Pseudomacrobicyclic phthalocyaninate-capped cobalt(iii) tris-pyridineoximates : Template synthesis, x-ray structure and spectral characteristics. / Belova, Svetlana A.; Dudkin, Semyon V.; Belov, Alexander S. et al.
In: Macroheterocycles, Vol. 12, No. 2, 2019, p. 193-197.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Pseudomacrobicyclic phthalocyaninate-capped cobalt(iii) tris-pyridineoximates
T2 - Template synthesis, x-ray structure and spectral characteristics
AU - Belova, Svetlana A.
AU - Dudkin, Semyon V.
AU - Belov, Alexander S.
AU - Nelyubina, Yulia V.
AU - Novikov, Valentin V.
AU - Zubavichus, Yan V.
AU - Voloshin, Yan Z.
N1 - Publisher Copyright: © ISUCT Publishing.
PY - 2019
Y1 - 2019
N2 - First pseudomacrobicyclic phthalocyaninate-capped cobalt(III) tris-pyridineoximates were obtained in moderate yields (40-49%) by the direct template condensation of 2-acetylpyridineoxime with zirconium(IV) and hafnium(IV) phthalocyaninates on the cobalt ion as a matrix. These complexes were thoroughly characterized using elemental analysis, MALDI-TOF mass-spectrometry, NMR and UV-Vis spectroscopies and by the single-crystal X-ray diffraction. Their electrochemical behaviour was studied byusing the cyclic and differential pulse voltammetries.
AB - First pseudomacrobicyclic phthalocyaninate-capped cobalt(III) tris-pyridineoximates were obtained in moderate yields (40-49%) by the direct template condensation of 2-acetylpyridineoxime with zirconium(IV) and hafnium(IV) phthalocyaninates on the cobalt ion as a matrix. These complexes were thoroughly characterized using elemental analysis, MALDI-TOF mass-spectrometry, NMR and UV-Vis spectroscopies and by the single-crystal X-ray diffraction. Their electrochemical behaviour was studied byusing the cyclic and differential pulse voltammetries.
KW - Cobalt complexes
KW - Hafnium complexes
KW - Macrocyclic compounds
KW - Phthalocyanines
KW - Polynuclear complexes
KW - Template reactions
KW - Zirconium complexes
KW - ROUTE
KW - template reactions
KW - zirconium complexes
KW - hafnium complexes
KW - CLATHROCHELATE PRECURSORS
KW - COMPLEXES
KW - cobalt complexes
KW - IRON(II)
KW - NICKEL(II)
KW - phthalocyanines
KW - LIGANDS
KW - polynuclear complexes
KW - BINUCLEAR
UR - http://www.scopus.com/inward/record.url?scp=85073558917&partnerID=8YFLogxK
U2 - 10.6060/mhc190550d
DO - 10.6060/mhc190550d
M3 - Article
AN - SCOPUS:85073558917
VL - 12
SP - 193
EP - 197
JO - Macroheterocycles
JF - Macroheterocycles
SN - 1998-9539
IS - 2
ER -
ID: 25463672