Standard

Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I). / Mikhailov, M. A.; Berezin, A. S.; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 12, 8, 12.2021, p. 1896-1906.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhailov, MA, Berezin, AS, Sukhikh, TS, Sheven’, DG, Gushchin, AL & Sokolov, MN 2021, 'Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I)', Journal of Structural Chemistry, vol. 62, no. 12, 8, pp. 1896-1906. https://doi.org/10.1134/S002247662112009X

APA

Mikhailov, M. A., Berezin, A. S., Sukhikh, T. S., Sheven’, D. G., Gushchin, A. L., & Sokolov, M. N. (2021). Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I). Journal of Structural Chemistry, 62(12), 1896-1906. [8]. https://doi.org/10.1134/S002247662112009X

Vancouver

Mikhailov MA, Berezin AS, Sukhikh TS, Sheven’ DG, Gushchin AL, Sokolov MN. Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I). Journal of Structural Chemistry. 2021 Dec;62(12):1896-1906. 8. doi: 10.1134/S002247662112009X

Author

Mikhailov, M. A. ; Berezin, A. S. ; Sukhikh, T. S. et al. / Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I). In: Journal of Structural Chemistry. 2021 ; Vol. 62, No. 12. pp. 1896-1906.

BibTeX

@article{ecf0c370cd54432cbe0b402a7b79c858,
title = "Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I)",
abstract = "Two new cluster complexes (Bu4N)2[Mo6X8(OOC–C≡CH)6] (1) (X = Br) and (2) (X = I) are synthesized by the reaction of (Bu4N)2[Mo6X8(OOCCH3)6] (X = Br, I) with HOOC–C≡CH propiolic acid, their crystal structures are determined, and the luminescent properties are studied for powder samples at different temperatures. According to X-ray crystallographic data, molybdenum atoms are monodentately coordinated by oxygen atoms of the carboxyl group at Mo–O distances of 2.108(2)-2.121(16) {\AA}. The propiolate complexes are characterized by electrospray mass spectrometry, 1Н and 13С NMR, elemental analysis, and IR spectroscopy.",
keywords = "bromides, clusters, electrochemistry, iodides, luminescence, molybdenum, propiolate complexes, X-ray crystallographic analysis",
author = "Mikhailov, {M. A.} and Berezin, {A. S.} and Sukhikh, {T. S.} and Sheven{\textquoteright}, {D. G.} and Gushchin, {A. L.} and Sokolov, {M. N.}",
note = "Funding Information: The work was supported by the Ministry of Science and Higher Education of the Russian Federation, project No. 121031700313-8 (study of the electrochemical properties of new cluster complexes 1 and 2 , preparation of samples, and determination of the chemical composition and structures of 1 and 2 ), RFBR grant No. 20-03-00410 (search and optimization of synthesis methods for new cluster compound 1 and 2 ), and Russian Science Foundation grant No. 19-73-20196 (study of luminescent properties of new cluster complexes 1 and 2 ). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = dec,
doi = "10.1134/S002247662112009X",
language = "English",
volume = "62",
pages = "1896--1906",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "12",

}

RIS

TY - JOUR

T1 - Propiolate cluster complexes (Bu4N)2[Mo6 X 8(OOC–C≡CH)6] (X = Br, I)

AU - Mikhailov, M. A.

AU - Berezin, A. S.

AU - Sukhikh, T. S.

AU - Sheven’, D. G.

AU - Gushchin, A. L.

AU - Sokolov, M. N.

N1 - Funding Information: The work was supported by the Ministry of Science and Higher Education of the Russian Federation, project No. 121031700313-8 (study of the electrochemical properties of new cluster complexes 1 and 2 , preparation of samples, and determination of the chemical composition and structures of 1 and 2 ), RFBR grant No. 20-03-00410 (search and optimization of synthesis methods for new cluster compound 1 and 2 ), and Russian Science Foundation grant No. 19-73-20196 (study of luminescent properties of new cluster complexes 1 and 2 ). Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/12

Y1 - 2021/12

N2 - Two new cluster complexes (Bu4N)2[Mo6X8(OOC–C≡CH)6] (1) (X = Br) and (2) (X = I) are synthesized by the reaction of (Bu4N)2[Mo6X8(OOCCH3)6] (X = Br, I) with HOOC–C≡CH propiolic acid, their crystal structures are determined, and the luminescent properties are studied for powder samples at different temperatures. According to X-ray crystallographic data, molybdenum atoms are monodentately coordinated by oxygen atoms of the carboxyl group at Mo–O distances of 2.108(2)-2.121(16) Å. The propiolate complexes are characterized by electrospray mass spectrometry, 1Н and 13С NMR, elemental analysis, and IR spectroscopy.

AB - Two new cluster complexes (Bu4N)2[Mo6X8(OOC–C≡CH)6] (1) (X = Br) and (2) (X = I) are synthesized by the reaction of (Bu4N)2[Mo6X8(OOCCH3)6] (X = Br, I) with HOOC–C≡CH propiolic acid, their crystal structures are determined, and the luminescent properties are studied for powder samples at different temperatures. According to X-ray crystallographic data, molybdenum atoms are monodentately coordinated by oxygen atoms of the carboxyl group at Mo–O distances of 2.108(2)-2.121(16) Å. The propiolate complexes are characterized by electrospray mass spectrometry, 1Н and 13С NMR, elemental analysis, and IR spectroscopy.

KW - bromides

KW - clusters

KW - electrochemistry

KW - iodides

KW - luminescence

KW - molybdenum

KW - propiolate complexes

KW - X-ray crystallographic analysis

UR - http://www.scopus.com/inward/record.url?scp=85121734276&partnerID=8YFLogxK

UR - https://www.elibrary.ru/item.asp?id=47550213

UR - https://www.mendeley.com/catalogue/50b4076b-7d54-3555-9051-18e1a31abb54/

U2 - 10.1134/S002247662112009X

DO - 10.1134/S002247662112009X

M3 - Article

AN - SCOPUS:85121734276

VL - 62

SP - 1896

EP - 1906

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

M1 - 8

ER -

ID: 35195924