non-specifically get detached from the surface, but more specific bonds are formed between nano-objects and the surface, which allows us to enhance the sensitivity and selectivity of sensors based on affine interactions. With the help of oscillatory treatment, we carried out the separation of oligonucleotides from the mixture containing fully complementary oligonucleotides and those having mismatches.
AB - Oscillating quartz crystal microbalance (QCM) surface was used to increase the rates of reactions on this surface. It is demonstrated that the rate of the formation of chemisorbed monolayer increases when the surface oscillates, so the time necessary for surface modification decreases from 20 h to 20 min. During surface oscillation, the molecules bound non-specifically get detached from the surface, but more specific bonds are formed between nano-objects and the surface, which allows us to enhance the sensitivity and selectivity of sensors based on affine interactions. With the help of oscillatory treatment, we carried out the separation of oligonucleotides from the mixture containing fully complementary oligonucleotides and those having mismatches.
KW - Bond rupture
KW - QCM
KW - Selectivity
KW - Surface modification
KW - ELECTROCHEMISTRY
KW - GOLD
KW - SELF-ASSEMBLED MONOLAYERS
KW - AU(111)
KW - ADSORPTION-KINETICS
KW - HORSERADISH-PEROXIDASE
KW - SPECTROSCOPY
KW - BOND RUPTURE FORCES
KW - SCANNING-TUNNELING-MICROSCOPY
UR - http://www.scopus.com/inward/record.url?scp=84989881039&partnerID=8YFLogxK
U2 - 10.1016/j.snb.2016.08.054
DO - 10.1016/j.snb.2016.08.054
M3 - Article
AN - SCOPUS:84989881039
VL - 239
SP - 494
EP - 500
JO - Sensors and Actuators, B: Chemical
JF - Sensors and Actuators, B: Chemical
SN - 0925-4005
ER -
ID: 10321871