Pulse microcalorimetry study of methane dry reforming reaction on ni/ceria-zirconia catalyst

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Pulse microcalorimetry study of methane dry reforming reaction on ni/ceria-zirconia catalyst. / Simonov, Mikhail N.; Rogov, Vladimir A.; Smirnova, Marina Yu et al.

In: Catalysts, Vol. 7, No. 9, 268, 12.09.2017.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{daf46d87723642d19d2e8791598b9f3b,

title = "Pulse microcalorimetry study of methane dry reforming reaction on ni/ceria-zirconia catalyst",

abstract = "For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species.",

keywords = "Ceria-zirconia, Mechanism, Methane dry reforming, Pulse microcalorimetry, Synthesis in supercritical alcohol, OXIDATION, methane dry reforming, MECHANISM, pulse microcalorimetry, STATE, CO, ceria-zirconia, KINETICS, synthesis in supercritical alcohol, SURFACE, mechanism, CARBON-DIOXIDE, TRANSIENT",

author = "Simonov, {Mikhail N.} and Rogov, {Vladimir A.} and Smirnova, {Marina Yu} and Sadykov, {Vladislav A.}",

note = "Publisher Copyright: {\textcopyright} 2017 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2017",

month = sep,

day = "12",

doi = "10.3390/catal7090268",

language = "English",

volume = "7",

journal = "Catalysts",

issn = "2073-4344",

publisher = "MDPI AG",

number = "9",

}

RIS

TY - JOUR

T1 - Pulse microcalorimetry study of methane dry reforming reaction on ni/ceria-zirconia catalyst

AU - Simonov, Mikhail N.

AU - Rogov, Vladimir A.

AU - Smirnova, Marina Yu

AU - Sadykov, Vladislav A.

PY - 2017/9/12

Y1 - 2017/9/12

N2 - For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species.

AB - For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species.

KW - Ceria-zirconia

KW - Mechanism

KW - Methane dry reforming

KW - Pulse microcalorimetry

KW - Synthesis in supercritical alcohol

KW - OXIDATION

KW - methane dry reforming

KW - MECHANISM

KW - pulse microcalorimetry

KW - STATE

KW - CO

KW - ceria-zirconia

KW - KINETICS

KW - synthesis in supercritical alcohol

KW - SURFACE

KW - mechanism

KW - CARBON-DIOXIDE

KW - TRANSIENT

UR - http://www.scopus.com/inward/record.url?scp=85029458168&partnerID=8YFLogxK

U2 - 10.3390/catal7090268

DO - 10.3390/catal7090268

M3 - Article

AN - SCOPUS:85029458168

VL - 7

JO - Catalysts

JF - Catalysts

SN - 2073-4344

IS - 9

M1 - 268

ER -

ID: 9912178