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Proton Relaxometry of Long-Lived Spin Order. / Kiryutin, Alexey S.; Panov, Mikhail S.; Yurkovskaya, Alexandra V. et al.

In: ChemPhysChem, Vol. 20, No. 5, 04.03.2019, p. 766-772.

Research output: Contribution to journal › Article › peer-review

Harvard

Kiryutin, AS, Panov, MS, Yurkovskaya, AV, Ivanov, KL & Bodenhausen, G 2019, 'Proton Relaxometry of Long-Lived Spin Order', ChemPhysChem, vol. 20, no. 5, pp. 766-772. https://doi.org/10.1002/cphc.201800960

APA

Kiryutin, A. S., Panov, M. S., Yurkovskaya, A. V., Ivanov, K. L., & Bodenhausen, G. (2019). Proton Relaxometry of Long-Lived Spin Order. ChemPhysChem, 20(5), 766-772. https://doi.org/10.1002/cphc.201800960

Vancouver

Kiryutin AS, Panov MS, Yurkovskaya AV, Ivanov KL, Bodenhausen G. Proton Relaxometry of Long-Lived Spin Order. ChemPhysChem. 2019 Mar 4;20(5):766-772. doi: 10.1002/cphc.201800960

Author

Kiryutin, Alexey S. ; Panov, Mikhail S. ; Yurkovskaya, Alexandra V. et al. / Proton Relaxometry of Long-Lived Spin Order. In: ChemPhysChem. 2019 ; Vol. 20, No. 5. pp. 766-772.

BibTeX

@article{7f52027163d94285a2fcae7793ef83a3,
title = "Proton Relaxometry of Long-Lived Spin Order",
abstract = "A study of long-lived spin order in chlorothiophene carboxylates at both high and low magnetic fields is presented. Careful sample preparation (removal of dissolved oxygen in solution, chelating of paramagnetic impurities, reduction of convection) allows one to obtain very long-lived singlet order of the two coupled protons in chlorothiophene derivatives, having lifetimes of about 130 s in D2O and 240 s in deuterated methanol, which are much longer than the T1-relaxation times (18 and 30 s, respectively, at a field (Formula presented.) =9.4 T). In protonated solvents the relaxation times become shorter, but the lifetime is still substantially longer than (Formula presented.). In addition, long-lived coherences are shown to have lifetimes as long as 30 s. Thiophene derivatives can be used as molecular tags to study slow transport, slow dynamics and slow chemical processes, as has been shown in recent years.",
keywords = "field dependence, kinetics, long-lived states, magnetic properties, relaxometry, SLOW DIFFUSION, PARA-HYDROGEN, FIELD, DIFFUSION-COEFFICIENTS, RELAXATION, SINGLET-STATES, LEVEL ANTI-CROSSINGS, NMR, MAGNETIC-RESONANCE, POLARIZATION",
author = "Kiryutin, {Alexey S.} and Panov, {Mikhail S.} and Yurkovskaya, {Alexandra V.} and Ivanov, {Konstantin L.} and Geoffrey Bodenhausen",
note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2019",
month = mar,
day = "4",
doi = "10.1002/cphc.201800960",
language = "English",
volume = "20",
pages = "766--772",
journal = "ChemPhysChem",
issn = "1439-4235",
publisher = "Wiley-Blackwell",
number = "5",

}

RIS

TY - JOUR

T1 - Proton Relaxometry of Long-Lived Spin Order

AU - Kiryutin, Alexey S.

AU - Panov, Mikhail S.

AU - Yurkovskaya, Alexandra V.

AU - Ivanov, Konstantin L.

AU - Bodenhausen, Geoffrey

N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2019/3/4

Y1 - 2019/3/4

N2 - A study of long-lived spin order in chlorothiophene carboxylates at both high and low magnetic fields is presented. Careful sample preparation (removal of dissolved oxygen in solution, chelating of paramagnetic impurities, reduction of convection) allows one to obtain very long-lived singlet order of the two coupled protons in chlorothiophene derivatives, having lifetimes of about 130 s in D2O and 240 s in deuterated methanol, which are much longer than the T1-relaxation times (18 and 30 s, respectively, at a field (Formula presented.) =9.4 T). In protonated solvents the relaxation times become shorter, but the lifetime is still substantially longer than (Formula presented.). In addition, long-lived coherences are shown to have lifetimes as long as 30 s. Thiophene derivatives can be used as molecular tags to study slow transport, slow dynamics and slow chemical processes, as has been shown in recent years.

AB - A study of long-lived spin order in chlorothiophene carboxylates at both high and low magnetic fields is presented. Careful sample preparation (removal of dissolved oxygen in solution, chelating of paramagnetic impurities, reduction of convection) allows one to obtain very long-lived singlet order of the two coupled protons in chlorothiophene derivatives, having lifetimes of about 130 s in D2O and 240 s in deuterated methanol, which are much longer than the T1-relaxation times (18 and 30 s, respectively, at a field (Formula presented.) =9.4 T). In protonated solvents the relaxation times become shorter, but the lifetime is still substantially longer than (Formula presented.). In addition, long-lived coherences are shown to have lifetimes as long as 30 s. Thiophene derivatives can be used as molecular tags to study slow transport, slow dynamics and slow chemical processes, as has been shown in recent years.

KW - field dependence

KW - kinetics

KW - long-lived states

KW - magnetic properties

KW - relaxometry

KW - SLOW DIFFUSION

KW - PARA-HYDROGEN

KW - FIELD

KW - DIFFUSION-COEFFICIENTS

KW - RELAXATION

KW - SINGLET-STATES

KW - LEVEL ANTI-CROSSINGS

KW - NMR

KW - MAGNETIC-RESONANCE

KW - POLARIZATION

UR - http://www.scopus.com/inward/record.url?scp=85061255935&partnerID=8YFLogxK

U2 - 10.1002/cphc.201800960

DO - 10.1002/cphc.201800960

M3 - Article

C2 - 30600920

AN - SCOPUS:85061255935

VL - 20

SP - 766

EP - 772

JO - ChemPhysChem

JF - ChemPhysChem

SN - 1439-4235

IS - 5

ER -

ID: 18485202